Manganese(II) acetate

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Names

[ CAS No. ]:
638-38-0

[ Name ]:
Manganese(II) acetate

[Synonym ]:
manganousacetate
octanmanganaty
Manganese(2+) diacetate
manganesediacetate
manganese acetate
MFCD00013039
Acetic acid, manganese(2+) salt (2:1)
manganese(ii) acetate
EINECS 211-334-3
manganese(2+) acetate
diacetylmanganese

Chemical & Physical Properties

[ Density]:
1.589

[ Boiling Point ]:
117.1ºC at 760 mmHg

[ Melting Point ]:
180°C

[ Molecular Formula ]:
C4H6MnO4

[ Molecular Weight ]:
173.026

[ Flash Point ]:
40ºC

[ Exact Mass ]:
172.964661

[ PSA ]:
52.60000

[ LogP ]:
0.02760

MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
AI5770000
CAS REGISTRY NUMBER :
638-38-0
LAST UPDATED :
199712
DATA ITEMS CITED :
23
MOLECULAR FORMULA :
C4-H6-O4.Mn
MOLECULAR WEIGHT :
173.04
WISWESSER LINE NOTATION :
OV1 2 &-MN-

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
2940 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value

MUTATION DATA

TYPE OF TEST :
DNA repair
TEST SYSTEM :
Bacteria - Bacillus subtilis
DOSE/DURATION :
50 mmol/L
REFERENCE :
MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 31,185,1975 *** REVIEWS *** ACGIH TLV-TWA 0.2 mg(Mn)/m3 DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 *** U.S. STANDARDS AND REGULATIONS *** MSHA STANDARD-air:CL 5 mg(Mn)/m3 DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: 3,149,1971 OSHA PEL (Gen Indu):CL 5 mg(Mn)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1910.1000,1994 OSHA PEL (Construc):CL 5 mg(Mn)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1926.55,1994 OSHA PEL (Shipyard):CL 5 mg(Mn)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1915.1000,1993 OSHA PEL (Fed Cont):CL 5 mg(Mn)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 41,50-204.50,1994 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-AUSTRALIA:TWA 5 mg(Mn)/m3 JAN 1993 OEL-BELGIUM:TWA 5 mg(Mn)/m3 JAN 1993 OEL-DENMARK:TWA 2.5 mg(Mn)/m3 JAN 1993 OEL-FINLAND:TWA 2.5 mg(Mn)/m3 JAN 1993 OEL-HUNGARY:TWA 0.3 mg(Mn)/m3;STEL 0.6 mg(Mn)/m3 JAN 1993 OEL-JAPAN:TWA 0.3 mg(Mn)/m3 JAN 1993 OEL-THE NETHERLANDS:TWA 1 mg(Mn)/m3 JAN 1993 OEL-POLAND:TWA 0.3 mg(Mn)/m3 JAN 1993 OEL-SWEDEN:TWA 1 mg(Mn)/m3;STEL 2.5 mg(Mn)/m3 (resp. dust) JAN 1993 OEL-SWEDEN:TWA 2.5 mg(Mn)/m3;STEL 5 mg(Mn)/m3 (total dust) JAN 1993 OEL-UNITED KINGDOM:TWA 5 mg(Mn)/m3 JAN 1993 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - 84621 No. of Facilities: 88 (estimated) No. of Industries: 2 No. of Occupations: 5 No. of Employees: 1178 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - 84621 No. of Facilities: 33 (estimated) No. of Industries: 2 No. of Occupations: 3 No. of Employees: 1283 (estimated) No. of Female Employees: 241 (estimated)

Safety Information

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xn

[ Risk Phrases ]:
R20/21/22

[ Safety Phrases ]:
S26-S27-S36/37/39

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ RTECS ]:
AI5770000

[ HS Code ]:
2915299090

Synthetic Route

Precursor & DownStream

Precursor

  • Manganese
  • Manganese acetate tetrahydrate
  • Ethanoic anhydride
  • acetic acid
  • Manganese(3+) tris(4-oxo-2-penten-2-olate)
  • Manganese(II) acetate
  • Acetone Semicarbazone
  • Hydrazinecarboxamide,2-(phenylmethylene)-
  • [(4-chlorophenyl)methylideneamino]urea
  • Hydrazinecarboxamide,2-[(4-nitrophenyl)methylene]-

DownStream

  • manganese(iii) acetate meso-tetraphenylporphine
  • 2-Acetoxy-3-butanone
  • Methylbenzylalcohol
  • Acetophenone
  • 9-Anthracenol,9-acetate
  • Anthraquinone
  • (4-oxo-2,3-dihydrochromen-3-yl) acetate
  • manganese(2+),propanoate
  • 2-Pentanone,5-(acetyloxy)-
  • decane-2,9-dione

Customs

[ HS Code ]: 2915299090

[ Summary ]:
2915299090 salts of acetic acid。supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward)。VAT:17.0%。tax rebate rate:9.0%。MFN tariff:5.5%。general tariff:50.0%


Related Compounds

  • manganese(ii) acetate tetrahydrate
  • (bis-(3-methoxy)salicylaldehyde-ethylenediimine)manganese(II) acetate
  • 1,4,8,11,15,18,25-octapentylthiophthalocyaninato manganese(II) acetate(1-)
  • manganese(3+) acetate
  • manganese(II) monochloroacetate
  • manganese(II) (2,4-dichlorophenoxyacetate)2