4-Methoxy-2-methylbenzoic acid

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Names

[ CAS No. ]:
6245-57-4

[ Name ]:
4-Methoxy-2-methylbenzoic acid

[Synonym ]:
2-Methyl-p-anisic acid
2-methyl-4-methoxybenzoic acid
4-Methoxy-2-methyl-benzoesaeure
MFCD00020291
4-Methoxy-2-methylbenzoic acid
2-Methyl-4-methoxybenzoesaeure
Benzoic acid, 4-methoxy-2-methyl-
4-methoxy-2-methyl benzoic acid

Chemical & Physical Properties

[ Density]:
1.2±0.1 g/cm3

[ Boiling Point ]:
294.3±20.0 °C at 760 mmHg

[ Melting Point ]:
177-181ºC(lit.)

[ Molecular Formula ]:
C9H10O3

[ Molecular Weight ]:
166.174

[ Flash Point ]:
118.6±15.3 °C

[ Exact Mass ]:
166.062988

[ PSA ]:
46.53000

[ LogP ]:
2.42

[ Vapour Pressure ]:
0.0±0.7 mmHg at 25°C

[ Index of Refraction ]:
1.541

Safety Information

[ Personal Protective Equipment ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter

[ Hazard Codes ]:
Xi

[ Risk Phrases ]:
36/37/38

[ Safety Phrases ]:
26-37

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2918990090

Synthetic Route

Precursor & DownStream

Precursor

  • Carbon dioxide
  • 4-Bromo-3-methyl-anisole
  • 4-Methoxy-2-methylbenzaldehyde
  • p-Anisic acid
  • methyl iodide
  • carbon monoxide
  • 3-Methylanisole
  • 4-methoxy-2-methylphenylmagnesium bromide
  • 4-methoxy-2-methylacetophenone
  • 1-Ethynyl-4-methoxy-2-methylbenzene

DownStream

  • methyl 4-methoxy-2-methylbenzoate
  • 4-Methoxyphthalic acid
  • 4-Hydroxyphthalic acid
  • 4-Hydroxy-2-methylbenzoic acid
  • 4-Methoxy-2-methylbenzamide
  • Benzoyl chloride, 4-methoxy-2-methyl- (9CI)
  • Methyl 2-(bromomethyl)-4-methoxybenzoate
  • 5-(4-methoxy-2-methylphenyl)-3-phenyl-1H-1,2,4-triazole
  • N,N-diethyl-4-methoxy-2-methylbenzamide
  • 4-Methoxy-2-methylphenylacetic acid

Customs

[ HS Code ]: 2918990090

[ Summary ]:
2918990090. other carboxylic acids with additional oxygen function and their anhydrides, halides, peroxides and peroxyacids; their halogenated, sulphonated, nitrated or nitrosated derivatives. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

Articles

A new class of nonhormonal pregnancy-terminating agents. Synthesis and contragestational activity of 3,5-diaryl-s-triazoles.

J. Med. Chem. 26(8) , 1187-92, (1983)

A series of 3,5-diaryl-s-triazoles were synthesized and evaluated as postimplantation contragestational agents. The introduction of various substituents (e.g., an o-alkyl chain on one phenyl and a m-a...

Pd(O2CCF3)2/benzoquinone: a versatile catalyst system for the decarboxylative olefination of arene carboxylic acids.

Org. Lett. 11(11) , 2341-4, (2009)

A versatile palladium catalyst system was developed to effect the decarboxylative Heck coupling of a variety of arenecarboxylic acids with a wide range of olefins. The key to obtaining the efficient c...

Spectral and thermal investigation of rare earth element 4-methoxy-2-methylbenzoates. Brzyska W and Ozga W.

J. Therm. Anal. Calorim. 70(2) , 467-474, (2002)


More Articles


Related Compounds

  • 4-methoxy-2-methylbenzoicacid
  • 4-methoxy-2,3-diphenylnaphthalen-1-ol
  • [4-methoxy-2-(3-methyloxiran-2-yl)phenyl] 2-methylpropanoate
  • [4-methoxy-2-(methoxymethoxy)phenyl]boronic acid
  • 4-methoxy-2-methylsulfanylaniline
  • 4-methoxy-2,2,6,6-tetramethylpiperidin-1-ium 1-oxide,nitrate
  • 4-Methoxy-2-pyridinecarboxylic acid
  • 2-Cyclopropoxy-N-methyl-6-nitroaniline
  • 3-Chloro-5-cyclopropoxy-2-fluoropyridine
  • 2-Tert-butoxy-4-cyclopropoxy-6-methoxypyridine
  • N-(4-Aminocyclohexyl)-3-methylbut-2-enamide
  • 3-Cyclopropoxy-2-fluoro-5-(methylthio)pyridine
  • 5-Cyclopropoxy-4-(methylamino)nicotinic acid
  • 3-Cyclopropoxy-N,N-dimethyl-5-(methylthio)pyridin-2-amine
  • 4-Cyclopropoxy-2-methoxy-5-(methylthio)pyridine
  • 1-(3-((6-Amino-5-(4-phenoxyphenyl)pyrimidin-4-yl)amino)azetidin-1-yl)prop-2-en-1-one
  • Methyl 4-chloro-2-isobutoxybenzoate
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