1-(Pentafluorophenyl)ethanone

Names

[ CAS No. ]:
652-29-9

[ Name ]:
1-(Pentafluorophenyl)ethanone

[Synonym ]:
1-(2,3,4,5,6-pentafluorophenyl)ethanone
1-(Pentafluorophenyl)ethanone
2,3,4,5,6-Pentafluoroacetophenone
MFCD00000296
EINECS 211-487-6
Ethanone, 1-(2,3,4,5,6-pentafluorophenyl)-

Chemical & Physical Properties

[ Density]:
1.5±0.1 g/cm3

[ Boiling Point ]:
130.5±0.0 °C at 760 mmHg

[ Molecular Formula ]:
C₈H₃F₅O

[ Molecular Weight ]:
210.101

[ Flash Point ]:
65.6±0.0 °C

[ Exact Mass ]:
210.010406

[ PSA ]:
17.07000

[ LogP ]:
1.11

[ Vapour Pressure ]:
9.7±0.2 mmHg at 25°C

[ Index of Refraction ]:
1.424

MSDS

Safety Information

[ Personal Protective Equipment ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
F

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S24/25

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2914700090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

(perfluorophenyl)zinc(II) chloride
BIS(PENTAFLUOROPHENYL)ZINC
Acetyl chloride
Pentafluorobenzene
pentafluorophenacyl bromide
Diethyl phosphite
lithium trifluoroacetate
Pentafluor-α-methyl-α-nitromethylbenzylalkohol

DownStream

pentafluorophenacyl bromide
Benzenemethanol,2,3,4,5,6-pentafluoro-a-methyl-
r(+)-1-(pentafluorophenyl)ethanol
3-Ethoxy-1,2,4,5-tetrafluorobenzene
ethyl acetate
4,4,4-trifluoro-1-(2,3,4,5,6-pentafluorophenyl)butane-1,3-dione
2-(2,3,4,5,6-pentafluorophenyl)-1H-indole
5,6,7,8-tetrafluoro-4-oxochromene-2-carboxylic acid
5-(2,3,4,5,6-pentafluorophenyl)-2H-1,2,4-triazine-3-thione

Customs

[ HS Code ]: 2914700090

[ Summary ]:
HS: 2914700090 halogenated, sulphonated, nitrated or nitrosated derivatives of ketones and quinones, whether or not with other oxygen function Tax rebate rate:9.0% Supervision conditions:none VAT:17.0% MFN tariff:5.5% General tariff:30.0%

Articles

Identification, cloning, and characterization of a novel ketoreductase from the cyanobacterium Synechococcus sp. strain PCC 7942.

Appl. Environ. Microbiol. 74(21) , 6697-702, (2008)

A new ketoreductase useful for asymmetric synthesis of chiral alcohols was identified in the cyanobacterium Synechococcus sp. strain PCC 7942. Mass spectrometry of trypsin-digested peptides identified...

Magnetic field effects on the photochemical hydrogen abstraction of 2′, 3′, 4′, 5′, 6′-pentafluoroacetophenone in a Brij 35 micellar solution. Igarashi M, et al.

Mol. Phys. 82(6) , 1165-79, (1994)

Polyfluoroaryl carbonyl chemistry. Benzalacetophenones. Filler R, et al.

J. Org. Chem. 40(7) , 935-39, (1975)