4-AMINO-3-METHYLBIPHENYL

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Names

[ CAS No. ]:
63019-98-7

[ Name ]:
4-AMINO-3-METHYLBIPHENYL

[Synonym ]:
4-BIPHENYLAMINE,3-METHYL
3-methyl-biphenyl-4-ylamine
3-Methyl-4-aminodiphenyl
4-Amino-3-methylbiphenyl
3-methylbiphenyl-4-amine
3-methyl-(1,1'-biphenyl)-4-amine
3-Methyl-4-aminobiphenyl
3-Methyl-biphenyl-4-ylamin
2-methyl-4-phenyl-aniline
4-Amino-3-methyl-diphenyl

Chemical & Physical Properties

[ Density]:
1.057g/cm3

[ Boiling Point ]:
312.1ºC at 760 mmHg

[ Melting Point ]:
38-39ºC

[ Molecular Formula ]:
C13H13N

[ Molecular Weight ]:
183.24900

[ Flash Point ]:
151ºC

[ Exact Mass ]:
183.10500

[ PSA ]:
26.02000

[ LogP ]:
3.82540

[ Index of Refraction ]:
1.607

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
DV0175000
CHEMICAL NAME :
4-Biphenylamine, 3-methyl-
CAS REGISTRY NUMBER :
63019-98-7
BEILSTEIN REFERENCE NO. :
2802968
LAST UPDATED :
199612
DATA ITEMS CITED :
2
MOLECULAR FORMULA :
C13-H13-N
MOLECULAR WEIGHT :
183.27
WISWESSER LINE NOTATION :
ZR B1 DR

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Subcutaneous
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
1200 mg/kg/W-I
TOXIC EFFECTS :
Tumorigenic - equivocal tumorigenic agent by RTECS criteria Sense Organs and Special Senses (Ear) - effect, not otherwise specified Gastrointestinal - tumors
REFERENCE :
BMBUAQ British Medical Bulletin. (Longman Group UK Ltd., Longman House, Burnt Mill, Harlow, Essex CM20 2JE, UK) V.1- 1943- Volume(issue)/page/year: 14,141,1958
TYPE OF TEST :
TD - Toxic dose (other than lowest)
ROUTE OF EXPOSURE :
Subcutaneous
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
1600 mg/kg
TOXIC EFFECTS :
Tumorigenic - equivocal tumorigenic agent by RTECS criteria Gastrointestinal - tumors
REFERENCE :
AICCA6 Acta Unio Internationalis Contra Cancrum. (Louvain, Belgium) V.1-20, 1936-64. For publisher information, see IJCNAW. Volume(issue)/page/year: 10,174,1954

Safety Information

[ Hazard Codes ]:
Xi

[ HS Code ]:
2921499090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • 4-Bromo-2-methylaniline
  • Phenylboronic acid
  • 4-Iodo-2-methylaniline
  • 3METHYL4NITROBIPHENYL
  • 4'-Phenyl-o-acetotoluide
  • O-ACETOTOLUIDIDE
  • 4'-bromo-2'-methylacetanilide
  • N-chloro-2'-methylacetanilide
  • benzene
  • 3-Phenyltoluene

DownStream

  • 4'-Phenyl-o-acetotoluide

Customs

[ HS Code ]: 2921499090

[ Summary ]:
2921499090 other aromatic monoamines and their derivatives; salts thereof VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

Related Compounds

  • 4-amino-3-methylbiphenyl hydrochloride
  • 4-amino-3-methylbiphenyl hydrochloride
  • 4-Amino-3-methylbiphenyl-2’,3’,4’,5’,6’-d5
  • 4-Amino-3-methoxybenzamide
  • 4-amino-3-(4-amino-phenyl)-naphthalene-1-sulfonic acid
  • 4-Amino-3-chloro-8-methylquinoline
  • 3-Bromo-8-fluoroquinolin-5-amine
  • 2-[(1-Methylcyclopentyl)oxy]-1,3-thiazol-5-amine
  • 2-(Cyclobutylmethoxy)-1,3-thiazol-5-amine
  • 2,2,4-Trimethyl-1,9-dioxa-5-azaspiro[5.6]dodecane
  • 8-Tert-butyl-2,2-dimethyl-6-oxa-10-azaspiro[4.5]decane
  • 2-({1-[({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)methyl]cyclopentyl}formamido)hex-4-ynoic acid
  • 2-({2-[({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)methyl]-1,3-thiazol-4-yl}formamido)hex-4-ynoic acid
  • 1-{[(3R)-3-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)butanamido]methyl}spiro[2.3]hexane-1-carboxylic acid
  • 1-{[(2R,3S)-3-(benzyloxy)-2-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)butanamido]methyl}spiro[2.3]hexane-1-carboxylic acid
  • rac-2-{1-[(1R,5S)-5-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)cyclohex-3-ene-1-carbonyl]pyrrolidin-3-yl}acetic acid
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