2-Amino-3-nitro-4-picoline

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Names

[ CAS No. ]:
6635-86-5

[ Name ]:
2-Amino-3-nitro-4-picoline

[Synonym ]:
2-Pyridinamine, 4-methyl-3-nitro-
MFCD00006315
4-methyl-3-nitropyridin-2-amin
2-Amino-3-nitro-4-picoline
4-Methyl-3-nitro-2-pyridinamine
4-methyl-3-nitropyridin-2-amine

Chemical & Physical Properties

[ Density]:
1.4±0.1 g/cm3

[ Boiling Point ]:
306.8±37.0 °C at 760 mmHg

[ Melting Point ]:
136-140 °C(lit.)

[ Molecular Formula ]:
C6H7N3O2

[ Molecular Weight ]:
153.139

[ Flash Point ]:
139.3±26.5 °C

[ Exact Mass ]:
153.053833

[ PSA ]:
84.73000

[ LogP ]:
2.08

[ Vapour Pressure ]:
0.0±0.7 mmHg at 25°C

[ Index of Refraction ]:
1.625

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xn:Harmful;

[ Risk Phrases ]:
R20/21/22;R36/37/38

[ Safety Phrases ]:
S26-S36-S36/37/39-S22

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
29333999

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • Aminopicoline
  • 4-Methyl-N-nitropyridin-2-amine
  • Crotonaldehyde
  • 2-nitroethene-1,1-diamine
  • Sulfuric acid

DownStream

  • 2-Fluoronicotinic acid
  • 3,5-Dinitro-2-pyridinamine
  • 2-amino-4-methyl-3,5-dinitro-pyridine
  • 3-Amino-4-methylpyridine
  • 3-Fluor-4-methylpyridin
  • 4-Methyl-3-nitro-2-pyridinol
  • 4-Methylpyridine-2,3-diamine
  • ethyl 3-bromo-7-methyl-8-nitroimidazo[1,2-a]pyridine-2-carboxylate
  • 5-Bromo-4-methyl-3-nitro-2-pyridinamine
  • 3-Fluoropyridine-4-carboxylic acid ethyl ester

Customs

[ HS Code ]: 2933399090

[ Summary ]:
2933399090. other compounds containing an unfused pyridine ring (whether or not hydrogenated) in the structure. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

Articles

Molecular and crystal structures, vibrational studies and quantum chemical calculations of 3 and 5-nitroderivatives of 2-amino-4-methylpyridine.

Spectrochim. Acta. A. Mol. Biomol. Spectrosc. 96 , 952-62, (2012)

The crystal structures of 2-amino-4-methyl-3-nitropyridine (I), 2-amino-4-methyl-3,5-dinitropyridine (II) and 2-amino-4-methyl-5-nitropyridine (III) have been determined. The compounds crystallize in ...

Microbial transformation of 2-amino-4-methyl-3-nitropyridine.

J. Ind. Microbiol. Biotechnol. 39(12) , 1789-99, (2012)

Biotransformation of the highly substituted pyridine derivative 2-amino-4-methyl-3-nitropyridine by Cunninghamella elegans ATCC 26269 yielded three products each with a molecular weight of 169 Da whic...


More Articles

Related Compounds

  • 2-Amino-3-nitro-4-picoline
  • 2-amino-3-nitro-4,6-diphenylbenzonitrile
  • 2-amino-3-nitro-4-(3-nitrophenyl)-6-phenylbenzonitrile
  • 2-Amino-3-nitro-4-phenylpyridine
  • 2-Amino-3-nitro-4,6-dimethyl-5-bromopyridine
  • 2-amino-3-nitro-4-phenyl-5,6,7,8-tetrahydronaphthalene-1-carbonitrile
  • 4-((Cyclohexylamino)methyl)benzoic acid hydrochloride
  • 1-[(2,4-Dichlorophenyl)methyl]-N-(1,1-dimethylethyl)-2-methyl-1H-indole-3-methanamine
  • 2-Methoxy-6-(pyrazol-1-yl)-benzonitrile
  • 1H-3-Benzazepin-7-ol, 8-chloro-2,3,4,5-tetrahydro-5-(3-iodophenyl)-3-methyl-, (S)-
  • 3H-Imidazo[4,5-c]pyridine, 4,5,6,7-tetrahydro-3-methyl-2-(2-phenoxyethyl)-
  • (4-Methyl-tetrahydro-furan-2-yl)-methanol
  • N-(1-cyanocyclopentyl)-2-[4-(4-fluorobenzenesulfonyl)-1,4-diazepan-1-yl]acetamide
  • 4,5,6,7-Tetrahydrobenzo[d]isoxazole-3-carbaldehyde
  • tert-Butyl-DL-alanine
  • 4-amino-N-[2-tert-butyl-1-(tetrahydro-2H-pyran-4-ylmethyl)-1H-benzimidazol-5-yl]-N-ethylbenzenesulfonamide