4-Bromomethylbenzoic acid

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Names

[ CAS No. ]:
6232-88-8

[ Name ]:
4-Bromomethylbenzoic acid

[Synonym ]:
4-(Bromomethyl)benzoic acid
4-bromomethyl benzoic acid
EINECS 228-343-3
p-Toluic acid, α-bromo-
α-Bromo-para-toluic acid
benzoic acid, 4-(bromomethyl)
Benzoic acid, 4-(bromomethyl)-
MFCD00002567
p-(Bromomethyl)benzoic acid
α-Bromo-p-toluic acid
Eprosartan Impurity 4

Chemical & Physical Properties

[ Density]:
1.6±0.1 g/cm3

[ Boiling Point ]:
328.8±25.0 °C at 760 mmHg

[ Melting Point ]:
224-229 °C(lit.)

[ Molecular Formula ]:
C8H7BrO2

[ Molecular Weight ]:
215.044

[ Flash Point ]:
152.7±23.2 °C

[ Exact Mass ]:
213.962936

[ PSA ]:
37.30000

[ LogP ]:
2.60

[ Vapour Pressure ]:
0.0±0.8 mmHg at 25°C

[ Index of Refraction ]:
1.614

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi:Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S36

[ RIDADR ]:
3261

[ WGK Germany ]:
3

[ Packaging Group ]:
III

[ Hazard Class ]:
8

[ HS Code ]:
29163900

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • 4-Methylbenzoic acid
  • p-tolylmethanol
  • p-Tolualdehyde
  • 4-Cyanobenzyl bromide
  • 1,4-Benzenedimethanol
  • Benzoyl bromide, 4-(bromomethyl)-
  • Ethyl 4-methylbenzoate
  • Ethyl 4-(bromomethyl)benzoate
  • 4-Bromotoluene
  • 4-bromomethyl benzoyl chloride

DownStream

  • 4-(Bromomethyl)-3-nitrobenzoic acid
  • 4-(Cyanomethyl)benzoic acid
  • 4-bromomethyl-3-nitrobenzoic acid succinimide ester
  • 4-(Ethoxymethyl)benzoic acid
  • 4-Carboxyphenylacetic acid
  • 4-Bromomethylbenzaldehyde
  • SOTS-1
  • 2-[4-(bromomethyl)phenyl]-1,3-benzoxazole
  • 4-(Hydroxymethyl)benzoic acid
  • 4-diethoxy-phosphoryl-methylbenzoic acid

Customs

[ HS Code ]: 2916399090

[ Summary ]:
2916399090 other aromatic monocarboxylic acids, their anhydrides, halides, peroxides, peroxyacids and their derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

Articles

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Nanoscale 7 , 14413-21, (2015)

Cellulose nanocrystals were grafted with imidazole functionalities up to DS 0.06 using a one-pot functionalization strategy. The resulting nanocrystals were shown to have a pH responsive surface charg...

Highly charged cellulose-based nanocrystals as flocculants for harvesting Chlorella vulgaris.

Bioresour. Technol. 194 , 270-5, (2015)

This study presents a novel flocculant for harvesting Chlorella vulgaris as model species for freshwater microalgae based on cellulose nanocrystals (CNCs), thus synthesized from a renewable and biodeg...

5-Arylidene-2,4-thiazolidinediones as inhibitors of protein tyrosine phosphatases.

Bioorg. Med. Chem. 15(15) , 5137-49, (2007)

4-(5-Arylidene-2,4-dioxothiazolidin-3-yl)methylbenzoic acids (2) were synthesized and evaluated in vitro as inhibitors of PTP1B and LMW-PTP, two protein tyrosine phosphatases (PTPs) which act as negat...


More Articles

Related Compounds

  • 3-Bromo-4-bromomethylbenzoic acid
  • 3-fluoro-4-bromomethylbenzoic acid
  • 4-bromomethylbenzoic acid allylester
  • 4-Bromomethylbenzoic acid methyl ester
  • 4-Bromomethylbenzoic acid tert-butyl ester
  • 3-Bromo-4-bromomethylbenzoic acid methyl ester
  • [(4-Pentyloxyphenyl)sulfonyl](3-pyridylmethyl)amine
  • 1-(Prop-1-en-2-yl)cyclohexane-1-carboxylic acid
  • 1(2H)-Pyridineacetamide, 2-oxo-N-[4-(2-phenyldiazenyl)phenyl]-5-(1-pyrrolidinylsulfonyl)-
  • 1-[3-(Trifluoromethyl)phenyl]-4-[2,4,6-tris(propan-2-yl)benzenesulfonyl]piperazine
  • Acetamide, N-[4-(2-phenyldiazenyl)phenyl]-2-[[5-(phenylmethyl)-1,3,4-oxadiazol-2-yl]thio]-
  • 2-({4-ethyl-11-methyl-3-oxo-8-thia-4,6-diazatricyclo[7.4.0.0^{2,7}]trideca-1(9),2(7),5-trien-5-yl}sulfanyl)-N-(4-sulfamoylphenyl)acetamide
  • 2-chloro-N-[2-(1H-imidazol-5-yl)ethyl]-5-(1H-tetrazol-1-yl)benzamide
  • (2-(Thiophen-3-yl)ethyl)hydrazine
  • 1-(4-Bromophenyl)cycloheptane-1-carbonitrile
  • 1-(5-Chloro-2-methoxyphenyl)cyclopropane-1-carboxylic acid
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