tert-Butyl phenyl carbonate

Names

[ Name ]:
tert-Butyl phenyl carbonate

[Synonym ]:
1-tert-butoxycarbonyloxybenzene
t-Butyl phenyl carbonate
tBuOC(O)OPh
EINECS 229-601-8
O-Boc-phenol
MFCD00008804
phenyl tert-butyl carbonate
(tert-butoxycarbonyloxy)benzene

Chemical & Physical Properties

[ Density]:
1.05

[ Boiling Point ]:
83ºC (0.6 mmHg)

[ Molecular Formula ]:
C₁₁H₁₄O₃

[ Molecular Weight ]:
194.22700

[ Flash Point ]:
101ºC

[ Exact Mass ]:
194.09400

[ PSA ]:
35.53000

[ LogP ]:
3.00050

[ Appearance of Characters ]:
Liquid or Low Melting Solid | Colorless

[ Index of Refraction ]:
n20/D 1.480

[ Water Solubility ]:
Slightly soluble in water.

MSDS

Safety Information

[ Personal Protective Equipment ]:
Eyeshields;Gloves

[ Hazard Codes ]:
Xn

[ Safety Phrases ]:
S23-S24/25

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2920909090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

Di-tert-butyl dicarbonate
Phenol
Boc-1-tert-butoxy-1,2-dihydroisoquinoline
Phenyl chloroformate
tert-Butanol
potassium t-butoxide
phenyl 5-bromo-2-phenyl-2H-pyridine-1-carboxylate
phenyl 3-bromopyridin-1-ium-1-carboxylate,chloride

DownStream

Boc-7-Ahp-OH
N-Boc-1,5-diaminopentane
tert-butyl N-(3-trimethoxysilylpropyl)carbamate
tert-Butyl [(2S)-1-aminopropan-2-yl]carbamate
2-Methyl-2-propanyl (2-aminopropyl)carbamate
4-Phenylmorpholine
tert-Butyl (2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl) carbonate
N-BOC-Pyrrole
Bocdien*HCl
N1-Boc-2,2'-iminodiethylamine

Customs

[ HS Code ]: 2920909090

[ Summary ]:
2920909090 esters of other inorganic acids of non-metals (excluding esters of hydrogen halides) and their salts; their halogenated, sulphonated, nitrated or nitrosated derivatives。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:6.5%。General tariff:30.0%

Articles

Determination of octanol-water partition coefficients for carbonate esters and other small organic molecules by microemulsion electrokinetic chromatography.

Electrophoresis 24(6) , 1038-46, (2003)

Microemulsion electrokinetic chromatography (MEEKC) was assessed as a tool for determination of octanol-water partition coefficients using 34 solutes encompassing 8 carbonate esters. It was confirmed ...

Organic Synth. 84 , 209, (2007)

Synthesis of 2-nitroindoles via the Sundberg indole synthesis. Pelkey ET and Gribble GW.

Tetrahedron Lett. 38(32) , 5603-5606, (1997)

tert-Butyl [3-(Hydroxymethyl)phenyl] Carbonate
4-(tert-Butoxycarbonyloxy)phenylboronic acid pinacol ester
tert-Butyl 4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)benzoate
tert-butyl phenyl telluride
tert-butyl-phenyl-bis(trimethylsilyl)silane
tert-butyl-phenyl-(2-trimethylstannylethyl)phosphane