Silane, trimethyl((2-methyl-1-propenyl)oxy)-

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Names

[ Name ]:
Silane, trimethyl((2-methyl-1-propenyl)oxy)-

[Synonym ]:
trimethyl[(2-methylprop-1-en-1-yl)oxy]silane
2-methyl-1-(trimethylsilyloxy)prop-1-ene
Silane, trimethyl((2-methyl-1-propenyl)oxy)-
2-Methyl-1-(trimethylsilyloxy)-1-propene
2-methyl-1-(trimethylsilyloxy)propene
trimethyl-(2-methyl-propenyloxy)-silane
2-methyl-1-(trimethylsiloxy)-1-propene
MFCD00192331
Silane, trimethyl[(2-methyl-1-propen-1-yl)oxy]-
TMSO-CH=C(Me)2
Trimethyl[(2-methyl-1-propen-1-yl)oxy]silane
ITSE

Chemical & Physical Properties

[ Density]:
0.8±0.1 g/cm3

[ Boiling Point ]:
119.3±8.0 °C at 760 mmHg

[ Molecular Formula ]:
C₇H₁₆OSi

[ Molecular Weight ]:
144.287

[ Flash Point ]:
15.6±8.3 °C

[ Exact Mass ]:
144.097046

[ PSA ]:
9.23000

[ LogP ]:
3.29

[ Vapour Pressure ]:
19.2±0.2 mmHg at 25°C

[ Index of Refraction ]:
1.414

[ Storage condition ]:
2~8℃，Seal

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS02, GHS07

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H225-H315-H319-H335

[ Precautionary Statements ]:
P210-P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
F,Xi

[ Risk Phrases ]:
11-36/37/38

[ Safety Phrases ]:
16-26-36

[ RIDADR ]:
UN 1993 3/PG 2

[ WGK Germany ]:
3

[ Packaging Group ]:
II

[ Hazard Class ]:
3.1

[ HS Code ]:
2931900090

Synthetic Route

Click to get detail synthetic route

Customs

[ HS Code ]: 2931900090

[ Summary ]:
2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%

Articles

Preparation of modified peptides: direct conversion of α-amino acids into β-amino aldehydes.

Org. Biomol. Chem. 10(22) , 4448-61, (2012)

A direct method for the transformation of α-amino acids into β-amino aldehydes was developed, and applied to the modification of the C-terminal residue of peptides. The method takes place in good yiel...

Induction of the SOS function sfiA in E. coli by systems which generate triplet ketones.

Mutat. Res. 198(1) , 53-60, (1988)

Generation of triplet ketones, either chemically through thermal decomposition of 3-hydroxymethyl-3,4,4-trimethyl-1,2-dioxetane and 3-[N-(pyridino)carbamoyl]methyl-3,4,4-trimethyl-1,2-dioxetane++ + or...

Generation of electronically excited triplet species at the cellular level: a potential source of genotoxicity.

Toxicol. Lett. 67(1-3) , 17-28, (1993)

Selected enzymatic systems can efficiently produce a product in the electronically excited triplet state. Earlier, only the formation of electronically excited singlet species was known. The formation...

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