2'-hydroxy-5'-methyl-3'-nitroacetophenone

Names

[ CAS No. ]:
66108-30-3

[ Name ]:
2'-hydroxy-5'-methyl-3'-nitroacetophenone

[Synonym ]:
1-(2-hydroxy-5-methyl-3-nitrophenyl)ethanone
MFCD00192216

Chemical & Physical Properties

[ Density]:
1.323g/cm3

[ Boiling Point ]:
254ºC at 760 mmHg

[ Melting Point ]:
133-136 °C(lit.)

[ Molecular Formula ]:
C₉H₉NO₄

[ Molecular Weight ]:
195.17200

[ Flash Point ]:
106ºC

[ Exact Mass ]:
195.05300

[ PSA ]:
83.12000

[ LogP ]:
2.33460

[ Index of Refraction ]:
1.586

MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S36

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2914700090

Synthetic Route

Click to get detail synthetic route

Customs

[ HS Code ]: 2914700090

[ Summary ]:
HS: 2914700090 halogenated, sulphonated, nitrated or nitrosated derivatives of ketones and quinones, whether or not with other oxygen function Tax rebate rate:9.0% Supervision conditions:none VAT:17.0% MFN tariff:5.5% General tariff:30.0%

Articles

Densities and ultrasonic speed of 2-hydroxy-5-methyl-3-nitro acetophenone in N,N-dimethylformamide at different temperatures. Aswar AS and Choudhary DS.

Bull. Chem. Soc. Ethiop. 27(1) , 155-160., (2012)

Aromatic solvent effect on the rotational isomerism in 2-hydroxy-5-methyl-3-nitroacetophenone. Konopacka A, et al.

J. Phys. Org. Chem. 18(12) , 1190-95, (2005)

2'-hydroxy-5'-methyl-3'-methoxymethylacetophenone
2'-hydroxy-5'-methyl-3,4-methylenedioxy-3'-nitro-trans()-chalcone
1-(3-bromo-2-hydroxy-5-methyl-phenyl)-3-phenyl-propenone
1-(2-HYDROXY-5-ISOPROPYL-3-NITROPHENYL)ETHANONE
2-(2-hydroxy-5-methyl-benzoyl)benzoic acid
Azo-azoxy BN
4-((Cyclohexylamino)methyl)benzoic acid hydrochloride
N-(tetrahydro-thiopyran-4-yl)-guanidine
1-[(2,4-Dichlorophenyl)methyl]-N-(1,1-dimethylethyl)-2-methyl-1H-indole-3-methanamine
2-Methoxy-6-(pyrazol-1-yl)-benzonitrile
1H-3-Benzazepin-7-ol, 8-chloro-2,3,4,5-tetrahydro-5-(3-iodophenyl)-3-methyl-, (S)-
(4-Methyl-tetrahydro-furan-2-yl)-methanol
N-(1-cyanocyclopentyl)-2-[4-(4-fluorobenzenesulfonyl)-1,4-diazepan-1-yl]acetamide
1-(2-(4-Chlorophenyl)-4,4-dimethylcyclohex-1-enyl)ethanol
1-(1,3-Thiazol-2-yl)butane-1,3-dione
2-Ethyl-4-methylpyrimidin-5-ol