1,3-Bis(bromomethyl)benzene

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Names

[ CAS No. ]:
626-15-3

[ Name ]:
1,3-Bis(bromomethyl)benzene

[Synonym ]:
Benzene, 1,3-bis(bromomethyl)-
α,α′-Dibromo-m-xylene
E1R C1E
α,α'-Dibromo-m-xylene
m-Xylene, α,α'-dibromo- (8CI)
MFCD00000178
1,3-Bis(bromomethyl)benzene
m-Xylylene dibromide
meta-xylyl dibromide
m-Xylene, α,α'-dibromo-
EINECS 210-931-6
m-Xylylene Bromide

Chemical & Physical Properties

[ Density]:
1.8±0.1 g/cm3

[ Boiling Point ]:
258.2±0.0 °C at 760 mmHg

[ Melting Point ]:
74-77 °C(lit.)

[ Molecular Formula ]:
C₈H₈Br₂

[ Molecular Weight ]:
263.957

[ Flash Point ]:
138.1±21.0 °C

[ Exact Mass ]:
261.899261

[ LogP ]:
3.62

[ Vapour Pressure ]:
0.0±0.5 mmHg at 25°C

[ Index of Refraction ]:
1.611

[ Water Solubility ]:
dioxane: 0.1 g/mL, clear, colorless

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07, GHS08

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H315-H319-H334-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338-P342 + P311

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Faceshields;Gloves

[ Hazard Codes ]:
Xi

[ Risk Phrases ]:
R36/37/38:Irritating to eyes, respiratory system and skin . R43:May cause sensitization by skin contact.

[ Safety Phrases ]:
S26-S36/37

[ RIDADR ]:
UN 3448 6.1/PG 2

[ WGK Germany ]:
3

[ Packaging Group ]:
III

[ Hazard Class ]:
8

[ HS Code ]:
29036990

Synthetic Route

Click to get detail synthetic route

Customs

[ HS Code ]: 2903999090

[ Summary ]:
2903999090 halogenated derivatives of aromatic hydrocarbons VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%

Articles

Ribosomal synthesis of dehydroalanine-containing peptides.

J. Am. Chem. Soc. 128(22) , 7150-1, (2006)

Dehydroalanine is a nonproteinogenic amino acid, but it is a component of a wide variety of natural products with therapeutic activities. Indeed, this alpha,beta-unsaturated residue is a highly versat...

Bis-aminals: efficient tools for bis-macrocycle synthesis. Le Baccon M, et al.

New J. Chem. 25(9) , 1168-1174, (2001)

Preparation of new dinuclear half-titanocene complexes with ortho- and meta-xylene linkages and investigation of styrene polymerization. Linh NTB, et al.

J. Organomet. Chem. 694(21) , 3438-3443, (2009)

2-Bromo-1,3-bis(bromomethyl)benzene
5-methoxy-1,3-bis(bromomethyl)benzene
4,6-dimethyl-1,3-bis(bromomethyl)benzene
2,5-dimethoxy-1,3-bis(bromomethyl)benzene
2-[2,6-bis(bromomethyl)phenyl]-1,3-bis(bromomethyl)benzene
2-[2,6-bis(bromomethyl)phenyl]sulfanyl-1,3-bis(bromomethyl)benzene
3-(((Tert-butyldimethylsilyl)oxy)methyl)-4-iodo-1-methyl-1H-pyrazole
5-(1-Methyl-1H-benzimidazol-4-yl)-2-pyridinemethanol
1-Methyl-4-(6-(((triisopropylsilyl)oxy)methyl)pyridin-3-yl)-1H-benzo[d]imidazole
2-(4-(((1-Methyl-4-(pyridazin-3-yl)-1H-pyrazol-3-yl)oxy)methyl)phenyl)quinoline
Ethyl 1-methyl-3-((4-(quinolin-2-yl)benzyl)oxy)-1H-pyrazole-4-carboxylate
2-(4-((1,5-Dimethyl-1H-pyrazol-3-yl)methoxy)phenyl)-3-methylquinoline
3-(azetidin-3-yl)-1,5-dimethyl-1H-pyrazole
6-chloro-4-(methylthio)-2-(phenylmethoxy)-3-Pyridinemethanamine
3-methoxy-N,4-dimethylbenzene-1-sulfonamide
(2S,3S,4S,5R,6S)-6-(4-(((((((S)-4,11-Diethyl-4-hydroxy-3,14-dioxo-3,4,12,14-tetrahydro-1H-pyrano[3',4':6,7]indolizino[1,2-b]quinolin-9-yl)oxy)methyl)(2-(methylsulfonyl)ethyl)carbamoyl)oxy)methyl)-2-(2-(methylamino)acetamido)phenoxy)-3,4,5-trihydroxytetrahydro-2H-pyran-2-carboxylic acid

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