lithium diphenylphosphide

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Names

[ CAS No. ]:
65567-06-8

[ Name ]:
lithium diphenylphosphide

[Synonym ]:
Diphenylphosphino)lithium
Lithiodiphenylphosphine
Diphenyl lithium phosphide
Lithium Diphenylphosphanide
lithium diphenylphosphide
Lithium diphenylphosphide solution
MFCD00046054
Diphenylphosphine lithium salt
Lithiodiphenyl phosphide
lithium diphenylphosphinide
lithium diphenylphosphinite

Chemical & Physical Properties

[ Density]:
0.925 g/mL at 25 °C

[ Boiling Point ]:
65-67 °C

[ Molecular Formula ]:
C12H11LiP

[ Molecular Weight ]:
193.13100

[ Flash Point ]:
-20 °C

[ Exact Mass ]:
193.07600

[ PSA ]:
13.59000

[ LogP ]:
2.31590

[ Appearance of Characters ]:
Liquid | Orange to red

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS02, GHS05, GHS07, GHS08, GHS09

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H225-H302 + H332-H314-H335-H351-H410

[ Supplemental HS ]:
May form explosive peroxides.

[ Precautionary Statements ]:
P210-P260-P280-P305 + P351 + P338-P370 + P378-P403 + P235

[ Personal Protective Equipment ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
F,C,N

[ Risk Phrases ]:
11-19-20/21/22-34-50/53-40-37

[ Safety Phrases ]:
16-26-27-36/37/39-45-61

[ RIDADR ]:
UN 2924 3/PG 2

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • Chlorodiphenylphosphine
  • Triphenylphosphine
  • Diphenylphosphine
  • n-Butyllithium
  • Lithium
  • tert-butyl chloride
  • dppe
  • Dicyclohexylphosphine

DownStream

  • lithium triflate
  • (-)-diop
  • (+)-NEOMENTHYLDIPHENYLPHOSPHINE
  • diphenylphosphinoethane
  • Methoxymethyldiphenylphosphine oxide
  • Diphenyl-2-pyridylphosphine
  • Diphenylphosphine
  • Diphenylphosphinic acid
  • (E)-(2-phenylethenyl)diphenylphosphane oxide

Related Compounds

  • lithium diphenylphosphide
  • Lithium diphenylphosphide oxide
  • lithium citrate
  • lithium,trimethyl(prop-2-enyl)silane
  • lithium,methyl(diphenyl)silanide
  • lithium pyruvate
  • 2-(2,4-dioxo-4aH-quinazolin-3-yl)-N-(4-methylcyclohexyl)acetamide
  • N-(pyridin-3-ylmethyl)-4-[[(2-sulfanylidene-3,4,4a,5,6,7,8,8a-octahydro-1H-quinazolin-4-yl)amino]methyl]cyclohexane-1-carboxamide
  • (1-(Thiazol-5-ylmethyl)piperidin-3-yl)methanol
  • 2-(1-Benzylazetidin-3-yl)ethanol
  • 3-(3-Bromopropyl)piperidine
  • 2-(bromomethyl)-1-cyclopropyl-1H-pyrrole
  • 2-(bromomethyl)-1-cyclopropyl-1H-imidazole
  • Glycine, N-(4-methylphenyl)-, [[2-(4-methyl-1-piperazinyl)-5-nitrophenyl]methylene]hydrazide
  • 1-(Cyclopropylsulfonyl)-3-(4-fluorophenyl)azepane
  • N-(tetrahydro-2H-pyran-4-yl)-N-(thiophen-2-ylmethyl)cyclohex-3-enecarboxamide
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