1-(trimethylsilyloxy)-cyclohex-1-ene

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Names

[ CAS No. ]:
6651-36-1

[ Name ]:
1-(trimethylsilyloxy)-cyclohex-1-ene

[Synonym ]:
(1-Cyclohexen-1-yloxy)(trimethyl)silane
Silane, (1-cyclohexen-1-yloxy)trimethyl-
cyclohexen-1-yloxy(trimethyl)silane
Cyclohexene, 1-[(trimethylsilyl)oxy]-
(Cyclohex-1-en-1-yloxy)(trimethyl)silane
1-(trimethylsilyloxy)-cyclohex-1-ene
EINECS 229-675-1
MFCD00001541

Chemical & Physical Properties

[ Density]:
0.9±0.1 g/cm3

[ Boiling Point ]:
175.7±8.0 °C at 760 mmHg

[ Molecular Formula ]:
C9H18OSi

[ Molecular Weight ]:
170.324

[ Flash Point ]:
42.2±0.0 °C

[ Exact Mass ]:
170.112686

[ PSA ]:
9.23000

[ LogP ]:
3.86

[ Vapour Pressure ]:
1.5±0.3 mmHg at 25°C

[ Index of Refraction ]:
1.447

[ Storage condition ]:
2-8°C

MSDS

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Safety Information

[ Symbol ]:

GHS02

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H226

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
F: Flammable;

[ Risk Phrases ]:
R10

[ Safety Phrases ]:
S16

[ RIDADR ]:
UN 1993 3/PG 3

[ WGK Germany ]:
3

[ Packaging Group ]:
III

[ Hazard Class ]:
3

[ HS Code ]:
2931900090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • Chlorotrimethylsilane
  • Cyclohexanone
  • Trimethylsilyl trifluoromethanesulfonate
  • 2-trimethylsilyloctane-1,2-diol
  • 1-methoxy-1-trimethylsilyloxypropene
  • 1-Methoxy-1-(Trimethylsiloxy)-2-Methyl-1-Propene
  • magnesium,2-methylpropane
  • Ethyl (trimethylsilyl)acetate
  • Trimethylsilyl iodide
  • Cyclopentanone

DownStream

  • 2-diethoxyphosphorylcyclohexan-1-one
  • 2-[(4-bromophenyl)methylidene]cyclohexan-1-one
  • 2-Benzoylcyclohexanone
  • 2-Hydroxycyclohexanone
  • Adipic acid
  • Cyclohexanone
  • cyclohexenone
  • 2-trimethylsilyloxycyclohexan-1-one
  • 2-NITROCYCLOHEXANONE
  • trinitromethane

Customs

[ HS Code ]: 2931900090

[ Summary ]:
2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%

Articles

Organotin triflate as practical catalyst for Michael addition of enol silyl ethers. Sato T, et al.

Tetrahedron 47(47) , 9773-82, (1991)


More Articles

Related Compounds

  • 2-chloro-1-(trimethylsilyloxy)cyclohex-1-ene
  • 2-bromo-1-(trimethylsilyloxy)cyclohex-1-ene
  • 2-Methyl-1-cyclohex-1-ene carboxylic acid
  • Ethyl 2-methyl-1-cyclohex-1-ene carboxylate
  • 1-(bromomethyl)cyclohex-1-ene
  • 1-(bromodifluoromethyl)cyclohex-1-ene