2-HYDROXY-1,3,2-BENZODIOXASTIBOLE

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Names

[ CAS No. ]:
6295-12-1

[ Name ]:
2-HYDROXY-1,3,2-BENZODIOXASTIBOLE

[Synonym ]:
Benzo[1,3,2]dioxastibol-2-ol
Monoantimon(III)-brenzcatechinat
Brenzcatechin,Antimon(III)-brenzcatechinat-hydroxid
pyrocatechol,antimony (III)-pyrocatecholate hydroxide
monoantimony(III) 1,2-dihydroxybenzene
1,3,2-BENZODIOXASTIBOLE,2-HYDROXY
Brenzcatechin
o-Phenylene antimonate(III)
2-Hydroxy-1,3,2-benzodioxastibole
Pyrocatechol,cyclic ester with antimonic acid (H3SbO3)
o-Phenylene antimonate(III),(C6H4O2)(HO)Sb
1,2-Benzodioxastibole,2-hydroxy

Chemical & Physical Properties

[ Boiling Point ]:
245.5ºC at 760 mmHg

[ Molecular Formula ]:
C6H5O3Sb

[ Molecular Weight ]:
246.86200

[ Flash Point ]:
137.2ºC

[ Exact Mass ]:
245.92800

[ PSA ]:
38.69000

[ LogP ]:
1.19600

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
DF4725000
CHEMICAL NAME :
1,3,2-Benzodioxastibole, 2-hydroxy-
CAS REGISTRY NUMBER :
6295-12-1
BEILSTEIN REFERENCE NO. :
3905238
LAST UPDATED :
199712
DATA ITEMS CITED :
27
MOLECULAR FORMULA :
C6-H5-O3-Sb
MOLECULAR WEIGHT :
246.86
WISWESSER LINE NOTATION :
T66 BO-SB-O EHJ CQ

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
62500 ug/kg
REFERENCE :
CBCCT* "Summary Tables of Biological Tests," National Research Council Chemical-Biological Coordination Center. (National Academy of Science Library, 2101 Constitution Ave., NW, Washington, DC 20418) Volume(issue)/page/year: 4,227,1952 *** REVIEWS *** ACGIH TLV-TWA 0.5 mg(Sb)/m3 DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 *** U.S. STANDARDS AND REGULATIONS *** MSHA STANDARD-air:TWA 0.5 mg(Sb)/m3 DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: 3,15,1971 OSHA PEL (Gen Indu):8H TWA 0.5 mg(Sb)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1910.1000,1994 OSHA PEL (Construc):8H TWA 0.5 mg(Sb)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1926.55,1994 OSHA PEL (Shipyard):8H TWA 0.5 mg(Sb)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1915.1000,1993 OSHA PEL (Fed Cont):8H TWA 0.5 mg(Sb)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 41,50-204.50,1994 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-ARAB Republic of Egypt:TWA 0.5 mg(Sb)/m3 JAN 1993 OEL-AUSTRALIA:TWA 0.5 mg(Sb)/m3 JAN 1993 OEL-AUSTRIA:TWA 0.5 mg(Sb)/m3 JAN 1993 OEL-BELGIUM:TWA 0.5 mg(Sb)/m3 JAN 1993 OEL-DENMARK:TWA 0.5 mg(Sb)/m3 JAN 1993 OEL-FINLAND:.TWA (0.5 mg(Sb)/m3) JAN 1993 OEL-FRANCE:TWA 0.5 mg(Sb)/m3 JAN 1993 OEL-GERMANY:TWA 0.5 mg(Sb)/m3 (total dust) JAN 1993 OEL-HUNGARY:STEL 0.5 mg(Sb)/m3 JAN 1993 OEL-THE NETHERLANDS:TWA 0.5 mg(Sb)/m3 JAN 1993 OEL-THE PHILIPPINES:TWA 0.5 mg(Sb)/m3 JAN 1993 OEL-POLAND:TWA 0.5 mg(Sb)/m3 JAN 1993 OEL-RUSSIA:TWA 0.2 mg(Sb)/m3;STEL 0.5 mg(Sb)/m3 JAN 1993 OEL-SWEDEN:TWA 0.5 mg(Sb)/m3 JAN 1993 OEL-SWITZERLAND:TWA 0.5 mg(Sb)/m3 JAN 1993 OEL-TURKEY:TWA 0.5 mg(Sb)/m3 JAN 1993 OEL-UNITED KINGDOM:TWA 0.5 mg(Sb)/m3 JAN 1993 OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGIH TLV *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH RECOMMENDED EXPOSURE LEVEL (REL) : NIOSH REL TO ANTIMONY-air:10H TWA 0.5 mg(Sb)/m3 REFERENCE : NIOSH* National Institute for Occupational Safety and Health, U.S. Dept. of Health, Education, and Welfare, Reports and Memoranda. Volume(issue)/page/year: DHHS #92-100,1992

Synthetic Route

Precursor & DownStream

Precursor

  • Antimony trichloride
  • 1,2-Benzenediol

DownStream


Related Compounds

  • 2-Hydroxy-1,3,2-dioxaphospholane 2-oxide
  • tetrasodium,2-(2-hydroxy-3,5-disulfonatophenoxy)-1,3,2-benzodioxastibole-4,6-disulfonate
  • 1,3,2-Benzodioxastibol-4-ol,2-hydroxy-
  • 9-((2-hydroxy-1,3,2-dioxaphosphorinan-5-yl)oxymethyl)guanine P-oxide
  • Ethylene phosphite
  • 2-hydroxy-1,3-dinitroanthraquinone