4-Chlorobenzonitrile

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Names

[ CAS No. ]:
623-03-0

[ Name ]:
4-Chlorobenzonitrile

[Synonym ]:
p-chlorobenzonitrile
4-chloro-benzonitrile
para-chloro-benzonitrile
MFCD00001813
EINECS 210-765-4
4-chloro-benzonitril
p-Chlorbenzonitril
P-CHLORBENZONITRILE
4-Chlorbenzolcarbonitril
Benzonitrile, 4-chloro-
para-cyano chlorobenzene
p-Chlorotolunitrile
4-Chlorobenzonitrile
1-chloro-4-cyanobenzene
PCBN
p-chloro-benzonitril
p-chlorobenzylnitrile
4-CYANOCHLOROBENZENE

Chemical & Physical Properties

[ Density]:
1.2±0.1 g/cm3

[ Boiling Point ]:
223.0±0.0 °C at 760 mmHg

[ Melting Point ]:
90-93 °C(lit.)

[ Molecular Formula ]:
C7H4ClN

[ Molecular Weight ]:
137.566

[ Flash Point ]:
86.2±14.8 °C

[ Exact Mass ]:
137.003220

[ PSA ]:
23.79000

[ LogP ]:
2.20

[ Vapour Pressure ]:
0.1±0.4 mmHg at 25°C

[ Index of Refraction ]:
1.563

[ Water Solubility ]:
insoluble

MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
DI2800000
CHEMICAL NAME :
Benzonitrile, p-chloro-
CAS REGISTRY NUMBER :
623-03-0
LAST UPDATED :
199701
DATA ITEMS CITED :
4
MOLECULAR FORMULA :
C7-H4-Cl-N
MOLECULAR WEIGHT :
137.57
WISWESSER LINE NOTATION :
NCR DG

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
Standard Draize test
ROUTE OF EXPOSURE :
Administration into the eye
SPECIES OBSERVED :
Rodent - rabbit
REFERENCE :
85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J., Prague, Czechoslovakia, Avicenum, 1986 Volume(issue)/page/year: -,908,1986 ** ACUTE TOXICITY DATA **
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
>300 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
JMCMAR Journal of Medicinal Chemistry. (American Chemical Soc., Distribution Office Dept. 223, POB POB 57136, West End Stn., Washington, DC 20037) V.6- 1963- Volume(issue)/page/year: 21,906,1978
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
150 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: AD691-490

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H302 + H332-H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Faceshields;Gloves

[ Hazard Codes ]:
Xn:Harmful

[ Risk Phrases ]:
R20/22;R36/37/38

[ Safety Phrases ]:
S23-S26-S36

[ RIDADR ]:
3439

[ WGK Germany ]:
2

[ RTECS ]:
DI2800000

[ Packaging Group ]:
III

[ Hazard Class ]:
6.1(b)

[ HS Code ]:
29269095

Synthetic Route

Precursor & DownStream

Precursor

  • 4-Chlorobenzenecarbaldehyde oxime
  • p-chlorobenzylalcohol
  • 4-Chlorobenzaldehyde
  • 4-Chlorobenzylamine
  • Ethyl 4-chlorobenzoate
  • 4-Bromochlorobenzene
  • N,N-Dimethylformamide
  • Benzamide,4-chloro-N,N-dimethyl-
  • 4-Aminobenzonitrile
  • 4-Chloro-N-methoxy-N-methylbenzamide

DownStream

  • N-(4-CYANOPHENYL)-N''-PHENYLUREA
  • 4-(PYRIDIN-2-YL)BENZONITRILE
  • Ethyl 3-(4-cyanophenyl)-3-oxopropanoate
  • 4'-Methyl-4-biphenylcarbonitrile
  • BI-P-TOLYL
  • 4-Ethoxybenzamide
  • Biphenyl-4-carboxamide
  • 4-CYANO-4'-NITRODIPHENYL
  • 4-(Trifluoromethyl)benzonitrile
  • 4-Mercaptobenzonitrile

Customs

[ HS Code ]: 2926909090

[ Summary ]:
HS:2926909090 other nitrile-function compounds VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

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Related Compounds

  • 4-Chlorobenzonitrile
  • 4-Chlorobenzonitrile
  • 4-chlorobenzonitrile oxide
  • 2-Nitro-4-chlorobenzonitrile
  • 3-Bromo-4-chlorobenzonitrile
  • 2-Amino-4-Chlorobenzonitrile
  • 2-Amino-1-(thiolan-2-yl)ethan-1-ol
  • 1-Benzyl-5-trifluoromethylindoline-2,3-dione
  • 4-((Cyclohexylamino)methyl)benzoic acid hydrochloride
  • 7-Nitro-2,3-dihydro-1H-inden-4-amine
  • 1-[(2,4-Dichlorophenyl)methyl]-N-(1,1-dimethylethyl)-2-methyl-1H-indole-3-methanamine
  • 3,3-Difluorocyclobutanecarbohydrazide
  • 1-(2-morpholino-5H-pyrrolo[3,4-d]pyrimidin-6(7H)-yl)-3-(phenylthio)propan-1-one
  • 2-Methoxy-6-(pyrazol-1-yl)-benzonitrile
  • 1H-3-Benzazepin-7-ol, 8-chloro-2,3,4,5-tetrahydro-5-(3-iodophenyl)-3-methyl-, (S)-
  • (4-Methyl-tetrahydro-furan-2-yl)-methanol