5-METHYLBENZO(c)PHENANTHRENE

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Names

[ CAS No. ]:
652-04-0

[ Name ]:
5-METHYLBENZO(c)PHENANTHRENE

[Synonym ]:
5-Methyl-3,4-benzophenanthrene
5-methyl-benzo[c]phenanthrene
2-Methyl-3,4-benzphenanthrene
5-Methyl-benzo<c>-phenanthren
BENZO(c)PHENANTHRENE,5-METHYL

Chemical & Physical Properties

[ Density]:
1.164g/cm3

[ Boiling Point ]:
449.4ºC at 760 mmHg

[ Molecular Formula ]:
C19H14

[ Molecular Weight ]:
242.31400

[ Flash Point ]:
217.8ºC

[ Exact Mass ]:
242.11000

[ LogP ]:
5.45460

[ Index of Refraction ]:
1.748

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
DI9450000
CHEMICAL NAME :
Benzo(c)phenanthrene, 5-methyl-
CAS REGISTRY NUMBER :
652-04-0
BEILSTEIN REFERENCE NO. :
2329427
LAST UPDATED :
199612
DATA ITEMS CITED :
4
MOLECULAR FORMULA :
C19-H14
MOLECULAR WEIGHT :
242.33
WISWESSER LINE NOTATION :
L C6 B666J I1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
10 gm/kg/51W-I
TOXIC EFFECTS :
Tumorigenic - equivocal tumorigenic agent by RTECS criteria Skin and Appendages - tumors
REFERENCE :
PRLBA4 Proceedings of the Royal Society of London, Series B: Biological Sciences. (Royal Soc., 6 Carlton House Terrace, London SW1Y 5AG, UK) V.76- 1905- Volume(issue)/page/year: 129,439,1940
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
480 mg/kg/17W-I
TOXIC EFFECTS :
Tumorigenic - equivocal tumorigenic agent by RTECS criteria Skin and Appendages - tumors Tumorigenic - tumors at site of application
REFERENCE :
PRLBA4 Proceedings of the Royal Society of London, Series B: Biological Sciences. (Royal Soc., 6 Carlton House Terrace, London SW1Y 5AG, UK) V.76- 1905- Volume(issue)/page/year: 123,343,1937
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Subcutaneous
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
1800 mg/kg/27W-I
TOXIC EFFECTS :
Tumorigenic - equivocal tumorigenic agent by RTECS criteria Tumorigenic - tumors at site of application
REFERENCE :
PRLBA4 Proceedings of the Royal Society of London, Series B: Biological Sciences. (Royal Soc., 6 Carlton House Terrace, London SW1Y 5AG, UK) V.76- 1905- Volume(issue)/page/year: 129,439,1940
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Intravenous
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
10 mg/kg
TOXIC EFFECTS :
Tumorigenic - neoplastic by RTECS criteria Lungs, Thorax, or Respiration - tumors
REFERENCE :
JNCIAM Journal of the National Cancer Institute. (Washington, DC) V.1-60, 1940-78. For publisher information, see JJIND8. Volume(issue)/page/year: 1,225,1940

Safety Information

[ HS Code ]:
2902909090

Synthetic Route

Precursor & DownStream

Precursor

  • 8-methyl-benzo[c]phenanthrene-5,6-dicarboxylic acid-anhydride
  • 5,5-dimethyl-5,6-dihydro-benzo[c]phenanthrene
  • METHYLMAGNESIUM IODIDE
  • 5,5-dimethyl-5,6,6a,7,8,12b-hexahydro-benzo[c]phenanthrene
  • 8,8-dimethyl-6a,7,8,12b-tetrahydro-6H-benzo[c]phenanthren-5-one
  • 5-methyl-5,6,6a,7,8,12b-hexahydro-benzo[c]phenanthrene
  • 2-(2-phenyl-propyl)-3,4-dihydro-2H-naphthalen-1-one
  • 2-(2-Phenyl-propyl)-1,2,3,4-tetrahydro-[1]naphthol
  • benzene
  • Acetophenone

DownStream

  • methyl benzo[c]phenanthrene-5-carboxylate

Customs

[ HS Code ]: 2902909090

[ Summary ]:
2902909090 other aromatic hydrocarbons。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:2.0%。General tariff:30.0%


Related Compounds

  • 5-methylbenzo[c]phenanthrene,2,4,7-trinitrofluoren-9-one
  • 5-Methylbenzo[c][1,2,5]oxadiazole
  • 5-Methylbenzo[c]isothiazole
  • 2-methylbenzo[c]phenanthrene,2,4,7-trinitrofluoren-9-one
  • 3-methylbenzo[c]phenanthrene,2,4,7-trinitrofluoren-9-one
  • 4-methylbenzo[c]phenanthrene
  • N-{[1-(cyclopropylmethyl)-1H-1,2,3-triazol-4-yl]methyl}-N-methylhydroxylamine
  • 2-tert-butyl-5-[(2S)-oxiran-2-yl]-2H-1,2,3,4-tetrazole
  • (2S)-2-amino-2-[2-(dimethylamino)-5-fluorophenyl]ethan-1-ol
  • 4-(2-Methoxy-6-methylpyridin-4-yl)pyrrolidin-2-one
  • 1-(2-Methoxy-4-nitrophenyl)prop-2-en-1-one
  • 1-[2-(Methoxymethyl)-1,3-thiazol-4-yl]-2-(methylamino)ethan-1-ol
  • 2-(6-Methoxy-5-methylpyridin-3-yl)propanoic acid
  • 2-Amino-2-(6-methoxy-5-methylpyridin-3-yl)acetic acid
  • methyl (3R)-3-[6-(dimethylamino)pyridin-3-yl]-3-hydroxypropanoate
  • 1-(2,5-Dimethoxypyridin-4-yl)-2-(methylamino)ethan-1-ol
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