(2R)-2-[(Trityloxy)methyl]oxirane

Names

[ Name ]:
(2R)-2-[(Trityloxy)methyl]oxirane

[Synonym ]:
MFCD00273368
Oxirane, 2-[(triphenylmethoxy)methyl]-, (2R)-
(2R)-2-(trityloxymethyl)oxirane
(2R)-2-[(Trityloxy)methyl]oxirane

Chemical & Physical Properties

[ Density]:
1.1±0.1 g/cm3

[ Boiling Point ]:
438.8±40.0 °C at 760 mmHg

[ Melting Point ]:
99-102 °C(lit.)

[ Molecular Formula ]:
C₂₂H₂₀O₂

[ Molecular Weight ]:
316.393

[ Flash Point ]:
164.8±26.9 °C

[ Exact Mass ]:
316.146332

[ PSA ]:
21.76000

[ LogP ]:
6.50

[ Vapour Pressure ]:
0.0±1.0 mmHg at 25°C

[ Index of Refraction ]:
1.603

MSDS

Safety Information

[ Personal Protective Equipment ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter

[ Hazard Codes ]:
Xi:Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S37/39-S26

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2910900090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

Triphenylmethyl Chloride
(±)-Glycidol
(±)-Glycidol
(2R)-2-[(Trityloxy)methyl]oxirane
Carbon dioxide
1-Chloro-3-O-trityl-2-propanol

DownStream

(R)-4-(triphenylmethoxy)methyl-1,3-dioxolan-2-one
(2R)-2-[(Trityloxy)methyl]oxirane
(2S)-2-[(Trityloxy)methyl]oxirane
Butyl glycidyl ether
Triphenylmethane
(2S)-1-(Benzyloxy)-3-(trityloxy)-2-propanol

Customs

[ HS Code ]: 2910900090

[ Summary ]:
2910900090. epoxides, epoxyalcohols, epoxyphenols and epoxyethers, with a three-membered ring, and their halogenated, sulphonated, nitrated or nitrosated derivatives. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:5.5%. General tariff:30.0%

Articles

Brodfuehrer, P.R. et al.

Tetrahedron Lett. 35 , 3243, (1994)

Bennett, M.J. et al.

Tetrahedron Lett. 36 , 2207, (1995)

Lin, H.-K. Gelb, M.H.

J. Am. Chem. Soc. 115 , 3932, (1993)

(2S)-2-[(Trityloxy)methyl]oxirane
(2R)-2-methyl-2-(phenylmethoxymethyl)oxirane
(2R)-2-[(3-nitrophenoxy)methyl]oxirane
(2R)-2-[(2-chloroethoxy)methyl]oxirane
(2R)-2-[(2-methylsulfanylphenoxy)methyl]oxirane
2R)-2-[(3-broMophenoxy)Methyl]-oxirane
N-(3-methoxyphenyl)-2-(5-methyl-4-oxo-6-(3-(m-tolyl)-1,2,4-oxadiazol-5-yl)thieno[2,3-d]pyrimidin-3(4H)-yl)acetamide
2-(6-(3-(4-fluorophenyl)-1,2,4-oxadiazol-5-yl)-5-methyl-4-oxothieno[2,3-d]pyrimidin-3(4H)-yl)-N-phenethylacetamide
2-(5-methyl-4-oxo-6-(3-phenyl-1,2,4-oxadiazol-5-yl)thieno[2,3-d]pyrimidin-3(4H)-yl)-N-(4-methylbenzyl)acetamide
N-(2-fluorophenyl)-2-(5-methyl-4-oxo-6-(3-(m-tolyl)-1,2,4-oxadiazol-5-yl)thieno[2,3-d]pyrimidin-3(4H)-yl)acetamide
7-({[2-(4-chlorophenyl)-5-methyl-1,3-oxazol-4-yl]methyl}thio)-2-(4-ethylphenyl)pyrazolo[1,5-d][1,2,4]triazin-4(5H)-one
N-cyclohexyl-2-(5-methyl-4-oxo-6-(3-phenyl-1,2,4-oxadiazol-5-yl)thieno[2,3-d]pyrimidin-3(4H)-yl)acetamide
N-(3-fluorophenyl)-2-(5-methyl-4-oxo-6-(3-(m-tolyl)-1,2,4-oxadiazol-5-yl)thieno[2,3-d]pyrimidin-3(4H)-yl)acetamide
N-(4-fluorophenyl)-2-(5-methyl-4-oxo-6-(3-(m-tolyl)-1,2,4-oxadiazol-5-yl)thieno[2,3-d]pyrimidin-3(4H)-yl)acetamide
tert-butyl 4-((6-(3-methyl-5-(methylsulfonyl)-1H-indol-1-yl)pyrimidin-4-yl)oxy)piperidine-1-carboxylate
tert-butyl 4-((2-methyl-6-(3-methyl-5-(methylsulfonyl)-1H-indol-1-yl)pyrimidin-4-yl)oxy)piperidine-1-carboxylate

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