benzyl azide

Suppliers

Names

[ CAS No. ]:
622-79-7

[ Name ]:
benzyl azide

[Synonym ]:
MFCD00013836
Benzylazide

Chemical & Physical Properties

[ Density]:
1.0655

[ Boiling Point ]:
81-83°C 16mm

[ Melting Point ]:
157ºC

[ Molecular Formula ]:
C7H7N3

[ Molecular Weight ]:
133.15100

[ Flash Point ]:
82-85°C/16mm

[ Exact Mass ]:
133.06400

[ PSA ]:
49.75000

[ LogP ]:
1.94966

[ Index of Refraction ]:
1.5341

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
XS6650000
CHEMICAL NAME :
Toluene, alpha-azido-
CAS REGISTRY NUMBER :
622-79-7
BEILSTEIN REFERENCE NO. :
1907583
LAST UPDATED :
199612
DATA ITEMS CITED :
1
MOLECULAR FORMULA :
C7-H7-N3
MOLECULAR WEIGHT :
133.17
WISWESSER LINE NOTATION :
NNNR B1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
120 ug/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
AIPTAK Archives Internationales de Pharmacodynamie et de Therapie. (Heymans Institute of Pharmacology, De Pintelaan 185, B-9000 Ghent, Belgium) V.4- 1898- Volume(issue)/page/year: 108,473,1956

Safety Information

[ Symbol ]:

GHS08

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H351-H373

[ Precautionary Statements ]:
P281

[ Hazard Codes ]:
Xi

[ Risk Phrases ]:
2-11-48/20/21/22-40

[ Safety Phrases ]:
S15-S17-S33

[ RIDADR ]:
1993

[ Packaging Group ]:
III

[ Hazard Class ]:
3

[ HS Code ]:
2929909090

Synthetic Route

Click to get detail synthetic route

Customs

[ HS Code ]: 2929909090

[ Summary ]:
2929909090 other compounds with other nitrogen function VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

Articles

High-throughput chemical modification of oligonucleotides for systematic structure-activity relationship evaluation.

Bioconjug. Chem. 25(12) , 2222-32, (2014)

Chemical modification of siRNA is achieved in a high-throughput manner (96-well plate format) by copper catalyzed azide-alkyne cycloadditions. This transformation can be performed in one synthetic ope...

Bioorthogonal Labeling, Bioimaging, and Photocytotoxicity Studies of Phosphorescent Ruthenium(II) Polypyridine Dibenzocyclooctyne Complexes.

Chemistry 21 , 10729-40, (2015)

The synthesis, characterization, photophysics, lipophilicity, and cellular properties of new phosphorescent ruthenium(II) polypyridine complexes functionalized with a dibenzocyclooctyne (DIBO) or amin...

Phosphoramidite accelerated copper(i)-catalyzed [3 + 2] cycloadditions of azides and alkynes.

Chem. Commun. (Camb.) 16 , 2139-2141, (2009)

Monodentate phosphoramidite ligands are used to accelerate the copper(i)-catalyzed 1,3-dipolar cycloaddition of azides and alkynes (CuAAC) rapidly yielding a wide variety of functionalized 1,4-disubst...


More Articles

Related Compounds

  • p-F-benzyl azide
  • p-F-benzyl azide
  • methyl benzyl azide
  • p-acetylbenzyl azide
  • 4-vinyl benzyl azide
  • 2,6-difluoro benzyl azide
  • 4-((Cyclohexylamino)methyl)benzoic acid hydrochloride
  • Iodocinnamic acid
  • 1-[(2,4-Dichlorophenyl)methyl]-N-(1,1-dimethylethyl)-2-methyl-1H-indole-3-methanamine
  • 2-Methoxy-6-(pyrazol-1-yl)-benzonitrile
  • 1H-3-Benzazepin-7-ol, 8-chloro-2,3,4,5-tetrahydro-5-(3-iodophenyl)-3-methyl-, (S)-
  • (4-Methyl-tetrahydro-furan-2-yl)-methanol
  • N-(1-cyanocyclopentyl)-2-[4-(4-fluorobenzenesulfonyl)-1,4-diazepan-1-yl]acetamide
  • 4,5,6,7-Tetrahydrobenzo[d]isoxazole-3-carbaldehyde
  • 2-hydroxy-N-(5-methylpyridin-2-yl)butanamide
  • tert-Butyl-DL-alanine