2-Benzyloxyphenol

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Names

[ CAS No. ]:
6272-38-4

[ Name ]:
2-Benzyloxyphenol

[Synonym ]:
2-benzyloxy phenol
Phenol, 2-(phenylmethoxy)-
2-Benzyloxyphenol
2-(Benzyloxy)phenol
MFCD00002186
EINECS 228-461-5
Benzyl o-hydroxyphenyl ether

Chemical & Physical Properties

[ Density]:
1.143

[ Boiling Point ]:
335.5±17.0 °C at 760 mmHg

[ Melting Point ]:
35-40°C

[ Molecular Formula ]:
C13H12O2

[ Molecular Weight ]:
200.233

[ Flash Point ]:
183.9±5.9 °C

[ Exact Mass ]:
200.083725

[ PSA ]:
29.46000

[ LogP ]:
2.84

[ Vapour Pressure ]:
0.0±0.8 mmHg at 25°C

[ Index of Refraction ]:
1.591

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xi:Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
1

[ HS Code ]:
2909500000

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • Benzyl chloride
  • 1,2-Benzenediol
  • Benzyl bromide
  • (2-(Benzyloxy)phenyl)boronic acid
  • (2S,3R)-2,3-bis(benzyloxy)-5-hydroxycyclohexan-1-one
  • (3S,4S,5R,1'S)-3-bromo-5-(2'-bromo-1'-hydroxy)ethyl-4,5-dihydro-4-hydroxy-2-(3H)-furanone
  • methyl 2,6-dibromo-2,6-dideoxy-α-D-mannopyranoside
  • Salicylaldehyde
  • 2-(Benzyloxy)benzaldehyde

DownStream

  • 5-[[2-(4-hydroxyphenyl)ethylamino]methyl]-2-methoxy-phenol
  • 1-(2,3-Dihydro-1,4-benzodioxin-2-yl)methanamine
  • Dibenzo-30-crown 10-Ether
  • Phenol,2,2'-[oxybis(2,1-ethanediyloxy)]bis-
  • 4-Iodo-2-(phenylmethoxy)phenol
  • 2-phenylmethoxycyclohexa-2,5-diene-1,4-dione
  • 2,3-Dihydro-1,4-benzodioxin-2-ylmethanol
  • 2-Methoxyphenol-d3
  • o-Benzylisovanillin
  • 2-(2-methoxyethoxy)phenol

Customs

[ HS Code ]: 2909500000

[ Summary ]:
2909500000 ether-phenols, ether-alcohol-phenols and their halogenated, sulphonated, nitrated or nitrosated derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%

Articles

Hydroxylation activity of P450 BM-3 mutant F87V towards aromatic compounds and its application to the synthesis of hydroquinone derivatives from phenolic compounds.

Appl. Microbiol. Biotechnol. 67(4) , 556-62, (2005)

Cytochrome P450 BM-3 from Bacillus megaterium is a fatty acid hydroxylase exhibiting selectivity for long-chain substrates (12-20 carbons). Replacement of Phe87 in P450 BM-3 by Val (F87V) greatly incr...


More Articles

Related Compounds

  • 5-cyano-2-benzyloxyphenol
  • 3-methyl-2-benzyloxyphenol
  • 2-propenyl-4-benzyloxyphenol
  • 2-bromo-1-(3-phenylmethoxyphenyl)ethanone
  • 2-(4-tert-butylphenyl)phenol
  • 2-[5-Bromo-2-(hydroxymethyl)phenyl]ethanol
  • 5-(3-Chlorophenyl)-4-methyl-1,3-thiazole-2-carboxylic acid
  • N-(2-(2,4-dioxooxazolidin-3-yl)-1-phenylethyl)-2-(methylthio)benzamide
  • 1-Chloropyrrolo[1,2-a]pyrazine-7-carboxylic acid
  • 1-Chloropyrrolo[1,2-a]pyrazine-6-carboxylic acid
  • 6-Chloro-2,3-dihydro-1H-indene-4-carboxylic acid
  • 4-(1H-1,2,4-triazol-3-yl)oxane-4-carboxylic acid
  • 3-(4-acetamido-1H-pyrazol-1-yl)propanoic acid
  • 2-(2,3-Dihydro-1,4-benzodioxin-6-yl)-2-fluoroethan-1-amine
  • 2-(2,3-Dihydro-1,4-benzodioxin-5-yl)-2-fluoroethan-1-amine
  • 3-Amino-2-(2-fluoro-5-methylphenyl)propanoic acid
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