(2R)-2-[(Trityloxy)methyl]oxirane

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Names

[ CAS No. ]:
65291-30-7

[ Name ]:
(2R)-2-[(Trityloxy)methyl]oxirane

[Synonym ]:
MFCD00273368
Oxirane, 2-[(triphenylmethoxy)methyl]-, (2R)-
(2R)-2-(trityloxymethyl)oxirane
(2R)-2-[(Trityloxy)methyl]oxirane

Chemical & Physical Properties

[ Density]:
1.1±0.1 g/cm3

[ Boiling Point ]:
438.8±40.0 °C at 760 mmHg

[ Melting Point ]:
99-102 °C(lit.)

[ Molecular Formula ]:
C22H20O2

[ Molecular Weight ]:
316.393

[ Flash Point ]:
164.8±26.9 °C

[ Exact Mass ]:
316.146332

[ PSA ]:
21.76000

[ LogP ]:
6.50

[ Vapour Pressure ]:
0.0±1.0 mmHg at 25°C

[ Index of Refraction ]:
1.603

MSDS

Click to get detail MSDS

Safety Information

[ Personal Protective Equipment ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter

[ Hazard Codes ]:
Xi:Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S37/39-S26

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2910900090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • Triphenylmethyl Chloride
  • (±)-Glycidol
  • (±)-Glycidol
  • (2R)-2-[(Trityloxy)methyl]oxirane
  • Carbon dioxide
  • 1-Chloro-3-O-trityl-2-propanol

DownStream

  • (R)-4-(triphenylmethoxy)methyl-1,3-dioxolan-2-one
  • (2R)-2-[(Trityloxy)methyl]oxirane
  • (2S)-2-[(Trityloxy)methyl]oxirane
  • Butyl glycidyl ether
  • Triphenylmethane
  • (2S)-1-(Benzyloxy)-3-(trityloxy)-2-propanol

Customs

[ HS Code ]: 2910900090

[ Summary ]:
2910900090. epoxides, epoxyalcohols, epoxyphenols and epoxyethers, with a three-membered ring, and their halogenated, sulphonated, nitrated or nitrosated derivatives. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:5.5%. General tariff:30.0%

Articles

Brodfuehrer, P.R. et al.

Tetrahedron Lett. 35 , 3243, (1994)

Bennett, M.J. et al.

Tetrahedron Lett. 36 , 2207, (1995)

Lin, H.-K. Gelb, M.H.

J. Am. Chem. Soc. 115 , 3932, (1993)


More Articles

Related Compounds

  • (2S)-2-[(Trityloxy)methyl]oxirane
  • (2R)-2-methyl-2-(phenylmethoxymethyl)oxirane
  • (2R)-2-[(3-nitrophenoxy)methyl]oxirane
  • (2R)-2-[(2-chloroethoxy)methyl]oxirane
  • (2R)-2-[(2-methylsulfanylphenoxy)methyl]oxirane
  • 2R)-2-[(3-broMophenoxy)Methyl]-oxirane
  • 2-(Butan-2-yl)thiolane-2-carbaldehyde
  • 1-(4-Hydroxyoxolan-3-yl)cyclobutane-1-carbaldehyde
  • 3-[(Trimethylsilyl)methyl]oxolane-3-carbaldehyde
  • 2-(Cyclopropylmethyl)bicyclo[2.2.1]heptane-2-carbaldehyde
  • (18F)Fluoropropyl-trimethoprim
  • 1-(4,6-Dichloropyrimidin-5-yl)prop-2-en-1-one
  • 1-(4,6-Dichloropyrimidin-5-yl)prop-2-en-1-ol
  • (S)-2-(1,2-Diaminoethyl)pyridin-3-ol
  • (1S)-5-bromo-6-methoxy-1,2,3,4-tetrahydronaphthalen-1-amine
  • (R)-2-(5-Bromo-2-chlorophenyl)piperidine
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