Acetamidomethanol

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Names

[ CAS No. ]:
625-51-4

[ Name ]:
Acetamidomethanol

[Synonym ]:
MFCD00014417
N-Acetylmethanolamine
Acetamidomethanol
acetamidemethanol
hydroxymethyl acetamide
Formicin
EINECS 210-897-2
N-Hydroxymethylacetamide

Chemical & Physical Properties

[ Density]:
1.14

[ Boiling Point ]:
321.3ºC at 760 mmHg

[ Melting Point ]:
48-52 °C

[ Molecular Formula ]:
C3H7NO2

[ Molecular Weight ]:
89.09320

[ Flash Point ]:
148.1ºC

[ Exact Mass ]:
89.04770

[ PSA ]:
49.33000

[ Index of Refraction ]:
1.431

[ Storage condition ]:
Store at 0°C

MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
AC3610000
CHEMICAL NAME :
Acetamide, N-(hydroxymethyl)-
CAS REGISTRY NUMBER :
625-51-4
BEILSTEIN REFERENCE NO. :
0506226
LAST UPDATED :
199612
DATA ITEMS CITED :
1
MOLECULAR FORMULA :
C3-H7-N-O2
MOLECULAR WEIGHT :
89.11

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
9 gm/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
ARPMAS Archiv der Pharmazie (Weinheim, Germany) (VCH Pub., Inc., 303 NW 12th Ave., Deerfield Beach, FL 33441) V.51-261, 1835-1923; V.305- 1972- Volume(issue)/page/year: 305,427,1972

Safety Information

[ Personal Protective Equipment ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter

[ Hazard Codes ]:
Xi

[ Risk Phrases ]:
R36/37/38:Irritating to eyes, respiratory system and skin .

[ Safety Phrases ]:
S22-S24/25

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ RTECS ]:
AC3610000

[ HS Code ]:
2924199090

Synthetic Route

Precursor & DownStream

Precursor

  • Acetamide
  • Formaldehyde
  • 1,3,5,7-Tetraazabicyclo[3.3.1]nonane,3,7-diacetyl-
  • H-Gly-Gly-OH

DownStream

  • N-formylacetamide
  • H-Cys(Acm)-OH.H20
  • N-Methylacetamide
  • Acetamide
  • Formaldehyde
  • Acm-thiopropionic acid
  • Aminomethylphosphonic acid
  • acetamidomethyl acetate
  • 2-methyl-6-phenyl-5,6-dihydro-4H-1,3-oxazine
  • N-(2-aminoethylsulfanylmethyl)acetamide

Customs

[ HS Code ]: 2924199090

[ Summary ]:
2924199090. other acyclic amides (including acyclic carbamates) and their derivatives; salts thereof. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

Articles

D.R. Maulding et al.

J. Org. Chem. 48 , 2938, (1983)

F. Albericio et al.

Synthesis , 271, (1987)


More Articles


Related Compounds

  • 4-((Cyclohexylamino)methyl)benzoic acid hydrochloride
  • 1-[(2,4-Dichlorophenyl)methyl]-N-(1,1-dimethylethyl)-2-methyl-1H-indole-3-methanamine
  • 2-Methoxy-6-(pyrazol-1-yl)-benzonitrile
  • 1H-3-Benzazepin-7-ol, 8-chloro-2,3,4,5-tetrahydro-5-(3-iodophenyl)-3-methyl-, (S)-
  • (4-Methyl-tetrahydro-furan-2-yl)-methanol
  • N-(1-cyanocyclopentyl)-2-[4-(4-fluorobenzenesulfonyl)-1,4-diazepan-1-yl]acetamide
  • 4,5,6,7-Tetrahydrobenzo[d]isoxazole-3-carbaldehyde
  • 4-Iodo-3-methoxy-1H-indazole
  • tert-Butyl-DL-alanine
  • 4-amino-N-[2-tert-butyl-1-(tetrahydro-2H-pyran-4-ylmethyl)-1H-benzimidazol-5-yl]-N-ethylbenzenesulfonamide