(R)-(-)-1,3-Butanediol

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Names

[ Name ]:
(R)-(-)-1,3-Butanediol

[Synonym ]:
1,3-Butanediol,(3R)-
(-)-1,3-Butanediol
MFCD00064277
1,3-Butanediol, (R)-
(3R)-Butane-1,3-diol
1,3-Butanediol, (R)-(-)-
(R)-(-)-1,3-Butanediol
1,3-Butanediol,(R)-
EINECS 228-532-0
1,3-Butanediol, (3R)-
(R)-1,3-Butanediol
(3R)-1,3-Butanediol
L-Butane-1,3-diol

Chemical & Physical Properties

[ Density]:
1.005

[ Boiling Point ]:
207.0±0.0 °C at 760 mmHg

[ Melting Point ]:
0ºC

[ Molecular Formula ]:
C₄H₁₀O₂

[ Molecular Weight ]:
90.121

[ Flash Point ]:
108 ºC

[ Exact Mass ]:
90.068077

[ PSA ]:
40.46000

[ LogP ]:
-0.69

[ Vapour density ]:
3.1 (vs air)

[ Vapour Pressure ]:
0.1±0.8 mmHg at 25°C

[ Index of Refraction ]:
1.438

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xi:Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S36

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ RTECS ]:
EK0440000

[ HS Code ]:
29053920

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

Ethyl (R)-3-hydroxybutyrate
4-Hydroxy-2-butanone
Methyl (R)-(-)-3-hydroxybutyrate
(2SR,4RS)-4-methyl-2-phenyl-1,3-dioxane
vinyl acetate
(R)-4-methyl-1,3-dioxan
(R)-3-Hydroxybutanoic acid
2,6-Dimethyl-1,3-dioxan-4-ol
(2R,6S,7S,10R)-7-isopropyl-2,10-dimethyl-1,5-dioxaspiro[5.5]undecane

DownStream

(2R)-4-trityloxybutan-2-ol
Ketone Ester

Customs

[ HS Code ]: 29053920

Articles

Asymmetric synthesis of (R)-1,3-butanediol from 4-hydroxy-2-butanone by a newly isolated strain Candida krusei ZJB-09162.

Appl. Microbiol. Biotechnol. 94(4) , 969-76, (2012)

Biocatalytic asymmetric preparation of (R)-1,3-butanediol has been attracting much attention in pharmaceuticals industry. A new ideal strain, ZJB-09162, which exhibited high reduction activity and exc...

Effect of adulteration versus storage on volatiles in unifloral honeys from different floral sources and locations.

J. Food Sci. 78(2) , C184-91, (2013)

High fructose corn syrup (HFCS) was added at 5% to 40% to Indiana wildflower honey and added at 40% to Ohio and Indiana honeys from blueberry, star thistle, clover and wildflower, and an unknown sourc...

Increasing analytical space in gas chromatography-differential mobility spectrometry with dispersion field amplitude programming.

J. Chromatogr. A. 1173(1-2) , 129-38, (2007)

Enhancing the analytical space of differential mobility spectrometry with dispersion field amplitude programming was proposed. Six volatile organic compound candidate breath markers, 1,3-butanediol, b...

(R)-(-)-1,3-BUTANEDIOL
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