3-Chloro-o-xylene

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Names

[ CAS No. ]:
6781-98-2

[ Name ]:
3-Chloro-o-xylene

[Synonym ]:
Benzene, 1-chloro-2,3-dimethyl-
Benzene, 2-chloro-1,3-dimethyl-
2,6-dimethylphenyl chloride
4-Chloro-3,5-dimethylbenzene
Benzene,2-chloro-1,3-dimethyl
2,6-Dimethyl Chlorobenzene
1-chloro-2,6-dimethylbenzene
Benzene, chlorodimethyl-
MFCD00000565
1-Chloro-2,3-dimethylbenzene
2-chloro-m-xylene
m-Xylene,2-chloro
EINECS 229-843-4
2-Chloro-1,3-dimethylbenzene
3-Chloro-o-xylene
1,3-dimethyl-2-chlorobenzene

Chemical & Physical Properties

[ Density]:
1.0±0.1 g/cm3

[ Boiling Point ]:
186.0±0.0 °C at 760 mmHg

[ Melting Point ]:
−36 °C(lit.)

[ Molecular Formula ]:
C8H9Cl

[ Molecular Weight ]:
140.610

[ Flash Point ]:
63.3±0.0 °C

[ Exact Mass ]:
140.039276

[ LogP ]:
3.73

[ Vapour Pressure ]:
0.9±0.3 mmHg at 25°C

[ Index of Refraction ]:
1.521

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xn:Harmful;

[ Risk Phrases ]:
R20/21;R36/37/38

[ Safety Phrases ]:
S26-S36/37/39-S36/37-S23

[ RIDADR ]:
1993

[ WGK Germany ]:
3

[ Packaging Group ]:
I; II; III

[ HS Code ]:
2903999090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • (2,6-dimethylphenyl) chloroformate
  • 3,5-Dimethylphenylboronic acid
  • 2,6-Dimethylbromobenzene
  • Chloroform
  • 4-Chloro-1,2-dimethylcyclopentene
  • m-Xylene
  • 2,6-xylidine
  • 2,6-Xylenol
  • 1,2,4-Trichlorobenzene
  • o-xylene

DownStream

  • 2-(4-chloro-3,5-dimethylphenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
  • 1,2,3-Trimethylbenzene
  • 1,1,3,3-tetramethyl-1,3-dihydrobenzo[c][1,2]oxasilole
  • 2,6-Dimethylbenzanilide
  • 2-ethenyl-1,3-dimethylbenzene
  • m-Xylene
  • DIMETHYLBIPHENYL
  • 1,3-dimethyl-2-(2-methylphenyl)benzene
  • Toluene
  • 2,6-xylidine

Customs

[ HS Code ]: 2903999090

[ Summary ]:
2903999090 halogenated derivatives of aromatic hydrocarbons VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%

Articles

A practical heterogeneous catalyst for the Suzuki, Sonogashira, and Stille coupling reactions of unreactive aryl chlorides.

Angew. Chem. Int. Ed. Engl. 49(6) , 1119-22, (2010)

A new palladium catalyst system for the cyanation of aryl chlorides with K4[Fe(CN)6]. Schareina T, et al.

Tetrahedron Lett. 48(7) , 1087-90, (2007)


More Articles

Related Compounds

  • 3-Chloro-o-xylene
  • 5-tert-amyl-3-chloro-o-xylene
  • 4-tert-amyl-3-chloro-o-xylene
  • 4-tert-butyl-3-chloro-o-xylene
  • 5-tert-butyl-3-chloro-o-xylene
  • 3-chloro-O-deuterio-phenol
  • methyl 5-amino-1-(4-methylphenyl)-4-(oxolan-3-yl)-1H-pyrazole-3-carboxylate
  • methyl 5-amino-1-tert-butyl-4-(oxolan-3-yl)-1H-pyrazole-3-carboxylate
  • methyl 5-amino-4-(oxan-4-yl)-1-(2,2,2-trifluoroethyl)-1H-pyrazole-3-carboxylate
  • methyl 5-amino-4-(oxan-4-yl)-1-propyl-1H-pyrazole-3-carboxylate
  • methyl 5-amino-4-tert-butyl-1-(2,2,2-trifluoroethyl)-1H-pyrazole-3-carboxylate
  • methyl 5-amino-4-(2,2-dimethylpropyl)-1-ethyl-1H-pyrazole-3-carboxylate
  • 2-amino-3-(4,5-diiodo-1H-imidazol-1-yl)butanoic acid
  • 2-amino-3-[2-(propan-2-yl)-1H-imidazol-1-yl]butanoic acid
  • 2-amino-3-(2-propyl-1H-imidazol-1-yl)butanoic acid
  • 2-amino-3-(4-ethoxy-1H-pyrazol-1-yl)butanoic acid
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