Pentyl formate

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Names

[ CAS No. ]:
638-49-3

[ Name ]:
Pentyl formate

[Synonym ]:
m-Pentyl formate
MFCD00040440
Amyl methanoate
n-Amyl formate
N-PENTYL FORMATE
Formic acid, pentyl ester
pentyl formic acid ester
Pentyl methanoate
Formic acid,pentyl ester
formiate de n-pentyle
Amyl formate
n-Pentyl methanoate
EINECS 211-340-6

Chemical & Physical Properties

[ Density]:
0.9±0.1 g/cm3

[ Boiling Point ]:
132.4±3.0 °C at 760 mmHg

[ Melting Point ]:
-73.5ºC

[ Molecular Formula ]:
C6H12O2

[ Molecular Weight ]:
116.158

[ Flash Point ]:
31.9±4.4 °C

[ Exact Mass ]:
116.083733

[ PSA ]:
26.30000

[ LogP ]:
1.89

[ Vapour Pressure ]:
8.9±0.2 mmHg at 25°C

[ Index of Refraction ]:
1.399

MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
LQ9370000
CHEMICAL NAME :
Formic acid, pentyl ester
CAS REGISTRY NUMBER :
638-49-3
BEILSTEIN REFERENCE NO. :
1743363
LAST UPDATED :
199710
DATA ITEMS CITED :
9
MOLECULAR FORMULA :
C6-H12-O2
MOLECULAR WEIGHT :
116.18
WISWESSER LINE NOTATION :
VHO5

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
Standard Draize test
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
REFERENCE :
FCTXAV Food and Cosmetics Toxicology. (London, UK) V.1-19, 1963-81. For publisher information, see FCTOD7. Volume(issue)/page/year: 18,649,1980 ** ACUTE TOXICITY DATA **
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
>5 gm/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
FCTXAV Food and Cosmetics Toxicology. (London, UK) V.1-19, 1963-81. For publisher information, see FCTOD7. Volume(issue)/page/year: 18,649,1980
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
DOSE/DURATION :
>5 gm/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
FCTXAV Food and Cosmetics Toxicology. (London, UK) V.1-19, 1963-81. For publisher information, see FCTOD7. Volume(issue)/page/year: 18,649,1980
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Mammal - species unspecified
DOSE/DURATION :
6300 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 32(10),25,1988
TYPE OF TEST :
LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Mammal - species unspecified
DOSE/DURATION :
14 gm/m3
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
GISAAA Gigiena i Sanitariya. For English translation, see HYSAAV. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1- 1936- Volume(issue)/page/year: 51(5),61,1986 *** REVIEWS *** TOXICOLOGY REVIEW AMIHAB AMA Archives of Industrial Health. (Chicago, IL) V.11-21, 1955-60. For publisher information, see AEHLAU. Volume(issue)/page/year: 20,517,1959 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-RUSSIA:STEL 10 mg/m3;Skin JAN 1993

Safety Information

[ Symbol ]:

GHS02, GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H226-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi

[ Risk Phrases ]:
10-36/37

[ Safety Phrases ]:
S24

[ RIDADR ]:
UN 1109 3/PG 3

[ WGK Germany ]:
2

[ RTECS ]:
LQ9370000

[ Packaging Group ]:
III

[ Hazard Class ]:
3.2

[ HS Code ]:
2915120000

Synthetic Route

Precursor & DownStream

Precursor

  • pentanol
  • Ethyl formate
  • Formic Acid
  • Pent-1-ene
  • Levulinic acid
  • 1-Chloropentane
  • Sodium formate
  • Rh(tetramesitylporphyrinato dianion)
  • pentyl ether
  • Hexanal

DownStream

  • Pentylsulfate
  • pentyl 3,5-dinitrobenzoate
  • 3-Methylbutyl (2E)-3-phenylacrylate
  • Amyl phenylacetate
  • pentanol
  • pentyl 3-phenylpropanoate
  • Pentane
  • 6-Bromo-5-methyl-1H-imidazo[4,5-b]pyridine
  • Formamide, N-phenyl-
  • Benzoic acid,4-hydroxy-, pentyl ester

Customs

[ HS Code ]: 2915120000

[ Summary ]:
2915120000 salts of formic acid。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:5.5%。General tariff:30.0%


Related Compounds

  • 3-PENTYL FORMATE
  • 2-pentyl formate
  • tert-pentyl formate
  • pentyl (E)-3-(2,4-dichlorophenoxy)prop-2-enoate
  • pentyl 3-[dichloro-(3-oxo-3-pentoxypropyl)stannyl]propanoate
  • pentyl 2-cyano-3-ethoxyprop-2-enoate
  • 4-((Cyclohexylamino)methyl)benzoic acid hydrochloride
  • 1-[(2,4-Dichlorophenyl)methyl]-N-(1,1-dimethylethyl)-2-methyl-1H-indole-3-methanamine
  • 2-Methoxy-6-(pyrazol-1-yl)-benzonitrile
  • 1H-3-Benzazepin-7-ol, 8-chloro-2,3,4,5-tetrahydro-5-(3-iodophenyl)-3-methyl-, (S)-
  • (4-Methyl-tetrahydro-furan-2-yl)-methanol
  • N-(1-cyanocyclopentyl)-2-[4-(4-fluorobenzenesulfonyl)-1,4-diazepan-1-yl]acetamide
  • 4,5,6,7-Tetrahydrobenzo[d]isoxazole-3-carbaldehyde
  • 1-(5-Chloro-2-hydroxyphenyl)-2-(methylamino)ethan-1-one
  • Tert-butyl 2-(5-fluoropyridin-3-yl)piperazine-1-carboxylate
  • tert-Butyl-DL-alanine