3-Chloro-o-xylene

Suppliers

Names

[ CAS No. ]:
6781-98-2

[ Name ]:
3-Chloro-o-xylene

[Synonym ]:
Benzene, 1-chloro-2,3-dimethyl-
Benzene, 2-chloro-1,3-dimethyl-
2,6-dimethylphenyl chloride
4-Chloro-3,5-dimethylbenzene
Benzene,2-chloro-1,3-dimethyl
2,6-Dimethyl Chlorobenzene
1-chloro-2,6-dimethylbenzene
Benzene, chlorodimethyl-
MFCD00000565
1-Chloro-2,3-dimethylbenzene
2-chloro-m-xylene
m-Xylene,2-chloro
EINECS 229-843-4
2-Chloro-1,3-dimethylbenzene
3-Chloro-o-xylene
1,3-dimethyl-2-chlorobenzene

Chemical & Physical Properties

[ Density]:
1.0±0.1 g/cm3

[ Boiling Point ]:
186.0±0.0 °C at 760 mmHg

[ Melting Point ]:
−36 °C(lit.)

[ Molecular Formula ]:
C8H9Cl

[ Molecular Weight ]:
140.610

[ Flash Point ]:
63.3±0.0 °C

[ Exact Mass ]:
140.039276

[ LogP ]:
3.73

[ Vapour Pressure ]:
0.9±0.3 mmHg at 25°C

[ Index of Refraction ]:
1.521

MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xn:Harmful;

[ Risk Phrases ]:
R20/21;R36/37/38

[ Safety Phrases ]:
S26-S36/37/39-S36/37-S23

[ RIDADR ]:
1993

[ WGK Germany ]:
3

[ Packaging Group ]:
I; II; III

[ HS Code ]:
2903999090

Synthetic Route

Precursor & DownStream

Precursor

  • (2,6-dimethylphenyl) chloroformate
  • 3,5-Dimethylphenylboronic acid
  • 2,6-Dimethylbromobenzene
  • Chloroform
  • 4-Chloro-1,2-dimethylcyclopentene
  • m-Xylene
  • 2,6-xylidine
  • 2,6-Xylenol
  • 1,2,4-Trichlorobenzene
  • o-xylene

DownStream

  • 2-(4-chloro-3,5-dimethylphenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
  • 1,2,3-Trimethylbenzene
  • 1,1,3,3-tetramethyl-1,3-dihydrobenzo[c][1,2]oxasilole
  • 2,6-Dimethylbenzanilide
  • 2-ethenyl-1,3-dimethylbenzene
  • m-Xylene
  • DIMETHYLBIPHENYL
  • 1,3-dimethyl-2-(2-methylphenyl)benzene
  • Toluene
  • 2,6-xylidine

Customs

[ HS Code ]: 2903999090

[ Summary ]:
2903999090 halogenated derivatives of aromatic hydrocarbons VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%

Articles

A practical heterogeneous catalyst for the Suzuki, Sonogashira, and Stille coupling reactions of unreactive aryl chlorides.

Angew. Chem. Int. Ed. Engl. 49(6) , 1119-22, (2010)

A new palladium catalyst system for the cyanation of aryl chlorides with K4[Fe(CN)6]. Schareina T, et al.

Tetrahedron Lett. 48(7) , 1087-90, (2007)


More Articles


Related Compounds

  • 3-Chloro-o-xylene
  • 5-tert-amyl-3-chloro-o-xylene
  • 4-tert-amyl-3-chloro-o-xylene
  • 4-tert-butyl-3-chloro-o-xylene
  • 5-tert-butyl-3-chloro-o-xylene
  • 3-chloro-O-deuterio-phenol
  • 2-(Toluene-4-sulfonyl)-hexahydro-cyclopenta[C]pyrrole-5,5-dicarboxylic acid diethyl ester
  • 1h-Pyrrolo[2,3-b]pyridine,5-fluoro-2-[1-(2-iodoethyl)-5,6-dimethoxy-1h-pyrrolo[3,2-b]pyridin-3-yl]-1-[(4-methylphenyl)sulfonyl]-
  • 1h-Pyrrolo[3,2-b]pyridine-1-carboxylic acid,3-[4-chloro-5-fluoro-1-[(4-methylphenyl)sulfonyl]-1h-pyrrolo[2,3-b]pyridin-2-yl]-5,6-dimethoxy-,1,1-dimethylethyl ester
  • N-((1H-Imidazol-2-yl)methyl)-2-(piperidin-1-yl)ethan-1-amine
  • 3-Benzyloxy-7-methoxynaphthalen-2-ylamine
  • 2-Cyclopropyl-1-(4-ethoxyphenyl)ethan-1-one
  • 1-(4-Amino-piperidin-1-yl)-2-cyclopropyl-ethanone
  • 2-Cyclopropyl-1-piperazin-1-yl-ethanone
  • 4-(6-Aminopyridin-3-yl)-1-methylpiperazin-2-one
  • 4-(4-Amino-2-pyridinyl)-1-methyl-2-piperazinone
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