Triphenylphosphine hydrobromide (1:1)

Names

[ Name ]:
Triphenylphosphine hydrobromide (1:1)

[Synonym ]:
MFCD00035107
phosphine, triphenyl-, hydrobromide
EINECS 229-012-6
triphenylphosphane,hydrobromide
Triphenylphosphine hydrobromide (1:1)
Phosphine, triphenyl-, hydrobromide (1:1)

Chemical & Physical Properties

[ Boiling Point ]:
360ºC at 760 mmHg

[ Melting Point ]:
196 °C (dec.)(lit.)

[ Molecular Formula ]:
C₁₈H₁₆BrP

[ Molecular Weight ]:
343.197

[ Flash Point ]:
181.7ºC

[ Exact Mass ]:
342.017303

[ PSA ]:
13.59000

[ LogP ]:
4.40290

[ Storage condition ]:
-20°C

MSDS

Safety Information

[ Symbol ]:

GHS05, GHS07

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H302-H314

[ Precautionary Statements ]:
P280-P305 + P351 + P338-P310

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges

[ Hazard Codes ]:
C:Corrosive;

[ Risk Phrases ]:
R34

[ Safety Phrases ]:
S26-S36/37/39-S45

[ RIDADR ]:
UN 3261 8/PG 3

[ WGK Germany ]:
3

[ Packaging Group ]:
III

[ Hazard Class ]:
6.1

[ HS Code ]:
29310095

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

Triphenylphosphine
2-Bromo-2-methylpropane
(2-butyl)triphenylphosphonium bromide
2,3-dihydro-1H-inden-1-yl(triphenyl)phosphanium,bromide

DownStream

2-(Triphenylphosphoranylidene)butanedioic acid dimethyl ester
3-Bromo-4-methoxybenzaldehyde
(2-hydroxyethyl)triphenylphosphonium bromide
4-(Benzyloxy)benzaldehyde
Methyltriphenylphosphonium bromide
2,3-dihydro-1H-inden-1-yl(triphenyl)phosphanium,bromide
(4-methoxyphenyl)methylidene-triphenyl-λ5-phosphane
naphthal
2,6-Dichlorobenzaldehyde

Customs

[ HS Code ]: 2902909090

[ Summary ]:
2902909090 other aromatic hydrocarbons。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:2.0%。General tariff:30.0%

Articles

Microwave-assisted synthesis of cyclopentanones using the relevant phosphorus ylides.

Comb. Chem. High Throughput Screen 15(4) , 354-7, (2012)

A one-pot synthesis of cyclopentanone derivatives from phosphorus ylide under lab-type microwave assisted methodology was described. The phosphorus ylides were obtained via the reaction of activated a...

Solubilization of triphenylamine, triphenylphosphine, triphenylphosphineoxide and triphenylmethanol in single and binary surfactant systems.

J. Colloid. Interface Sci. 364(1) , 163-9, (2011)

Solubilization and co-solubilization of triphenyls (TPs) viz., triphenylphosphine (TPP), triphenylphosphineoxide (TPPO), triphenylamine (TPA) and triphenylmethanol (TPM) were studied in various single...

Mixed ligand-silver(I) complexes with anti-inflammatory agents which can bind to lipoxygenase and calf-thymus DNA, modulating their function and inducing apoptosis.

Metallomics 4(6) , 545-60, (2012)

A new mixed ligand-silver(I) complex of formula [Ag(tpp)(2)(p-Hbza)] (1) (p-HbzaH = 4-hydroxybenzoic acid and tpp = triphenylphosphine) has been synthesized and characterized by elemental analysis, mp...

Formamidinium Bromide
Borane-triphenylphosphine (1:1)
Triphenylborane-triphenylphosphine (1:1)
1H-Pyrazole,hydrobromide (1:1)
2-Imidazolidinethione,hydrobromide (1:1)
4-Fluoropiperidine hydrobromide (1:1)
1-[1-(2,2-Difluoropropoxy)-2-iodoethyl]-4-fluorobenzene
4-(chloromethyl)-1-(1-cyclopropylethyl)-5-(trifluoromethyl)-1H-1,2,3-triazole
4-(chloromethyl)-1-(1-cyclobutylethyl)-5-(trifluoromethyl)-1H-1,2,3-triazole
4-(chloromethyl)-1-(cyclopropylmethyl)-5-(difluoromethyl)-1H-1,2,3-triazole
1-butyl-4-(chloromethyl)-5-(3-methylbutyl)-1H-1,2,3-triazole
4-(chloromethyl)-1-cyclopropyl-5-(3-methylbutyl)-1H-1,2,3-triazole
4-(chloromethyl)-5-cyclobutyl-1-cyclopentyl-1H-1,2,3-triazole
4-(chloromethyl)-5-(cyclopropylmethyl)-1-(3-methylbutan-2-yl)-1H-1,2,3-triazole
4-(chloromethyl)-1-(3-methylbutan-2-yl)-5-propyl-1H-1,2,3-triazole
4-(chloromethyl)-1-(2-cyclobutylethyl)-5-propyl-1H-1,2,3-triazole

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