Arsine, oxophenyl-

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Names

[ CAS No. ]:
637-03-6

[ Name ]:
Arsine, oxophenyl-

[Synonym ]:
Arsine, oxophenyl-
EINECS 211-275-3
Oxo(phenyl)arsine
Phenylarsine oxide
oxo(phenyl)arsane
arsorosobenzene
Phenyl arsenoxide
MFCD00001990

Chemical & Physical Properties

[ Density]:
1

[ Boiling Point ]:
100ºC

[ Melting Point ]:
145-148 °C

[ Molecular Formula ]:
C6H5AsO

[ Molecular Weight ]:
168.025

[ Exact Mass ]:
167.955643

[ PSA ]:
17.07000

[ LogP ]:
0.47410

[ Appearance of Characters ]:
powder | white to yellow

[ Storage condition ]:
Poison room

[ Stability ]:
Stable.

[ Water Solubility ]:
DMSO: 50 mg/mL

MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
CH8100000
CHEMICAL NAME :
Arsine, oxophenyl-
CAS REGISTRY NUMBER :
637-03-6
BEILSTEIN REFERENCE NO. :
2935227
LAST UPDATED :
199710
DATA ITEMS CITED :
12
MOLECULAR FORMULA :
C6-H5-As-O
MOLECULAR WEIGHT :
168.03
WISWESSER LINE NOTATION :
O-AS-R

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
1930 ug/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
JPETAB Journal of Pharmacology and Experimental Therapeutics. (Williams & Wilkins Co., 428 E. Preston St., Baltimore, MD 21202) V.1- 1909/10- Volume(issue)/page/year: 74,210,1942
TYPE OF TEST :
LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE :
Intravenous
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
1570 ug/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
PHBUA9 Pharmaceutical Bulletin. (Tokyo, Japan) V.1-5, 1953-57. For publisher information, see CPBTAL. Volume(issue)/page/year: 2,19,1954
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Unreported
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
1900 ug/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
JPETAB Journal of Pharmacology and Experimental Therapeutics. (Williams & Wilkins Co., 428 E. Preston St., Baltimore, MD 21202) V.1- 1909/10- Volume(issue)/page/year: 70,221,1940
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intravenous
SPECIES OBSERVED :
Rodent - rabbit
DOSE/DURATION :
790 ug/kg
TOXIC EFFECTS :
Nutritional and Gross Metabolic - weight loss or decreased weight gain
REFERENCE :
JPETAB Journal of Pharmacology and Experimental Therapeutics. (Williams & Wilkins Co., 428 E. Preston St., Baltimore, MD 21202) V.1- 1909/10- Volume(issue)/page/year: 69,342,1940 *** U.S. STANDARDS AND REGULATIONS *** OSHA PEL (Gen Indu):8H TWA 0.5 mg(As)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1910.1000,1994 OSHA PEL (Construc):8H TWA 0.5 mg(As)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1926.55,1994 OSHA PEL (Shipyard):8H TWA 0.5 mg(As)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1915.1000,1993 OSHA PEL (Fed Cont):8H TWA 0.5 mg(As)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 41,50-204.50,1994 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - M1555 No. of Facilities: 191 (estimated) No. of Industries: 10 No. of Occupations: 16 No. of Employees: 5958 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - M1555 No. of Facilities: 606 (estimated) No. of Industries: 7 No. of Occupations: 6 No. of Employees: 1922 (estimated) No. of Female Employees: 695 (estimated)

Safety Information

[ Symbol ]:

GHS06, GHS09

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H301 + H331-H410

[ Precautionary Statements ]:
P261-P273-P301 + P310-P311-P501

[ Hazard Codes ]:
T:Toxic;N:Dangerousfortheenvironment;

[ Risk Phrases ]:
R23/25;R50/53

[ Safety Phrases ]:
S20/21-S28-S45-S60-S61

[ RIDADR ]:
UN 3465 6.1/PG 3

[ WGK Germany ]:
3

[ RTECS ]:
CH8100000

[ Packaging Group ]:
III

[ Hazard Class ]:
6.1

Synthetic Route

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Related Compounds

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  • Arsine,As,As'-1,2-phenylenebis[As,As-dimethyl-
  • ARSINE OXIDE, 2-CHLOROVINYL-
  • Arsine oxide,triphenyl-
  • Arsine,tris(2-methylphenyl)-
  • Arsine, silyl-
  • (3S)-4-(2,3-dihydro-1-benzofuran-5-yl)-3-hydroxybutanoic acid
  • 3-(4-Chlorothiophen-2-yl)-1,2-oxazole-5-carboxylic acid
  • 1-[3-(difluoromethyl)-1-methyl-1H-pyrazol-4-yl]cyclopentane-1-carboxylic acid
  • 2-[1-(1,1,2,2-Tetrafluoroethyl)cyclobutyl]acetic acid
  • 3-(2,5-Dimethylthiophen-3-yl)-2-methoxypropanoic acid
  • 1-methyl-3-(4-methyl-1,3-thiazol-5-yl)-1H-pyrazole-5-carboxylic acid
  • rac-(1R,3R)-3-[(ethylsulfanyl)methyl]-2,2-dimethylcyclopropane-1-carboxylic acid
  • 3-(1-ethyl-1H-imidazol-5-yl)-2-methoxypropanoic acid
  • 3-(4-Chloro-2-hydroxyphenyl)-3,3-difluoropropanoic acid
  • Tert-butyl 2-(2,4,6-trifluorophenyl)piperazine-1-carboxylate
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