3-Iodotoluene

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Names

[ CAS No. ]:
625-95-6

[ Name ]:
3-Iodotoluene

[Synonym ]:
3-methyliodobenzene
3-iodo-toluene
Toluene,m-iodo-(7CI,8CI)
Toluene,m-iodo
3-Methylphenyl iodide
EINECS 210-918-5
Benzene,1-iodo-3-methyl
3-Iodotoluene
Toluene, m-iodo-
m-Iodotoluene
MFCD00001050
m-Tolyl iodide
Benzene, 1-iodo-3-methyl-
1-Iodo-3-methylbenzene
3-Me-C6H4-I
m-Methyliodobenzene

Chemical & Physical Properties

[ Density]:
1.7±0.1 g/cm3

[ Boiling Point ]:
213.0±0.0 °C at 760 mmHg

[ Melting Point ]:
-27°C

[ Molecular Formula ]:
C7H7I

[ Molecular Weight ]:
218.035

[ Flash Point ]:
82.2±0.0 °C

[ Exact Mass ]:
217.959229

[ LogP ]:
3.71

[ Vapour Pressure ]:
0.2±0.4 mmHg at 25°C

[ Index of Refraction ]:
1.605

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
DA3440000
CHEMICAL NAME :
Benzene, 1-iodo-3-methyl-
CAS REGISTRY NUMBER :
625-95-6
BEILSTEIN REFERENCE NO. :
1903634
LAST UPDATED :
199710
DATA ITEMS CITED :
3
MOLECULAR FORMULA :
C7-H7-I

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
2296 mg/kg
TOXIC EFFECTS :
Behavioral - convulsions or effect on seizure threshold
REFERENCE :
GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 36(9-10),44,1992

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xi:Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S36

[ RIDADR ]:
UN 2810

[ WGK Germany ]:
2

[ RTECS ]:
DA3440000

[ HS Code ]:
2903999090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • m-Tolylboronic acid
  • carbon monoxide
  • 1-iodyl-3-methylbenzene
  • (toluene-4-sulfonyl)-m-tolyl-diazene
  • lithium 2-iodo-4-methylbenzenesulfonate
  • lithium p-toluenesulphonate
  • m-tolylmagnesium bromide
  • m-methylbenzenediazonium tetrafluoroborate
  • 3-Toluidine
  • Toluene

DownStream

  • 2-(3-tert-butyl-5-methylphenyl)-1,3-dinitrobenzene
  • 3-Iodobenzhydrazide
  • 1-Methyl-3-phenoxybenzene
  • M-TOLYLHYDRAZINE
  • 3'-Methylacetanilide
  • 3-Iodobenzyl bromide
  • Ethyl meta-tolylacetate
  • 1-Methyl-3-(trifluoromethyl)benzene
  • N,N-Diethyl-m-toluidine

Customs

[ HS Code ]: 2903999090

[ Summary ]:
2903999090 halogenated derivatives of aromatic hydrocarbons VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%

Articles

Mizoroki-heck-type reaction mediated by potassium tert-butoxide.

Angew. Chem. Int. Ed. Engl. 50(20) , 4671-4, (2011)

Palladium-catalyzed synthesis of indene derivatives via propargylic carbonates with in situ generated organozinc compounds.

Org. Biomol. Chem. 6(6) , 1040-5, (2008)

The palladium-catalyzed carboannulation and arylation reaction of propargylic carbonates with in situ generated organozinc compounds produced an important new class of indene derivatives. The reaction...

[Information on basics of MAC for m-toluate iodide in the air of work area].

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Related Compounds

  • 4-azido-3-iodotoluene
  • α-Bromo-3-iodotoluene
  • 4-Bromo-3-iodotoluene
  • a-Bromo-3-iodotoluene
  • 4-Amino-3-iodotoluene
  • 2-Bromo-3-iodotoluene
  • 4-((Cyclohexylamino)methyl)benzoic acid hydrochloride
  • 1-[(2,4-Dichlorophenyl)methyl]-N-(1,1-dimethylethyl)-2-methyl-1H-indole-3-methanamine
  • 2-Methoxy-6-(pyrazol-1-yl)-benzonitrile
  • 1H-3-Benzazepin-7-ol, 8-chloro-2,3,4,5-tetrahydro-5-(3-iodophenyl)-3-methyl-, (S)-
  • (4-Methyl-tetrahydro-furan-2-yl)-methanol
  • N-(1-cyanocyclopentyl)-2-[4-(4-fluorobenzenesulfonyl)-1,4-diazepan-1-yl]acetamide
  • 4,5,6,7-Tetrahydrobenzo[d]isoxazole-3-carbaldehyde
  • tert-Butyl-DL-alanine
  • 4-amino-N-[2-tert-butyl-1-(tetrahydro-2H-pyran-4-ylmethyl)-1H-benzimidazol-5-yl]-N-ethylbenzenesulfonamide
  • N-[3-(Aminooxy)propyl]-N-butyl-1-butanamine