4-aminoheptafluorotoluene

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Names

[ CAS No. ]:
651-83-2

[ Name ]:
4-aminoheptafluorotoluene

[Synonym ]:
2,3,5,6-Tetrafluoro-4-(trifluoromethyl)aniline
Benzenamine, 2,3,5,6-tetrafluoro-4-(trifluoromethyl)-
2,3,5,6-Tetrafluor-4-(trifluormethyl)anilin
2,3,5,6-tetrafluoro-4-trifluoromethylaniline
MFCD00091518
4-aminoheptafluorotoluene

Chemical & Physical Properties

[ Density]:
1.6±0.1 g/cm3

[ Boiling Point ]:
171.7±40.0 °C at 760 mmHg

[ Molecular Formula ]:
C7H2F7N

[ Molecular Weight ]:
233.086

[ Flash Point ]:
67.9±18.0 °C

[ Exact Mass ]:
233.007553

[ PSA ]:
26.02000

[ LogP ]:
3.28

[ Vapour Pressure ]:
1.4±0.3 mmHg at 25°C

[ Index of Refraction ]:
1.413

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Hazard Codes ]:
Xi

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S36

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2921420090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • Perfluorotoluene
  • benzylidene 4-trifluoromethyl-2,3,5,6-tetrafluoroaniline
  • 1,2,4,5-tetrafluoro-3-nitro-6-(trifluoromethyl)benzene
  • 4-trifluoromethyl-2,3,5,6-tetrafluorophenylhydroxylamine
  • 2,3,5,6-tetrafluoro-4-hydrazinobenzotrifluoride

DownStream

  • N-[2,5-difluoro-4-(trifluoromethyl)phenyl]acetamide
  • oxido-[2,3,5,6-tetrafluoro-4-(trifluoromethyl)phenyl]-[2,3,5,6-tetrafluoro-4-(trifluoromethyl)phenyl]iminoazanium

Customs

[ HS Code ]: 2921420090

[ Summary ]:
HS:2921420090 aniline derivatives and their salts VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

Articles

Pd(II)-catalyzed carbonylation of C(sp3)-H bonds: a new entry to 1,4-dicarbonyl compounds.

J. Am. Chem. Soc. 49th ed., 132 , 17378-17380, (2010)

Pd(II)-catalyzed β-C(sp(3))-H carbonylation of N-arylamides under CO (1 atm) has been achieved. Following amide-directed C(sp(3))-H cleavage and insertion of CO into the resulting [Pd(II)-C(sp(3))] bo...

Pd-catalyzed intermolecular C-H amination with alkylamines.

J. Am. Chem. Soc. 20th ed., 133 , 7652-7655, (2011)

C-H amination of N-aryl benzamides with O-benzoyl hydroxylamines has been achieved with either Pd(II) or Pd(0) catalysts. Furthermore, we demonstrate that secondary amines can be directly used with be...

Pd(II)-catalyzed enantioselective C-H activation of cyclopropanes.

J. Am. Chem. Soc. 49th ed., 133 , 19598-19601, (2011)

Systematic ligand development has led to the identification of novel mono-N-protected amino acid ligands for Pd(II)-catalyzed enantioselective C-H activation of cyclopropanes. A diverse range of organ...


More Articles

Related Compounds

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  • 4-(4-Chlorophenyl)-4-Bromopiperide
  • 4-(2-nitroimidazol-1-yl)butane-1,2-diol
  • 4-Iodo-1H-indazole-3-carboxylic acid
  • 4-chlorooxolan-3-ol,formic acid
  • 4,6-Pyrimidinedicarboxylic acid
  • 4-((Cyclohexylamino)methyl)benzoic acid hydrochloride
  • 1-[(2,4-Dichlorophenyl)methyl]-N-(1,1-dimethylethyl)-2-methyl-1H-indole-3-methanamine
  • 2-Methoxy-6-(pyrazol-1-yl)-benzonitrile
  • 1H-3-Benzazepin-7-ol, 8-chloro-2,3,4,5-tetrahydro-5-(3-iodophenyl)-3-methyl-, (S)-
  • 1,5-Diethoxynaphthalene
  • (4-Methyl-tetrahydro-furan-2-yl)-methanol
  • N-(1-cyanocyclopentyl)-2-[4-(4-fluorobenzenesulfonyl)-1,4-diazepan-1-yl]acetamide
  • Bis[4-(3-maleimidophenoxy)phenyl]sulfone
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  • tert-Butyl-DL-alanine