Difluoro-4-morpholinylsulfonium tetrafluoroborate

[ Melting Point ]:
117-126°C (lit.)

[ Molecular Formula ]:
C₄H₈BF₆NOS

[ Molecular Weight ]:
242.97900

[ Exact Mass ]:
243.03200

[ PSA ]:
37.77000

[ LogP ]:
1.85880

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[ Symbol ]:

GHS05, GHS06

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H301 + H311 + H331-H314

[ Precautionary Statements ]:
P261-P280-P301 + P310-P305 + P351 + P338-P310

[ Hazard Codes ]:
T

[ Risk Phrases ]:
R23/24/25;R34

[ Safety Phrases ]:
S26;S36/37/39;S45

[ RIDADR ]:
UN 3290 6.1/PG 2

Aminodifluorosulfinium tetrafluoroborate salts as stable and crystalline deoxofluorinating reagents.

Org. Lett. 11 , 5050, (2009)

Aminodifluorosulfinium tetrafluoroborate salts were found to act as efficient deoxofluorinating reagents when promoted by an exogenous fluoride source and, in most cases, exhibited greater selectivity...

Aminodifluorosulfinium salts: selective fluorination reagents with enhanced thermal stability and ease of handling.

J. Org. Chem. 75 , 3401, (2010)

Diethylaminodifluorosulfinium tetrafluoroborate (XtalFluor-E) and morpholinodifluorosulfinium tetrafluoroborate (XtalFluor-M) are crystalline fluorinating agents that are more easily handled and signi...

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