Dimethylcyanoarsine

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Names

[ CAS No. ]:
683-45-4

[ Name ]:
Dimethylcyanoarsine

[Synonym ]:
Kakodylcyanid
dimethylcyanarsine
Dimethylarsencyanid
ARSINE,CYANODIMETHYL
Dimethylarsine cyanide
cyano-dimethyl-arsine
Dimethyl-cyano-arsin
Dimethylarsinous cyanide
Cyan-dimethyl-arsin
Arsinous cyanide,dimethyl
Dimethyl-cyan-arsin
Dimethylcyanoarsine

Chemical & Physical Properties

[ Boiling Point ]:
99ºC at 760 mmHg

[ Molecular Formula ]:
C3H6AsN

[ Molecular Weight ]:
131.00800

[ Flash Point ]:
4.2ºC

[ Exact Mass ]:
130.97200

[ PSA ]:
23.79000

[ LogP ]:
0.80358

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
CH2100000
CHEMICAL NAME :
Arsine, cyanodimethyl-
CAS REGISTRY NUMBER :
683-45-4
BEILSTEIN REFERENCE NO. :
1737194
LAST UPDATED :
199612
DATA ITEMS CITED :
8
MOLECULAR FORMULA :
C3-H6-As-N
MOLECULAR WEIGHT :
131.02
WISWESSER LINE NOTATION :
NC-AS-1&1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
50 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
NCNSA6 National Academy of Sciences, National Research Council, Chemical-Biological Coordination Center, Review. (Washington, DC) Volume(issue)/page/year: 5,13,1953
TYPE OF TEST :
LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
400 mg/m3/15M
TOXIC EFFECTS :
Gastrointestinal - other changes Blood - other changes Skin and Appendages - hair
REFERENCE :
ZGEMAZ Zeitschrift fuer die Gesamte Experimentelle Medizin. (Berlin, Fed. Rep. Ger.) V.1-139, 1913-65. For publisher information, see REXMAS. Volume(issue)/page/year: 13,523,1921
TYPE OF TEST :
LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Mammal - dog
DOSE/DURATION :
900 mg/m3/8M
TOXIC EFFECTS :
Sense Organs and Special Senses (Eye) - corneal damage Behavioral - excitement Lungs, Thorax, or Respiration - other changes
REFERENCE :
ZGEMAZ Zeitschrift fuer die Gesamte Experimentelle Medizin. (Berlin, Fed. Rep. Ger.) V.1-139, 1913-65. For publisher information, see REXMAS. Volume(issue)/page/year: 13,523,1921
TYPE OF TEST :
LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Mammal - cat
DOSE/DURATION :
100 mg/m3/5M
TOXIC EFFECTS :
Lungs, Thorax, or Respiration - other changes Gastrointestinal - changes in structure or function of salivary glands Gastrointestinal - nausea or vomiting
REFERENCE :
ZGEMAZ Zeitschrift fuer die Gesamte Experimentelle Medizin. (Berlin, Fed. Rep. Ger.) V.1-139, 1913-65. For publisher information, see REXMAS. Volume(issue)/page/year: 13,523,1921 *** U.S. STANDARDS AND REGULATIONS *** OSHA PEL (Gen Indu):8H TWA 0.5 mg(As)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1910.1000,1994 OSHA PEL (Construc):8H TWA 0.5 mg(As)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1926.55,1994 OSHA PEL (Shipyard):8H TWA 0.5 mg(As)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1915.1000,1993 OSHA PEL (Fed Cont):8H TWA 0.5 mg(As)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 41,50-204.50,1994

Safety Information

[ HS Code ]:
2931900090

Synthetic Route

Precursor & DownStream

Precursor

  • chlorodimethylarsine
  • Sodium cyanide
  • POTASSIUM CYANIDE
  • dimethylarsanyloxy(dimethyl)arsane
  • HYDROGEN CYANIDE

DownStream

  • Silver cyanide
  • Arsonium, tetramethyl-,iodide (8CI,9CI)
  • tetramethyl-arsonium, triiodide

Customs

[ HS Code ]: 2931900090

[ Summary ]:
2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%


Related Compounds

  • 4-((Cyclohexylamino)methyl)benzoic acid hydrochloride
  • 1-[(2,4-Dichlorophenyl)methyl]-N-(1,1-dimethylethyl)-2-methyl-1H-indole-3-methanamine
  • 2-Methoxy-6-(pyrazol-1-yl)-benzonitrile
  • 1H-3-Benzazepin-7-ol, 8-chloro-2,3,4,5-tetrahydro-5-(3-iodophenyl)-3-methyl-, (S)-
  • (4-Methyl-tetrahydro-furan-2-yl)-methanol
  • N-(1-cyanocyclopentyl)-2-[4-(4-fluorobenzenesulfonyl)-1,4-diazepan-1-yl]acetamide
  • 4,5,6,7-Tetrahydrobenzo[d]isoxazole-3-carbaldehyde
  • 2-Chloro-1-(4-ethoxypiperidin-1-yl)ethan-1-one
  • tert-Butyl-DL-alanine
  • 4-amino-N-[2-tert-butyl-1-(tetrahydro-2H-pyran-4-ylmethyl)-1H-benzimidazol-5-yl]-N-ethylbenzenesulfonamide