2-Bromo-2'-nitroacetophenone

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Names

[ CAS No. ]:
6851-99-6

[ Name ]:
2-Bromo-2'-nitroacetophenone

[Synonym ]:
Ethanone, 2-bromo-1-(2-nitrophenyl)-
Ethanone,2-broMo-1-(2-nitrophenyl)
2'-Nitro-
1-(2-Nitrophenyl)-2-bromoethanone
2-Bromo-2`-nitroacetophenone
2-Bromo-1-(2-nitrophenyl)ethanone
2'-NITROPHENACYL BROMIDE
MFCD00010294
2-Bromo-2&#39-nitroacetophenone

Chemical & Physical Properties

[ Density]:
1.7±0.1 g/cm3

[ Boiling Point ]:
335.7±17.0 °C at 760 mmHg

[ Melting Point ]:
55-57 °C(lit.)

[ Molecular Formula ]:
C8H6BrNO3

[ Molecular Weight ]:
244.042

[ Flash Point ]:
156.9±20.9 °C

[ Exact Mass ]:
242.953094

[ PSA ]:
62.89000

[ LogP ]:
1.80

[ Vapour Pressure ]:
0.0±0.7 mmHg at 25°C

[ Index of Refraction ]:
1.609

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS05

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H314

[ Precautionary Statements ]:
P280-P305 + P351 + P338-P310

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges

[ Hazard Codes ]:
C: Corrosive;

[ Risk Phrases ]:
R34

[ Safety Phrases ]:
S26-S27-S28-S36/37/39-S45

[ RIDADR ]:
UN 3261 8/PG 2

[ WGK Germany ]:
3

[ Packaging Group ]:
III

[ Hazard Class ]:
8

[ HS Code ]:
2914700090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • 2′-Nitroacetophenone
  • 2-Nitrobenzaldehyde
  • (2-nitrobenzoyl)diazomethane
  • 2-Nitrobenzoyl chloride
  • Hydrogen bromide
  • acetic acid
  • Bromine

DownStream

  • 2,4-dimethyl-8-(2-nitrophenyl)imidazo[1,2-a][1,8]naphthyridine
  • 4-(2-Nitro-Phenyl)-Thiazol-2-Ylamine
  • Kynurenine
  • [1]benzothiolo[3,2-b]quinoline
  • Indigo
  • 2-Methyl-4-(2-nitrophenyl)thiazole
  • 2-(2-methyl-1,3-thiazol-4-yl)aniline
  • 2-(2-Nitrophenyl)ethanol
  • 2-(2-NITROPHENYL)H-IMIDAZO[1,2-A]PYRIDINE
  • 2-AMINO-1-(2-NITRO-PHENYL)-ETHANONE HYDROCHLORIDE

Customs

[ HS Code ]: 2914700090

[ Summary ]:
HS: 2914700090 halogenated, sulphonated, nitrated or nitrosated derivatives of ketones and quinones, whether or not with other oxygen function Tax rebate rate:9.0% Supervision conditions:none VAT:17.0% MFN tariff:5.5% General tariff:30.0%

Articles

Derivatization procedures for detection of prostaglandins in biological matrices by liquid chromatography/electrochemistry.

Talanta 36(3) , 373-7, (1989)

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Related Compounds

  • 2-bromo-2',6'-dimethoxy-4,5-dimethylbiphenyl
  • 2-Bromo-2'-[hydroxyl(diphenyl)methyl]biphenyl
  • 2-BROMO-2'-METHYLBENZOPHENONE
  • 2-bromo-2',4'-dimethoxyacetophenone
  • 2-bromo-2',4'-dichloroacetophenone
  • 2-Bromo-2',4'-dichloroacetophenone
  • 1-(1H-imidazol-2-yl)-1-phenylpropan-1-ol
  • 4-Iodo-1H-indazole-6-carboxylic acid
  • (R)-Methyl 1-(piperidin-4-yl)pyrrolidine-2-carboxylate dihydrochloride
  • 4-Fluoro-3-(1,2,3,6-tetrahydropyridin-4-yl)-1H-indole hydrochloride
  • 1-Tosylcyclopropanamine
  • N-(4-(1H-Pyrrol-1-yl)phenyl)-2,2,2-trifluoroacetamide
  • Methyl 4-(cyclohexylamino)-4-oxobut-2-enoate
  • 3-Bromo-6-(methylthio)pyridazine
  • 4-Bromo-1-(phenylsulfonyl)-6-(trifluoromethyl)-1H-indole
  • 4-(Piperidin-3-yl)pyridine hydrochloride
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