Tetrachlorocyclopropene

Names

[ CAS No. ]:
6262-42-6

[ Name ]:
Tetrachlorocyclopropene

[Synonym ]:
1,2,3,3-tetrachlorocyclopropene
EINECS 228-418-0
MFCD00001267

Chemical & Physical Properties

[ Density]:
1.45 g/mL at 25ºC(lit.)

[ Boiling Point ]:
125-130ºC(lit.)

[ Molecular Formula ]:
C₃Cl₄

[ Molecular Weight ]:
177.84400

[ Flash Point ]:
35.9ºC

[ Exact Mass ]:
175.87500

[ LogP ]:
2.86310

[ Appearance of Characters ]:
Liquid | Clear colorless

[ Index of Refraction ]:
n20/D 1.507(lit.)

[ Storage condition ]:
2-8°C

MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xi

[ Risk Phrases ]:
36/37

[ Safety Phrases ]:
26-36

[ RIDADR ]:
UN 2810 6.1/PG 2

[ WGK Germany ]:
3

[ HS Code ]:
2903890090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

pentachlorocyclopropane
diiodoacetylene
phenyl(trichloromethyl)mercury

DownStream

2,3,4,4-tetrachlorobicyclo[3.2.1]octa-2,6-diene
Cyclopropane,1,1,2,2,3,3-hexachloro-
2,3-bis(4-methoxyphenyl)cycloprop-2-en-1-one
DPC
2-CYCLOPROPEN-1-ONE
Benzene,1,1'-[(1E)-1,2-ethenediylbis(sulfonyl)]bis-
pentachlorocyclopropane
Chlorotributyltin
3,4,5-Trichloropyridazine
TRICHLOROACRYLONITRILE

Customs

[ HS Code ]: 2903890090

[ Summary ]:
2903890090. halogenated derivatives of cyclanic, cyclenic or cyclotherpenic hydrocarbons. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:5.5%. General tariff:30.0%

Articles

Electrochemical preparation of tris(tert-butyldimethylsilyl)cyclopropene and its hydride abstraction to tris(tert-butyldimethylsilyl)cyclopropenium tetrafluoroborate.

Proc. Natl. Acad. Sci. U. S. A. 96(18) , 10003-5, (1999)

Electrochemical reductive tert-butyldimethylsilylation of tetrachlorocyclopropene to 1,2,3-tris(tert-butyldimethylsilyl)cyclopropene, a potential strained precursor for Diels-Alder and related cycload...

3,3-Diethyl-and 3,3-dibenzyl-1,2-diferrocenylcyclopropenes.

Org. Biomol. Chem. 1(24) , 4458-64, (2003)

Reactions of 2,3-diferrocenylcyclopropenone 1 with ethyl- and benzylmagnesium chlorides afford 3,3-diethyl-and 3,3-dibenzyl- 1,2-diferrocenylcyclopropenes 2 and 3, respectively, and products of nucleo...

tetrachlorocyclopropene
N-[(diethyl-1,3-thiazol-2-yl)methyl]cyclopropanamine
1-butyl-4-hydrazinyl-1H-pyrazolo[3,4-d]pyrimidine
Methyl 2-(1,2-thiazol-3-yloxy)acetate
2-Amino-6-methoxy-5,6,7,8-tetrahydroquinoline-3-carbonitrile
2-Amino-6-tert-butyl-5,6,7,8-tetrahydro-1,6-naphthyridine-3-carbonitrile
4-(2,4,6-Trimethylphenyl)thiophene-2-carbaldehyde
5-(2,4,6-Trimethylphenyl)pyridine-2-carbaldehyde
6-(2,4,6-Trimethylphenyl)pyridine-3-carbaldehyde
4-Methyl-9-(2-methylbutan-2-yl)-2-azaspiro[4.5]decan-6-one
4-Methyl-2-azaspiro[4.6]undecan-6-one

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