Ethyl azidoacetate

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Names

[ CAS No. ]:
637-81-0

[ Name ]:
Ethyl azidoacetate

[Synonym ]:
ethyl 2-azidoacetate
Acetic acid, 2-azido-, ethyl ester
Ethyl azidoacetate
EINECS 211-301-3
MFCD00190177

Chemical & Physical Properties

[ Density]:
1.127 g/mL at 25ºC

[ Boiling Point ]:
44-46°C 2mm

[ Molecular Formula ]:
C4H7N3O2

[ Molecular Weight ]:
129.117

[ Flash Point ]:
25 °C

[ Exact Mass ]:
129.053833

[ PSA ]:
76.05000

[ LogP ]:
0.83

[ Index of Refraction ]:
1.43

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
AF4340000
CHEMICAL NAME :
Acetic acid, azido-, ethyl ester
CAS REGISTRY NUMBER :
637-81-0
LAST UPDATED :
199612
DATA ITEMS CITED :
1
MOLECULAR FORMULA :
C4-H7-N3-O2
MOLECULAR WEIGHT :
129.14

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

MUTATION DATA

TYPE OF TEST :
Mutation in microorganisms
TEST SYSTEM :
Bacteria - Salmonella typhimurium
DOSE/DURATION :
20 umol/plate
REFERENCE :
MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 216,27,1989

Safety Information

[ Symbol ]:

GHS08

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H351

[ Precautionary Statements ]:
P281

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xn

[ Risk Phrases ]:
R1;R11;R38;R48/20;R63;R65;R67

[ Safety Phrases ]:
S7-S16-S26-S35-S36-S47-S62-S45-S36/37

[ RIDADR ]:
UN 1593 6.1/PG 3

[ WGK Germany ]:
2

[ HS Code ]:
2929909090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • ethyl 2-bromoacetate
  • ethyl chloroacetate
  • Glycine ethyl ester hydrochloride
  • Ethyl iodoacetate
  • Azidotrimethylsilane
  • Acetic acid,2-[(methylsulfonyl)oxy]-, ethyl ester
  • (N-nitroso-hydrazino)-acetic acid ethyl ester
  • Ethyl glycinate

DownStream

  • 3-Bromo-4H-thieno[3,2-b]pyrrole-5-carboxylic acid
  • Ethyl imidazo[1,2-a]pyridine-2-carboxylate
  • ethyl 2-azido-3-(imidazo[1,2-a]pyridin-2-yl)propenoate
  • Ethyl 4H-thieno[3,2-b]pyrrole-5-carboxylate
  • Ethyl glycinate
  • Acetamide, 2-azido-
  • Ethyl 2-(4-cyano-1H-1,2,3-triazol-1-yl)acetate
  • 2-azidoacetic acid
  • 2-CARBETHOXY-4-BENZYLOXYINDOLE
  • ethyl α-azido-β-(imidazo[1,2-a]pyridin-8-yl)propenoate

Customs

[ HS Code ]: 2929909090

[ Summary ]:
2929909090 other compounds with other nitrogen function VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

Related Compounds

  • ethyl 8-(4-fluorophenyl)-8-oxooctanoate
  • ETHYL 4-(3,4-DIMETHYLPHENYL)-4-OXOBUTYRATE
  • ETHYL 8-(1-NAPHTHYL)-8-OXOOCTANOATE
  • ethyl 3-(3-nitrophenyl)-4-oxopent-2-enoate
  • ETHYL 2-((TERT-BUTOXYCARBONYL)AMINO)THIAZOLE-5-CARBOXYLATE
  • ETHYL 5-OXO-5-(4-TRIFLUOROMETHYLPHENYL)VALERATE