N,4-Dimethylaniline

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Names

[ CAS No. ]:
623-08-5

[ Name ]:
N,4-Dimethylaniline

[Synonym ]:
MFCD00025628
N-Methyl-p-toluidine
p-Toluidine, N-methyl-
EINECS 210-769-6
Benzenamine, N,4-dimethyl-
N,4-Dimethylaniline

Chemical & Physical Properties

[ Density]:
1.0±0.1 g/cm3

[ Boiling Point ]:
210.0±0.0 °C at 760 mmHg

[ Melting Point ]:
141.00 - 144.00ºC

[ Molecular Formula ]:
C8H11N

[ Molecular Weight ]:
121.180

[ Flash Point ]:
72.1±14.2 °C

[ Exact Mass ]:
121.089149

[ PSA ]:
12.03000

[ LogP ]:
2.06

[ Vapour Pressure ]:
0.2±0.4 mmHg at 25°C

[ Index of Refraction ]:
1.564

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS06, GHS08

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H301 + H311 + H331-H373-H412

[ Precautionary Statements ]:
P261-P273-P280-P301 + P310-P311

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
T:Toxic;

[ Risk Phrases ]:
R23/24/25;R33;R52/53

[ Safety Phrases ]:
S28-S36/37-S45

[ RIDADR ]:
UN 2810 6.1/PG 2

[ WGK Germany ]:
3

[ Packaging Group ]:
II

[ Hazard Class ]:
6.1(a)

[ HS Code ]:
2921430090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • p-Toluidine
  • methyl iodide
  • N,4'-DIMETHYLFORMANILIDE
  • 2-(methyl(p-tolyl)amino)benzo[cd]indazol-5(2H)-one
  • 2-(methyl(p-tolyl)amino)benzo[cd]indazol-3(2H)-one
  • Methanol
  • lithium,methylbenzene
  • 4,N,N-Trimethylaniline
  • 4-Bromotoluene

DownStream

  • N-methyl-N-(4-methylphenyl)benzenesulfonamide
  • N,4-Dimethylaniline, HCl
  • 4,N,N-Trimethylaniline
  • N-methyl-N-(4-methylphenyl)carbamoyl chloride
  • 3-(4-methylphenyl)-2H-phthalazine-1,4-dione
  • tetramethyl naphthalene-1,2,3,4-tetracarboxylate
  • dimethyl N-methyl-N-(p-tolyl)aminomaleate
  • dimethyl 1,5-dimethylindole-2,3-dicarboxylate
  • Thiourea,N-methyl-N-(4-methylphenyl)-

Customs

[ HS Code ]: 2921430090

[ Summary ]:
HS:2921430090 toluidines and their derivatives; salts thereof VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

Articles

Simultaneous encapsulation: molecules held at close range. Rebek J.

Angew. Chem. Int. Ed. Engl. 44(14) , 2068-2078, (2005)

Microwave-assisted synthesis of pyrazolo [3,4-d] pyrimidines from 2-amino-4, 6-dichloropyrimidine-5-carbaldehyde under solvent-free conditions. Quiroga J, et al.

Tetrahedron Lett. 49(20) , 3257-3259, (2008)

Palladium-promoted aromatic annelation with acetylene dicarboxylates. Sakakibara T, et al.

Chem. Lett. 15(5) , 797-800, (1986)


More Articles

Related Compounds

  • N,4-Dimethylaniline
  • N,4-Dimethylaniline,HCl
  • 3-Iodo-N,4-dimethylaniline
  • 3-bromo-N,4-dimethylaniline
  • 2-bromo-N,4-dimethylaniline
  • N-ethyl-N,4-dimethylaniline
  • tert-Butyl N-[cis-3-hydroxy-4-piperidyl]-n-methyl-carbamate
  • {2-methyl-1H-pyrrolo[2,3-b]pyridin-6-yl}methanol
  • methyl 1,3-dimethyl-1H-indazole-6-carboxylate
  • 2-iodo-1H-pyrrolo[2,3-b]pyridin-6-amine
  • 4-chloro-3-methyl-5-nitro-1H-pyrrolo[2,3-b]pyridine
  • (R)-1-Benzyl-3,3-difluoro-4-hydroxypyrrolidin-2-one
  • methyl 2-methyl-1H-pyrrolo[2,3-b]pyridine-5-carboxylate
  • {1-methyl-1H-pyrrolo[2,3-b]pyridin-4-yl}methanamine
  • 4-bromo-3-methyl-1H-indole-6-carbonitrile
  • 2-Azetidinecarboxylic acid, 2-(trifluoromethyl)-, 1,1-dimethylethyl ester, (2R)-
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