2-Hydroxy-5-methoxybenzaldehyde

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Names

[ CAS No. ]:
672-13-9

[ Name ]:
2-Hydroxy-5-methoxybenzaldehyde

[Synonym ]:
2-Hydroxy-5-methoxybenzaldehyde
5-Methoxysalicylaldehyde
Salicylaldehyde,5-methoxy
2-hydroxy-5-methoxy benzaldehyde
Benzaldehyde,2-hydroxy-5-methoxy
Benzaldehyde, 2-hydroxy-5-methoxy-
EINECS 211-589-0
m-Anisaldehyde,6-hydroxy
6-Hydroxy-m-anisaldehyde
2-Hydroxy-5-methoxybenzolcarbaldehyd
5-methoxy-2-hydroxy benzaldehyde
2-hydroxy-5-methoxylbenzaldehyde
MFCD00003332

Chemical & Physical Properties

[ Density]:
1.2±0.1 g/cm3

[ Boiling Point ]:
247.5±0.0 °C at 760 mmHg

[ Melting Point ]:
4 °C(lit.)

[ Molecular Formula ]:
C8H8O3

[ Molecular Weight ]:
152.147

[ Flash Point ]:
108.1±15.3 °C

[ Exact Mass ]:
152.047348

[ PSA ]:
46.53000

[ LogP ]:
1.52

[ Vapour Pressure ]:
0.0±0.5 mmHg at 25°C

[ Index of Refraction ]:
1.588

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
BZ2800000
CHEMICAL NAME :
m-Anisaldehyde, 6-hydroxy-
CAS REGISTRY NUMBER :
672-13-9
BEILSTEIN REFERENCE NO. :
1100532
LAST UPDATED :
199612
DATA ITEMS CITED :
1
MOLECULAR FORMULA :
C8-H8-O3
MOLECULAR WEIGHT :
152.16
WISWESSER LINE NOTATION :
VHR BQ EO1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
125 mg/kg
TOXIC EFFECTS :
Behavioral - muscle contraction or spasticity Lungs, Thorax, or Respiration - dyspnea
REFERENCE :
CBCCT* "Summary Tables of Biological Tests," National Research Council Chemical-Biological Coordination Center. (National Academy of Science Library, 2101 Constitution Ave., NW, Washington, DC 20418) Volume(issue)/page/year: 6,228,1954

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xi:Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S36-S24/25

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ RTECS ]:
BZ2800000

[ HS Code ]:
29124900

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • Formaldehyde
  • Mequinol
  • 2,5-Dimethoxybenzaldehyde
  • 2-(1,3-dithiolan-2-yl)-4-methoxyphenol
  • Ethanol
  • Chloroform
  • Aminoform
  • 2-Iodo-5-methoxybenzaldehyde
  • m-Anisaldehyde

DownStream

  • 2-(Bromomethyl)-5-methoxy-1-benzofur
  • 5-METHOXYBENZOFURAN-2-CARBOXYLIC ACID,ETHYL ESTER
  • 3-bromo-2-hydroxy-5-methoxybenzaldehyde
  • 2-Hydroxy-5-methoxybenzonitrile
  • (6-FLUORO-1,2,3,4-TETRAHYDRO-NAPHTHALEN-2-YL)-ACETICACID
  • ETHANONE, 1-(5-METHOXY-2-BENZOFURANYL)-
  • Diethyl succinosuccinate
  • 5-methoxy-2-prop-2-ynoxybenzaldehyde
  • 5-METHOXYBENZOFURAN-2-CARBALDEHYDE

Customs

[ HS Code ]: 2912499000

[ Summary ]:
2912499000. other aldehyde-ethers, aldehyde-phenols and aldehydes with other oxygen function. VAT:17.0%. Tax rebate rate:9.0%. . MFN tariff:5.5%. General tariff:30.0%

Articles

Palladium(0)-mediated C-H bond activation of N-(naphthyl)salicylaldimine and related ligands: utilization of the resulting organopalladium complexes in catalytic C-C and C-N coupling reactions.

Dalton Trans. 44 , 13615-32, (2015)

N-(Naphthyl)-4-R-salicylaldimines (R = OCH(3), H and Cl; H(2L)(1)-H(2)L(3)) and 2-hydroxy-N-(naphthyl)naphthaldimine (H(2)L(4)) readily undergo, upon reaction with Na(2)[PdCl(4)] in the presence of tr...

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Related Compounds

  • 4-bromo-2-hydroxy-5-methoxybenzaldehyde
  • 3-bromo-2-hydroxy-5-methoxybenzaldehyde
  • 3-chloro-2-hydroxy-5-methoxybenzaldehyde
  • 4-Chloro-2-hydroxy-5-methoxybenzaldehyde
  • 2-hydroxy-5-methoxybenzaldehyde, sodium salt
  • 3-tert-butyl-2-hydroxy-5-methoxybenzaldehyde