2,3-Diaminophenazine

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Names

[ CAS No. ]:
655-86-7

[ Name ]:
2,3-Diaminophenazine

[Synonym ]:
2,3-Diaminophenazine
MFCD00160693
DAP
EINECS 211-512-0
2,3-diaminophenazene
phenazine-2,3-diyldiamine
2,3-diamino-phenazin
PHENAZINE-2,3-DIAMINE
2,3-Phenazinediamine
2,3-diamonophenazine
Phenazine,2,3-diamino

Chemical & Physical Properties

[ Density]:
1.4±0.1 g/cm3

[ Boiling Point ]:
497.8±15.0 °C at 760 mmHg

[ Melting Point ]:
>300ºC

[ Molecular Formula ]:
C12H10N4

[ Molecular Weight ]:
210.235

[ Flash Point ]:
287.1±7.6 °C

[ Exact Mass ]:
210.090546

[ PSA ]:
77.82000

[ LogP ]:
1.82

[ Vapour Pressure ]:
0.0±1.3 mmHg at 25°C

[ Index of Refraction ]:
1.853

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
SG1577650
CHEMICAL NAME :
Phenazine, 2,3-diamino-
CAS REGISTRY NUMBER :
655-86-7
BEILSTEIN REFERENCE NO. :
0014422
LAST UPDATED :
199612
DATA ITEMS CITED :
3
MOLECULAR FORMULA :
C12-H10-N4
MOLECULAR WEIGHT :
210.26

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
Specific locus test

MUTATION DATA

TEST SYSTEM :
Insect - Drosophila melanogaster
DOSE/DURATION :
4900 nmol/vial
REFERENCE :
MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 369,75,1996

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H302-H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi: Irritant;Xn: Harmful;

[ Risk Phrases ]:
R22

[ Safety Phrases ]:
26-36/37

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ RTECS ]:
SG1577650

[ HS Code ]:
2933990090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • o-Phenylenediamine
  • 3,4-Diaminobenzoicacid
  • (4-chloro-2-nitrophenyl) thiohypochlorite
  • 2,3-Diaminobenzoic acid
  • 4-Methoxy-3-nitrobenzoic acid
  • 4-Amino-3-nitrobenzoic acid
  • Benzofuroxan
  • Benzene,1-azido-2-nitro-
  • benzene-o-diamine monohydrochloride
  • Aniline Yellow

DownStream

  • pyrazino[2,3-b]phenazine
  • Phenazine
  • 2-Phenazinamine
  • 5,7,12,14-Tetrahydroquinoxalino[2,3-b]phenazine
  • Pyrazinetetracarboxylic acid

Customs

[ HS Code ]: 2933990090

[ Summary ]:
2933990090. heterocyclic compounds with nitrogen hetero-atom(s) only. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

Articles

Spectrophotometric quantification of horseradish peroxidase with o-phenylenediamine.

Anal. Biochem. 407(2) , 293-5, (2010)

The assay conditions for the spectrophotometric quantification of horseradish peroxidase (HRP) with the chromogenic substrate o-phenylenediamine (OPD) at 25°C in the presence of hydrogen peroxide (H(2...

Spectrophotometric quantification of lactose in solution with a peroxidase-based enzymatic cascade reaction system.

Anal. Bioanal. Chem 401 , 2307-2310, (2011)

A spectrophotometric assay was developed for the quantification of lactose in aqueous solution via a one-pot enzymatic cascade reaction at 25 °C and pH 7.2. Lactose (0.2-1.8 mM), E. coli β-galactosida...

Photoinduced DNA cleavage and cellular damage in human dermal fibroblasts by 2,3-diaminophenazine.

Photochem. Photobiol. 81(1) , 89-95, (2005)

Aromatic amines, such as o-phenylenediamine (OPD), have been used extensively in commercial hair dyes and in the synthesis of agricultural pesticides. Air oxidation of OPD results in the formation of ...


More Articles

Related Compounds

  • 2,3-dihydroxypropanesulphonic acid
  • 2-(3,4-dimethoxyphenyl)pyrazolidin-3-one
  • 2,3,5-trichloro-6-[5-(diethylamino)-1H-pyrazol-4-yl]benzene-1,4-diol
  • 2,3-BIS(4-FLUOROPHENYL)-5-PHENYLTETRAZOLIUM CHLORIDE
  • 2,3-BIS(4-CHLOROPHENYL)-5-PHENYLTETRAZOLIUM CHLORIDE
  • 2-(3-Chloropropoxy)-1-methoxy-4-nitrobenzene
  • 4-((Cyclohexylamino)methyl)benzoic acid hydrochloride
  • 1-(2-((4-((3,5-Dimethylisoxazol-4-yl)methyl)piperazin-1-yl)sulfonyl)ethyl)piperidine-2,6-dione
  • N-(3,3-dimethyl-4-oxo-5-propyl-2,3,4,5-tetrahydrobenzo[b][1,4]oxazepin-8-yl)-5-ethyl-2-methoxybenzenesulfonamide
  • 1-[(2,4-Dichlorophenyl)methyl]-N-(1,1-dimethylethyl)-2-methyl-1H-indole-3-methanamine
  • N-[7-(Dimethylamino)pyrazolo[1,5-a]pyrimidin-5-yl]-4-(1,1-dimethylethyl)benzamide
  • 2-Methoxy-6-(pyrazol-1-yl)-benzonitrile
  • 1,2,5,6,7,8-Hexahydro-4,6-dimethyl-2-oxo-3-quinolinecarbonitrile
  • 1H-3-Benzazepin-7-ol, 8-chloro-2,3,4,5-tetrahydro-5-(3-iodophenyl)-3-methyl-, (S)-
  • N-Boc-Tyr-Ala-Trp-OMe
  • 3-(2,5-dimethylfuran-3-yl)-1,4-dimethyl-1H-pyrazol-5-amine