Cyanuric fluoride

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Names

[ CAS No. ]:
675-14-9

[ Name ]:
Cyanuric fluoride

[Synonym ]:
2,4,6-trifluorotriazine
1,3,5-Triazine, 2,4,6-trifluoro-
2,4,6-trifluoro-s-triazine
1,3,5-trifluoro-2,4,6-triazine
2,4,6-tri-fluoro-1,3,5-triazine
Trifluoro-s-triazine
MFCD00014597
2,4,6-trifluro-s-triazin
cyanuric trifluoride
Cyanuric Flouride
EINECS 211-620-8
2,4,6-Trifluoro-1,3,5-triazine
Cyanuric fluoride
Cyanuricfluoride
Trifluoro-1,3,5-triazine
Trifluorotriazine

Chemical & Physical Properties

[ Density]:
1.7±0.1 g/cm3

[ Boiling Point ]:
316.1±25.0 °C at 760 mmHg

[ Melting Point ]:
-38°C

[ Molecular Formula ]:
C₃F₃N₃

[ Molecular Weight ]:
135.047

[ Flash Point ]:
145.0±23.2 °C

[ Exact Mass ]:
135.004425

[ PSA ]:
38.67000

[ LogP ]:
1.21

[ Vapour Pressure ]:
0.0±0.6 mmHg at 25°C

[ Index of Refraction ]:
1.416

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :: XZ1750000

CHEMICAL NAME :: s-Triazine, 2,4,6-trifluoro-

CAS REGISTRY NUMBER :: 675-14-9

BEILSTEIN REFERENCE NO. :: 0124237

LAST UPDATED :: 199709

DATA ITEMS CITED :: 3

MOLECULAR FORMULA :: C3-F3-N3

MOLECULAR WEIGHT :: 135.06

WISWESSER LINE NOTATION :: T6N CN ENJ BF DF FF

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LC50 - Lethal concentration, 50 percent kill

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 3100 ppb/4H

TOXIC EFFECTS :: Behavioral - excitement Lungs, Thorax, or Respiration - chronic pulmonary edema Lungs, Thorax, or Respiration - dyspnea

REFERENCE :: AIHAAP American Industrial Hygiene Association Journal. (AIHA, 475 Wolf Ledges Pkwy., Akron, OH 44311) V.19- 1958- Volume(issue)/page/year: 33,382,1972

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rabbit

DOSE/DURATION :: 160 mg/kg

TOXIC EFFECTS :: Sense Organs and Special Senses (Eye) - lacrimation Lungs, Thorax, or Respiration - bronchiolar constriction Tumorigenic - Carcinogenic by RTECS criteria

REFERENCE :: AIHAAP American Industrial Hygiene Association Journal. (AIHA, 475 Wolf Ledges Pkwy., Akron, OH 44311) V.19- 1958- Volume(issue)/page/year: 33,382,1972

Safety Information

[ Symbol ]:

GHS05, GHS06

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H310 + H330-H314

[ Precautionary Statements ]:
P260-P280-P284-P302 + P350-P305 + P351 + P338-P310

[ Personal Protective Equipment ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
T+:Verytoxic;C:Corrosive;

[ Risk Phrases ]:
R24;R26;R35

[ Safety Phrases ]:
S26-S28-S36/37/39-S45

[ RIDADR ]:
UN 3389 6.1/PG 1

[ WGK Germany ]:
3

[ RTECS ]:
XZ1750000

[ Packaging Group ]:
I

[ Hazard Class ]:
6.1

[ HS Code ]:
2933699090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

Cyanuric chloride
Trifluorostibine
sulfur(+2) tetrahydride cation tetrafluoride
cyanogen fluoride
2-chloro-4,6-difluoro-1,3,5-triazine
2,4-dichloro-6-fluoro-[1,3,5]triazine
cyanogen iodide
bis{bis(trifluoromethyl)amino} mercury
Cyanogen chloride
FERROCENE

DownStream

1,3,5-Triazine-2,4,6-triamine,N2,N4,N6-triphenyl-
nitrogen trifluoride
Carbon tetrafluoride
Perfluor-(1,4-diazapent-2-en)
cyanogen fluoride
Trifluoroacetonitrile
1,1-difluoro-N-(trifluoromethyl)methanimine
2,4,6-TRIMETHOXY-S-TRIAZINE

Customs

[ HS Code ]: 2933699090

[ Summary ]:
2933699090 other compounds containing an unfused triazine ring (whether or not hydrogenated) in the structure。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:6.5%。General tariff:20.0%

Articles

[43] cyanuration.

Meth. Enzymol. 25 , 506, (1972)

Cyanuric fluoride (CyF) is introduced as a tyrosine modifying reagent. The reason that CyF may be considered as a very reactive acid halide, cyanuration of tyrosine should give the O-derivative, in co...

Chemical reactivity of the tyrosyl residues in yeast hexokinase. Properties of the nitroenzyme.

Biochim. Biophys. Acta 484 , 322, (1977)

Reactivity of acid fluoride-terminated self-assembled monolayers on gold.

Langmuir 23(3) , 1209-14, (2007)

This report describes the reactivity of acid fluoride (AF)-terminated self-assembled monolayers (SAMs) on gold toward amine and alcohol compounds and the potentiality of AF as a reactive intermediate ...