6-Methoxynicotinaldehyde

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Names

[ CAS No. ]:
65873-72-5

[ Name ]:
6-Methoxynicotinaldehyde

[Synonym ]:
MFCD02683446
2-Methoxypyridine-5-carboxaldehyde
6-Methoxypyridine-3-Carbaldehyde
6-Methoxynicotinaldehyde
3-Pyridinecarboxaldehyde, 6-methoxy-

Chemical & Physical Properties

[ Density]:
1.2±0.1 g/cm3

[ Boiling Point ]:
244.2±20.0 °C at 760 mmHg

[ Melting Point ]:
51-54 °C(lit.)

[ Molecular Formula ]:
C7H7NO2

[ Molecular Weight ]:
137.14

[ Flash Point ]:
101.5±21.8 °C

[ Exact Mass ]:
137.047684

[ PSA ]:
39.19000

[ LogP ]:
1.31

[ Vapour Pressure ]:
0.0±0.5 mmHg at 25°C

[ Index of Refraction ]:
1.551

[ Water Solubility ]:
insoluble

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi:Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S36

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2933399090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • 2-Methoxy-5-Bromopyridine
  • N,N-Dimethylformamide
  • 6-Methoxynicotinonitrile
  • Semicarbazide hydrochloride
  • (6-Methoxypyridin-3-yl)methanol
  • 2-Methoxypyridine
  • 5-(dimethoxymethyl)-2-methoxypyridine
  • 2,6-Bis(chloromethyl)pyridine hydrochloride (1:1)
  • sodium sulfate
  • 2,5-Dibromopyridine

DownStream

  • (6-Methoxypyridin-3-yl)methanol
  • 2-Methoxy-5-pyridinecarboxylic acid
  • 6-Hydroxynicotinaldehyde
  • 5-formyl-2-methoxy-4-picoline
  • 3-Pyridinecarboxaldehyde, 6-methoxy-5-methyl- (9CI)
  • 5-Chloro-6-methoxynicotinaldehyde
  • 5-(Chloromethyl)-2-methoxypyridine
  • 2-Chloro-5-(dichloromethyl)pyridine
  • 5-Bromo-6-methoxynicotinaldehyde
  • 3-(6-methoxypyridin-3-yl)-2-methylprop-2-enoic acid

Customs

[ HS Code ]: 2933399090

[ Summary ]:
2933399090. other compounds containing an unfused pyridine ring (whether or not hydrogenated) in the structure. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

Articles

Tetrahedron Asymmetry 14 , 3469-3477, (2003)

Tetrahedron Lett. 46 , 6991, (2005)

Lithiation of methoxypyridines directed by α-amino alkoxides. Comins DL and Killpack MO.

J. Org. Chem. 55(1) , 69-73, (1990)


More Articles

Related Compounds

  • 4-iodo-6-methoxynicotinaldehyde
  • 5-Bromo-6-methoxynicotinaldehyde
  • 4-Amino-6-methoxynicotinaldehyde
  • 2-AMINO-6-METHOXYNICOTINALDEHYDE
  • 2-BROMO-6-METHOXYNICOTINALDEHYDE
  • 4-bromo-6-methoxynicotinaldehyde