tri(m-tolyl)phosphine

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Names

[ CAS No. ]:
6224-63-1

[ Name ]:
tri(m-tolyl)phosphine

[Synonym ]:
Tris(3-methylphenyl)phosphine
tri(m-tolyl)phosphine
tris(3-methylphenyl)phosphane
phosphine, tri-m-tolyl-
Phosphine, tris(3-methylphenyl)-
EINECS 228-312-4
MFCD00008532
Tri-m-tolylphosphine

Chemical & Physical Properties

[ Boiling Point ]:
423.1±44.0 °C at 760 mmHg

[ Melting Point ]:
97-99 °C(lit.)

[ Molecular Formula ]:
C21H21P

[ Molecular Weight ]:
304.365

[ Flash Point ]:
221.6±34.7 °C

[ Exact Mass ]:
304.138092

[ PSA ]:
13.59000

[ LogP ]:
7.07

[ Vapour Pressure ]:
0.0±1.0 mmHg at 25°C

MSDS

Click to get detail MSDS

Safety Information

[ Hazard Codes ]:
Xi: Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S36

[ WGK Germany ]:
3

[ HS Code ]:
2902909090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • m-tolylmagnesium bromide
  • tri(3-methylphenyl)phosphine oxide
  • bromozinc(1+),methylbenzene
  • 3-Bromotoluene
  • (2-quinaldinate)(carbonyl)(P(3-CH3-C5H4)3)2rhodium(I)
  • 3-Chlorotoluene

DownStream

Customs

[ HS Code ]: 2902909090

[ Summary ]:
2902909090 other aromatic hydrocarbons。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:2.0%。General tariff:30.0%

Related Compounds

  • tri(m-tolyl)phosphine oxide
  • tri(m-tolyl)phosphine sulphide
  • tri-m-tolyl(2,3,4-triphenylcyclopenta-2,4-dien-1-ylidene)-l5-arsane
  • dodecyl-tri-m-tolyl-silane
  • dibromobis[tris(m-tolyl)phosphine]cobalt
  • Tris(α,α,α-trifluoro-m-tolyl)phosphine oxide
  • 6-(1-phenylethyl)-2-thioxo-2,3-dihydropyrimidin-4(1H)-one
  • 3-[(2R)-2-aminopropyl]-1H-indol-5-ol
  • Piperazine,1-[2-(4-chlorophenyl)-3-methyl-1-oxobutyl]-4-[4-(2-furanyl)-2-pyrimidinyl]-
  • N-{[(2-methyl-4-phenyl-1,3-thiazol-5-yl)amino]carbonyl}-1-benzothiophene-2-sulfonamide
  • N-(4-tert-butylcyclohexyl)benzylamine
  • 6-[2-(4-Sulfamoyl-phenyl)-ethylcarbamoyl]-pyridine-2-carboxylic acid
  • 4-chloro-2-cyclopropyl-5H,6H,7H,8H,9H-pyrimido[4,5-b]azepine
  • 1-Benzyl-4-[N-ethyl-N-(3-(2-methyl-1-propenyl)-2-pyridinyl)amino]piperidine
  • 2-Mercapto-5,7-dimethylquinoline-3-carbonitrile
  • 4,5,6,7-Tetrahydropyrazolo[3,4-c]azepin-8(1H)-one
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