2-Bromoacetamide

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Names

[ CAS No. ]:
683-57-8

[ Name ]:
2-Bromoacetamide

[Synonym ]:
Bromoacetamide
EINECS 226-270-1
Acetamide, 2-bromo-
MFCD00008025
2-Bromoacetamide

Chemical & Physical Properties

[ Density]:
1.8±0.1 g/cm3

[ Boiling Point ]:
271.6±23.0 °C at 760 mmHg

[ Melting Point ]:
87-91 °C(lit.)

[ Molecular Formula ]:
C2H4BrNO

[ Molecular Weight ]:
137.963

[ Flash Point ]:
118.1±22.6 °C

[ Exact Mass ]:
136.947617

[ PSA ]:
43.09000

[ LogP ]:
-0.52

[ Vapour Pressure ]:
0.0±0.6 mmHg at 25°C

[ Index of Refraction ]:
1.511

[ Storage condition ]:
Store at RT.

MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
AB4587000
CHEMICAL NAME :
Acetamide, 2-bromo-
CAS REGISTRY NUMBER :
683-57-8
BEILSTEIN REFERENCE NO. :
1739073
LAST UPDATED :
199612
DATA ITEMS CITED :
3
MOLECULAR FORMULA :
C2-H4-Br-N-O
MOLECULAR WEIGHT :
137.98
WISWESSER LINE NOTATION :
ZV1E

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Unreported
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
124 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
YHTPAD Yaoxue Tongbao. Bulletin of Pharmacology. (China International Book Trading Corp., POB 2820, Beijing, Peop. Rep. China) V.13-23, 1978-88. For publisher information, see ZYZAEU. Volume(issue)/page/year: 16(8),54,1981
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Unreported
SPECIES OBSERVED :
Mammal - dog
DOSE/DURATION :
>102 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
YHTPAD Yaoxue Tongbao. Bulletin of Pharmacology. (China International Book Trading Corp., POB 2820, Beijing, Peop. Rep. China) V.13-23, 1978-88. For publisher information, see ZYZAEU. Volume(issue)/page/year: 16(8),54,1981
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Unreported
SPECIES OBSERVED :
Rodent - rabbit
DOSE/DURATION :
61 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
YHTPAD Yaoxue Tongbao. Bulletin of Pharmacology. (China International Book Trading Corp., POB 2820, Beijing, Peop. Rep. China) V.13-23, 1978-88. For publisher information, see ZYZAEU. Volume(issue)/page/year: 16(8),54,1981

Safety Information

[ Symbol ]:

GHS05, GHS06

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H301-H314

[ Precautionary Statements ]:
P280-P301 + P310-P305 + P351 + P338-P310

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges

[ Hazard Codes ]:
T,C

[ Risk Phrases ]:
R25;R34

[ Safety Phrases ]:
S26-S27-S36/37/39-S45

[ RIDADR ]:
UN 2923 8/PG 2

[ WGK Germany ]:
3

[ RTECS ]:
AB4587000

[ Packaging Group ]:
III

[ Hazard Class ]:
8

[ HS Code ]:
2924199013

Synthetic Route

Precursor & DownStream

Precursor

  • Bromoacetyl bromide
  • Bromoacetyl chloride
  • Sulforhodamine 101
  • ketene
  • 2-bromo-N-chloroacetamide
  • ethyl 2-bromoacetate
  • Bromoacetonitrile
  • 2-bromo-acetimidoyl bromide
  • Cyclohexene
  • Bromoacetic acid

DownStream

  • 2-PHENYL-5-OXAZOLONE
  • Acetamide
  • Bromoacetonitrile
  • 2-[(Diphenylmethyl)Thio]Acetamide
  • (E)-2-(5-Bromo-2-(tosylimino)pyridin-1(2H)-yl)acetamide
  • 2-(3-Nitro-1H-pyrazol-1-yl)acetamide
  • 2,2',2'',2'''-(1,4,7,10-Tetraazacyclododecane-1,4,7,10-tetrayl)tetraacetamide
  • Piperazine-2,6-dione
  • 1,4,8,11-Tetrakis(aminocarbonylmethyl)-1,4,8,11-tetraazacyclotetradecane
  • 2-(6-chloro-2-oxo-4-phenyl-4H-3,1-benzoxazin-1-yl)acetamide

Customs

[ HS Code ]: 2924199013

[ Summary ]:
HS:2924199013 2-bromoacetamide VAT:17.0% Tax rebate rate:0.0% Supervision conditions:S MFN tariff:6.5% General tariff:30.0%

Articles

Carborane-derived local anesthetics are isomer dependent.

ChemMedChem 10(1) , 62-7, (2014)

Clinically there is a need for local anesthetics with a greater specificity of action on target cells and longer duration. We have synthesized a series of local anesthetic derivatives we call boronica...

(N)-methanocarba 2,N6-disubstituted adenine nucleosides as highly potent and selective A3 adenosine receptor agonists.

J. Med. Chem. 48(6) , 1745-58, (2005)

A series of ring-constrained (N)-methanocarba-5'-uronamide 2,N(6)-disubstituted adenine nucleosides have been synthesized via Mitsunobu condensation of the nucleobase precursor with a pseudosugar ring...

Kinetic analysis of sequence-specific alkylation of DNA by pyrimidine oligodeoxyribonucleotide-directed triple-helix formation.

Bioconjug. Chem. 8(3) , 354-64, (1997)

Attachment of a nondiffusible bromoacetyl electrophile to the 5-position of a thymine at the 5'-end of a pyrimidine oligodeoxyribonucleotide affords sequence-specific alkylation of a guanine base in d...


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Related Compounds

  • 2-BROMOACETAMIDE-1-14C
  • N-Benzyl-2-bromoacetamide
  • N-acetyl-2-bromoacetamide
  • N-Methyl-2-bromoacetamide
  • N-p-tolyl-2-bromoacetamide
  • N-isobutyl 2-bromoacetamide
  • Benzenamine, 2-bromo-4-cyclopropyl-3-fluoro-
  • Methylium, (4-chlorophenyl)difluoro-
  • 5,5-Dimethylpyrrolidine-2-carbonitrile hcl
  • 5-Amino-1,2,4-thiadiazole-3-carbonitrile hydroiodide
  • 1-(Azidomethyl)-2,2-difluoro-3-methylbicyclo[1.1.1]pentane
  • 1-(5-Fluoropyrimidin-4-yl)pyrrolidin-3-amine
  • 1-(Methylamino)-4-oxocyclohexane-1-carbonitrile
  • N,6-dimethyl-2,3-dihydro-1H-inden-1-amine hydrochloride
  • 2-(3-Amino-1,1,1-trifluoropropan-2-yl)-4-methoxyphenol
  • Tert-butyl 3-[(1,4-diazepan-1-yl)methyl]azetidine-1-carboxylate
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