2,4-dimethylanisole

Names

[ CAS No. ]:
6738-23-4

[ Name ]:
2,4-dimethylanisole

[Synonym ]:
EINECS 229-794-9
1-methoxy-2,4-dimethylbenzene
MFCD00008377

Chemical & Physical Properties

[ Density]:
0.973 g/mL at 25 °C(lit.)

[ Boiling Point ]:
191 °C(lit.)

[ Molecular Formula ]:
C₉H₁₂O

[ Molecular Weight ]:
136.19100

[ Flash Point ]:
146 °F

[ Exact Mass ]:
136.08900

[ PSA ]:
9.23000

[ LogP ]:
2.31200

[ Index of Refraction ]:
n20/D 1.514(lit.)

MSDS

Safety Information

[ Symbol ]:

GHS05, GHS07

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H302-H315-H318-H335

[ Precautionary Statements ]:
P261-P280-P305 + P351 + P338

[ Hazard Codes ]:
Xn

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S24/25

[ RIDADR ]:
3271

[ WGK Germany ]:
3

[ HS Code ]:
2909309090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

2,4-xylenol
methyl iodide
1,4-dimethoxy-1,4-dimethyl-2,5-cyclohexadiene
Tetramethyl ammonium chloride
(Trimethylsilyl)diazomethane
Dimethyl sulfate
4-Methylanisole
4-Methoxy-3-methylbenzaldehyde
2-(chloromethyl)-1-methoxy-4-methylbenzene
2-Methoxy-5-methylbenzaldehyde

DownStream

4-Methoxy-3-methylbenzaldehyde
2-METHOXY-5-METHYLBENZOIC ACID
4-Hydroxyisophthalic acid
2,4-Dimethyl-6-nitrophenol
3',5'-Dimethyl-2'-hydroxyacetophenone
2,4-xylenol
CHEMBRDG-BB 4016822
Dimethyl 4-methoxyisophthalate
4-Methoxyisophthalic acid

Customs

[ HS Code ]: 2909309090

[ Summary ]:
2909309090 other aromatic ethers and their halogenated, sulphonated, nitrated or nitrosated derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%

Articles

Reactions of the 1-hydroxy-1, 4-dimethylcyclohexadienyl cation, an intermediate in the solvolysis of 1, 4-dimethyl-4-nitrocyclohexa-2, 5-dien-1-ol. Fischer A, et al.

Can. J. Chem. 64(6) , 1093-1101, (1986)

Photochemical Nitration by Tetranitromethane. Part XXXVII. t Adduct Formation and the Regiochemistry of Attack of Trinitromethanide Ion on Radical Cations in the Photochemical Reactions of 2-Methyl-, 2, 3-Dimethyl-and 2, 4-Dimethylanisoles. Timmerman-Vaughan DJ.

Acta Chem. Scand. 51(19971) , 73-87, (1997)

The role of ion-molecule pair intermediates in acid-catalyzed solvolysis. General base-catalyzed formation of 4-methylbenzyl carbocation and its trapping by nucleophiles. Thibblin A.

J. Org. Chem. 58(26) , 7427-7433, (1993)

2,4-Dibromo-1-methoxy-3,5-dimethylbenzene
2-(4-(4-CHLOROBUTANOYL)PHENYL)-2-METHYLPROPANOIC ACID
2,4-dibromo-N-ethylaniline
2,4-Dibromo-6-methylpyridine
2-[(4-methylphenyl)sulfonylmethyl]benzo[f][1,3]benzodioxole
2,4-bis(trifluoromethyl)benzonitrile
2-[7-(4-chlorophenyl)-4-oxothieno[3,2-d]pyrimidin-3(4H)-yl]-N-(2,5-dimethoxyphenyl)acetamide
2-[7-(4-chlorophenyl)-4-oxothieno[3,2-d]pyrimidin-3(4H)-yl]-N-(3,4-dimethoxyphenyl)acetamide
2-[7-(4-chlorophenyl)-4-oxothieno[3,2-d]pyrimidin-3(4H)-yl]-N-(3,4,5-trimethoxyphenyl)acetamide
methyl 2-({[7-(4-chlorophenyl)-4-oxothieno[3,2-d]pyrimidin-3(4H)-yl]acetyl}amino)benzoate
methyl 4-({[7-(4-chlorophenyl)-4-oxothieno[3,2-d]pyrimidin-3(4H)-yl]acetyl}amino)benzoate
ethyl 4-({[7-(4-chlorophenyl)-4-oxothieno[3,2-d]pyrimidin-3(4H)-yl]acetyl}amino)benzoate
N-[4-(acetylamino)phenyl]-2-[7-(4-chlorophenyl)-4-oxothieno[3,2-d]pyrimidin-3(4H)-yl]acetamide
7-(3-chlorophenyl)-3-[2-(4-fluorophenoxy)ethyl]thieno[3,2-d]pyrimidin-4(3H)-one
7-(4-chlorophenyl)-3-(4-fluorobenzyl)thieno[3,2-d]pyrimidin-4(3H)-one
3-[4-(4-Bromophenyl)-3-oxo-3,4-dihydropyrazin-2-yl]-1-(3,5-dimethylphenyl)urea

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