bis(dimethylphosphino)methane

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Names

[ CAS No. ]:
64065-08-3

[ Name ]:
bis(dimethylphosphino)methane

[Synonym ]:
MFCD00058731
dmpm

Chemical & Physical Properties

[ Density]:
0.86 g/mL at 25ºC(lit.)

[ Boiling Point ]:
42ºC12 mm Hg(lit.)

[ Molecular Formula ]:
C5H14P2

[ Molecular Weight ]:
136.11200

[ Flash Point ]:
42°C/12mm

[ Exact Mass ]:
136.05700

[ PSA ]:
27.18000

[ LogP ]:
2.42690

[ Appearance of Characters ]:
Liquid | Colorless

[ Index of Refraction ]:
n20/D 1.5060(lit.)

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS02

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H250

[ Precautionary Statements ]:
P222-P231-P422

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
F

[ Risk Phrases ]:
R17

[ Safety Phrases ]:
S16-S29-S36-S37-S39

[ RIDADR ]:
UN 2845 4.2/PG 1

[ WGK Germany ]:
3

[ Packaging Group ]:
I

[ Hazard Class ]:
4.2

[ HS Code ]:
2901100000

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • Dichloromethane
  • N-TRIPHENYLMETHYL-5-(4-BROMOMETHYLBIPHENYL-2-YL) TETRAZOLE
  • lithium dimethylphosphide
  • (chloromethyl)dimethylphosphane
  • bis(dichlorophosphino)methane
  • Methylmagnesium chloride
  • lithium,methanidyl(dimethyl)phosphane
  • Dimethylchlorophosphine
  • bis(diphenoxyphosphino)methane
  • methyl iodide

DownStream

  • Norbornadiene
  • lithium,[dimethylphosphanyl(trimethylsilyl)methyl]-dimethylphosphane
  • Trimethylphosphine
  • molybdenum-bis-ethylen(PMe3)2(Me2PCH2PMe2)
  • Methylenebis(trimethylsilane)
  • bis(dimethylphosphino)methyl anion

Customs

[ HS Code ]: 2901100000

[ Summary ]:
2901100000 saturated acyclic hydrocarbons。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:2.0%。General tariff:30.0%

Articles

Anti-tumor activity of selective inhibitors of XPO1/CRM1-mediated nuclear export in diffuse malignant peritoneal mesothelioma: the role of survivin.

Oncotarget 6 , 13119-32, (2015)

Survivin, which is highly expressed and promotes cell survival in diffuse malignant peritoneal mesothelioma (DMPM), exclusively relies on exportin 1 (XPO1/CRM1) to be shuttled into the cytoplasm and p...


More Articles

Related Compounds

  • PdMe2(bis(dimethylphosphino)methane)
  • Ir2(CO)4(bis(dimethylphosphino)methane)2
  • Pd2I2(μ-S)(bis(dimethylphosphino)methane)2
  • Ir2(μ-CO3)(CO)2{bis(dimethylphosphino)methane}2
  • bis(dimethylphosphino)methyl anion
  • Bis(dimethylphosphino)(trimethylsilyl)methan
  • 1-(4-Methoxyphenyl)-1-(4-morpholinophenyl)prop-2-yn-1-ol
  • Unii-cwu44OX3IG
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