Dichloro(dimethylamino)phosphine

Names

[ CAS No. ]:
683-85-2

[ Name ]:
Dichloro(dimethylamino)phosphine

[Synonym ]:
MFCD00013613
N-dichlorophosphanyl-N-methylmethanamine

Chemical & Physical Properties

[ Density]:
1.271 g/mL at 25 °C(lit.)

[ Boiling Point ]:
150 °C(lit.)

[ Molecular Formula ]:
C₂H₆Cl₂NP

[ Molecular Weight ]:
145.95600

[ Flash Point ]:
−10 °F

[ Exact Mass ]:
144.96100

[ PSA ]:
16.83000

[ LogP ]:
2.25250

[ Index of Refraction ]:
n20/D 1.505(lit.)

[ Storage condition ]:
Refrigerator (+4°C) + Flammables area

MSDS

Safety Information

[ Symbol ]:

GHS02, GHS05

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H225-H314

[ Supplemental HS ]:
Reacts violently with water.

[ Precautionary Statements ]:
P210-P280-P305 + P351 + P338-P310

[ Personal Protective Equipment ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
F: Flammable;C: Corrosive;

[ Risk Phrases ]:
R11

[ Safety Phrases ]:
S16-S23-S26-S27-S36/37/39-S45

[ RIDADR ]:
UN 2924 3/PG 2

[ WGK Germany ]:
3

[ Packaging Group ]:
II

[ Hazard Class ]:
3

[ HS Code ]:
2929909090

Synthetic Route

Click to get detail synthetic route

Customs

[ HS Code ]: 2929909090

[ Summary ]:
2929909090 other compounds with other nitrogen function VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

Articles

Synthesis and biological evaluation of fluorinated deoxynucleotide analogs based on bis-(difluoromethylene)triphosphoric acid.

Proc. Natl. Acad. Sci. U. S. A. 107(36) , 15693-15698, (2010)

It is difficult to overestimate the importance of nucleoside triphosphates in cellular chemistry: They are the building blocks for DNA and RNA and important sources of energy. Modifications of biologi...

Equilibrium conformation of dimethylaminodichlorophosphine molecule: the use of the results of quantum-chemical calculations and spectroscopic measurements in the analysis of gas-phase electron diffraction data. Khaikin LS, et al.

Russ. Chem. Bull. 50(9) , 1550-1562, (2001)

Dimethylaminodimethylphosphine¹. Burg AB and Slota Jr PJ.

J. Am. Chem. Soc. 80(5) , 1107-1109, (1958)

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