1,3-Bis(diphenylphosphino)propane

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Names

[ CAS No. ]:
6737-42-4

[ Name ]:
1,3-Bis(diphenylphosphino)propane

[Synonym ]:
Phosphine, trimethylenebis[diphenyl-
MFCD00003050
Phosphine, 1,3-propanediylbis(diphenyl-
propane-1,3-diylbis(diphenylphosphane)
3-diphenylphosphanylpropyl(diphenyl)phosphane
1,3-bis(diphenylphosphino)propane
EINECS 229-791-2
1,3-Propanediylbis(diphenylphosphine)
Phosphine, 1,1'-(1,3-propanediyl)bis[1,1-diphenyl-
Propane-1,3-diylbis(diphenylphosphine)
DPPP

Chemical & Physical Properties

[ Boiling Point ]:
529.7±33.0 °C at 760 mmHg

[ Melting Point ]:
63-65 °C(lit.)

[ Molecular Formula ]:
C27H26P2

[ Molecular Weight ]:
412.443

[ Flash Point ]:
291.5±31.7 °C

[ Exact Mass ]:
412.150970

[ PSA ]:
27.18000

[ LogP ]:
8.95

[ Vapour Pressure ]:
0.0±1.3 mmHg at 25°C

[ Water Solubility ]:
insoluble

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi:Irritant

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S37/39

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
29310095

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • Lithium
  • 1,3-Dichloropropane
  • Triphenylphosphine
  • 1,3-Dibromopropane
  • Diphenylphosphine
  • 1-Bromo-3-chloropropane
  • Diphenylphosphine oxide
  • Methanol

DownStream

  • Methyl 4-(2-methoxy-2-oxoethyl)benzoate
  • Dibenzyl ether
  • Norbornadiene
  • Bis[1,2-bis(diphenylphosphino)ethane]palladium(0)
  • {Pd(C2H4)(1,3-bis(diphenylphosphino)propane)}
  • Phenyllithium
  • [1,3-Bis(diphenylphosphino)propane]palladium(II)Dichloride

Customs

[ HS Code ]: 2902909090

[ Summary ]:
2902909090 other aromatic hydrocarbons。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:2.0%。General tariff:30.0%

Articles

The cytotoxic and growth inhibitory effects of palladium(II) complexes on MDA-MB-435 cells.

Genet. Mol. Biol. 35 , 159-63, (2012)

The antitumorigenic potential of two palladium(II) complexes, [Pd(ca(2)-o-phen)Cl(2)] - C1 and [Pd(dmba)(dppp)Cl] - C2, was evaluated, using MDA-MB-435 cells, a human breast adenocarcinoma cell-line t...


More Articles

Related Compounds

  • [1,3-Bis(diphenylphosphino)propane]n
  • RhH(1,3-bis(diphenylphosphino)propane)2
  • [Ni(1,3-bis(diphenylphosphino)propane)2]
  • 1,3-bis(diphenylphosphino)propane dioxide
  • Cr(CO)4(1,3-bis(diphenylphosphino)propane)
  • 1,3-bis(diphenylphosphino)propane monooxide
  • N-(3,3-Dimethylbutyl)-2-methoxycyclopentanamine
  • tert-Butyl 4-(5-(1-aminoethyl)-6-methylpyridin-2-yl)piperazine-1-carboxylate
  • Tert-butyl 4-{3-[4-(methylsulfonyl)benzyl]-1,2,4-oxadiazol-5-yl}piperidine-1-carboxylate
  • tert-Butyl 4-(5-(1-aminopropyl)-6-methylpyridin-2-yl)piperazine-1-carboxylate
  • 3-{bicyclo[2.2.1]heptan-2-yl}-1-methyl-1H-pyrazol-5-amine
  • tert-Butyl 4-(5-(tert-butylthio)-6-methylpyridin-2-yl)piperazine-1-carboxylate
  • (Benzo[b]thiophene-2-carbonyl)-carbamic acid ethynyl ester
  • 4-(5-Formyl-6-methylpyridin-2-yl)piperazine-1-carbaldehyde
  • I+/--Bicyclo[2.2.1]hept-2-yl-1H-imidazole-2-ethanamine
  • Methyl 6-(4-formylpiperazin-1-yl)-2-methylnicotinate
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