Iodonium, diphenyl-, 4-methylbenzenesulfonate (9CI)

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Names

[ CAS No. ]:
6293-66-9

[ Name ]:
Iodonium, diphenyl-, 4-methylbenzenesulfonate (9CI)

[Synonym ]:
DPIpTS
diphenyliodonium p-toluenesulfonate
Toluol-4-sulfonsaeure,Diphenyljodonium-Salz
diphenyliodonium tosylate
Iodonium,p-toluenesulfonate
toluene-4-sulfonic acid,diphenyliodonium-salt
Diphenyliodonium 4-methylbenzenesulfonate
MFCD00467678
IODONIUM,DIPHENYL-,p-TOLUENESULFONATE

Chemical & Physical Properties

[ Melting Point ]:
188-191ºC(lit.)

[ Molecular Formula ]:
C19H17IO3S

[ Molecular Weight ]:
452.30600

[ Exact Mass ]:
451.99400

[ PSA ]:
65.58000

[ LogP ]:
1.79490

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
NN6670000
CHEMICAL NAME :
Iodonium, diphenyl-, p-toluenesulfonate
CAS REGISTRY NUMBER :
6293-66-9
LAST UPDATED :
198509
DATA ITEMS CITED :
1
MOLECULAR FORMULA :
C12-H10-I.C7-H7-O3-S

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intravenous
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
56 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. (Aberdeen Proving Ground, MD 21010) Volume(issue)/page/year: NX#01841

Safety Information

[ Personal Protective Equipment ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter

[ RIDADR ]:
NONH for all modes of transport

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • [Hydroxy(tosyloxy)iodo]benzene
  • benzene
  • Diphenyliodonium iodide
  • p-Toluenesulfonic acid
  • (p-chlorophenyl)phenyliodonium bromide
  • Diphenyliodonium chloride
  • Iodobenzene
  • Phenylboronic acid
  • Trimethyl(phenyl)silane
  • Tri-n-butylphenyltin

DownStream

  • 2-Propyn-1-one, 1,3-diphenyl-
  • Phenyl benzoate
  • Fluorobenzene
  • 2-(Phenylthio)ethanol
  • 1-Chloro-4-phenoxybenzene
  • 4-NITROPHENYL PHENYL ETHER
  • Benzenesulfonic acid,4-methyl-, phenyl ester
  • Diphenyl oxide
  • Diphenyl sulfone
  • 1-cyclohexyl-3-phenylprop-2-yn-1-one

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Related Compounds

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  • 1-Amino-3-(2,5-dimethoxyphenyl)propan-2-ol
  • 2-Methoxy-6-(pyrazol-1-yl)-benzonitrile
  • 1H-3-Benzazepin-7-ol, 8-chloro-2,3,4,5-tetrahydro-5-(3-iodophenyl)-3-methyl-, (S)-
  • (4-Methyl-tetrahydro-furan-2-yl)-methanol
  • N-(1-cyanocyclopentyl)-2-[4-(4-fluorobenzenesulfonyl)-1,4-diazepan-1-yl]acetamide
  • 4,5,6,7-Tetrahydrobenzo[d]isoxazole-3-carbaldehyde
  • tert-Butyl-DL-alanine
  • 2,2-Dimethyl-3-(1,3-thiazol-2-yl)propan-1-amine