TBS-Corey Lactone Aldehyde

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Names

[ CAS No. ]:
64091-14-1

[ Name ]:
TBS-Corey Lactone Aldehyde

[Synonym ]:
Corey-TBS aldehyde
(3aR,4S,5S,6aS)-5-{[Dimethyl(2-methyl-2-propanyl)silyl]oxy}-2-oxohexahydro-2H-cyclopenta[b]furan-4-carbaldehyde
2H-Cyclopenta[b]furan-4-carboxaldehyde, 5-[[(1,1-dimethylethyl)dimethylsilyl]oxy]hexahydro-2-oxo-, (3aR,4S,5S,6aS)-
TBS-COREY LACTONE ALDEHYDE
2H-Cyclopenta[b]furan-4-carboxaldehyde, 5-[[(1,1-dimethylethyl)dimethylsilyl]oxy]hexahydro-2-oxo-
5-{[Dimethyl(2-methyl-2-propanyl)silyl]oxy}-2-oxohexahydro-2H-cyclopenta[b]furan-4-carbaldehyde

Chemical & Physical Properties

[ Density]:
1.1±0.1 g/cm3

[ Boiling Point ]:
365.6±42.0 °C at 760 mmHg

[ Molecular Formula ]:
C14H24O4Si

[ Molecular Weight ]:
284.423

[ Flash Point ]:
145.3±23.4 °C

[ Exact Mass ]:
284.144379

[ PSA ]:
52.60000

[ LogP ]:
1.79

[ Vapour Pressure ]:
0.0±0.8 mmHg at 25°C

[ Index of Refraction ]:
1.476

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • 2-[[(1,1-Dimethylethyl)dimethylsilyl]oxy]corey lactone
  • (-)-3-OXO-6-BETA-TRITYLOXYMETHYL-7-ALPHA-BENZOYL-OXY-2-OXABICYCLO[3.3.0!OCTANE
  • (-)-Corey lactone benzoate
  • (-)-7α-hydroxy-6β-triphenylmethoxymethyl-cis-2-oxabicyclo[3.3.0]octan-3-one

DownStream

  • LatanoprostAcid
  • Latanoprost
  • tromethamine
  • Bimatoprost

Related Compounds

  • (3aR,4R,5R,6aS)-4-Formyl-2-oxohexahydro-2H-cyclopenta[b]furan-5-y l 4-biphenylcarboxylate
  • (+/-)-Corey lactone diol
  • (+)-Corey lactone
  • (+)-corey lactone, 4-phenylbenzoate alcohol
  • (+/-)-COREY LACTONE, 5-(4-PHENYLBENZOATE)
  • (-)-Corey aldehyde benzoate
  • 2-Chloro-N-(prop-2-YN-1-YL)pyridine-4-carboxamide
  • 4-((Cyclohexylamino)methyl)benzoic acid hydrochloride
  • 1-[(2,4-Dichlorophenyl)methyl]-N-(1,1-dimethylethyl)-2-methyl-1H-indole-3-methanamine
  • 2-Methoxy-6-(pyrazol-1-yl)-benzonitrile
  • 1H-3-Benzazepin-7-ol, 8-chloro-2,3,4,5-tetrahydro-5-(3-iodophenyl)-3-methyl-, (S)-
  • (4-Methyl-tetrahydro-furan-2-yl)-methanol
  • 5-Methyl-1,2,4-oxadiazole
  • N-(1-cyanocyclopentyl)-2-[4-(4-fluorobenzenesulfonyl)-1,4-diazepan-1-yl]acetamide
  • 4,5,6,7-Tetrahydrobenzo[d]isoxazole-3-carbaldehyde
  • tert-Butyl-DL-alanine