4-Bromo-2-iodoaniline

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Names

[ CAS No. ]:
66416-72-6

[ Name ]:
4-Bromo-2-iodoaniline

[Synonym ]:
4-Bromo-2-iodo-phenylamine
4-Bromo-2-iodoaniline
ZR BI DE
4-Bromo-2-iodobenzenamine
MFCD02093764
Benzenamine, 4-bromo-2-iodo-

Chemical & Physical Properties

[ Density]:
2.3±0.1 g/cm3

[ Boiling Point ]:
297.9±30.0 °C at 760 mmHg

[ Melting Point ]:
69-72 °C(lit.)

[ Molecular Formula ]:
C6H5BrIN

[ Molecular Weight ]:
297.919

[ Flash Point ]:
134.0±24.6 °C

[ Exact Mass ]:
296.864990

[ PSA ]:
26.02000

[ LogP ]:
3.42

[ Vapour Pressure ]:
0.0±0.6 mmHg at 25°C

[ Index of Refraction ]:
1.715

[ Storage condition ]:
Refrigerated.

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS05, GHS06, GHS09

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H301-H315-H318-H335-H411

[ Precautionary Statements ]:
P261-P273-P280-P301 + P310-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;Gloves;type P2 (EN 143) respirator cartridges

[ Hazard Codes ]:
T,N,Xi

[ Risk Phrases ]:
R25:Toxic if swallowed. R37/38:Irritating to respiratory system and skin . R41:Risk of serious damage to eyes. R51/53:Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment .

[ Safety Phrases ]:
S26-S36/37/39-S45-S61

[ RIDADR ]:
UN 2811 6.1/PG 3

[ WGK Germany ]:
3

[ HS Code ]:
2921420090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • 4-Bromoaniline
  • 2-Iodoaniline

DownStream

  • 6-Bromocinnoline
  • 6-Bromo-2-methylbenzo[d]thiazole
  • 2-Amino-5-bromobenzonitrile
  • 7-BROMO-2H-BENZO[B][1,4]THIAZIN-3(4H)-ONE
  • 4-Bromo-2,6-diiodoaniline
  • 6-bromo-2-quinolone
  • 2-Chloro-6-bromoquinoline
  • 6-Bromo-3H-benzothiazol-2-one
  • 5-bromo-2-indolecarboxylic acid
  • 5-bromo-a-phenyl benzimidazole

Customs

[ HS Code ]: 2921420090

[ Summary ]:
HS:2921420090 aniline derivatives and their salts VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

Articles

Solid-phase synthesis of 2,3,5-trisubstituted indoles.

Org. Lett. 3 , 3827-3830, (2001)

2,3,5-Trisubstituted indoles are synthesized in three steps starting from resin-bound aniline 2. R1 is introduced by a palladium-mediated coupling of the aryl iodide with terminal alkynes followed by ...

Palladium-catalyzed synthesis of 2-quinolone derivatives from 2-iodoanilines. Cortese NA, et al.

J. Org. Chem. 43(15) , 2952-2958, (1978)

ON SOME HALOGEN DERIVATIVES OF AROMATIC AMINES AND THEIR ANALYSIS. I. 1. Dains FB, et al.

J. Am. Chem. Soc. 40(6) , 930-936, (1918)


More Articles

Related Compounds

  • 4-Bromo-2-fluoro-6-iodoaniline
  • 4-bromo-2-chloro-6-iodoaniline
  • 4-Bromo-2-iodo-6-nitroaniline
  • 4-Bromo-3-chloro-2-iodoaniline
  • 4-bromo-5-chloro-2-iodoaniline
  • 4-Bromo-3,5-difluoro-2-iodoaniline
  • 4-((Cyclohexylamino)methyl)benzoic acid hydrochloride
  • 1-[(2,4-Dichlorophenyl)methyl]-N-(1,1-dimethylethyl)-2-methyl-1H-indole-3-methanamine
  • 2-Methoxy-6-(pyrazol-1-yl)-benzonitrile
  • 1H-3-Benzazepin-7-ol, 8-chloro-2,3,4,5-tetrahydro-5-(3-iodophenyl)-3-methyl-, (S)-
  • (4-Methyl-tetrahydro-furan-2-yl)-methanol
  • N-(1-cyanocyclopentyl)-2-[4-(4-fluorobenzenesulfonyl)-1,4-diazepan-1-yl]acetamide
  • 4,5,6,7-Tetrahydrobenzo[d]isoxazole-3-carbaldehyde
  • tert-Butyl-DL-alanine
  • 2-((2-Chloro-5-(trifluoromethyl)pyrimidin-4-yl)amino)-N-methylbenzamide
  • Cyclohexylmethyl diphenyl phosphate