Cytarabine hydrochloride

Suppliers

Names

[ CAS No. ]:
69-74-9

[ Name ]:
Cytarabine hydrochloride

[Synonym ]:
2(1H)-pyrimidinone, 1-β-D-arabinofuranosyl-3,4-dihydro-4-imino-, hydrochloride (1:1)
Cytosine, 1-β-D-arabino-furanosyl-, hydrochloride
1-b-D-Arabinofuranosylcytosine Monohydrochloride
Cytosine arabinoside hydrochloride
1-(β-D-Arabinofuranosyl)-4-imino-3,4-dihydropyrimidin-2(1H)-one hydrochloride (1:1)
4-amino-1-[(2R,3S,4S,5R)-3,4-dihydroxy-5-(hydroxymethyl)tetrahydrofuran-2-yl]pyrimidin-2(1H)-one hydrochloride
1-β-D-Arabinofuranosylcytosine hydrochloride
Ara-cytidine hydrochloride
4-Amino-1-b-D-arabinofuranosyl-2(1H)-pyrimidinone Monohydrochloride
u 19920a
4-Amino-1-(β-D-arabinofuranosyl)pyrimidin-2(1H)-one hydrochloride (1:1)
MFCD00012839
EINECS 200-713-9
4-Amino-1-(β-D-arabinofuranosyl)-2(1H)-pyrimidinone hydrochloride (1:1)
2(1H)-Pyrimidinone, 4-amino-1-β-D-arabinofuranosyl-, hydrochloride (1:1)
4-amino-1-β-D-arabinofuranosylpyrimidin-2(1H)-one hydrochloride

Chemical & Physical Properties

[ Boiling Point ]:
545.7ºC at 760 mmHg

[ Melting Point ]:
197-198 °C(lit.)

[ Molecular Formula ]:
C9H14ClN3O5

[ Molecular Weight ]:
279.678

[ Flash Point ]:
283.8ºC

[ Exact Mass ]:
279.062195

[ PSA ]:
130.83000

[ Stability ]:
Stable. Combustible. Incompatible with strong oxidizing agents.

MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
HA5500000
CHEMICAL NAME :
Cytosine, 1-beta-D-arabinofuranosyl-, monohydrochloride
CAS REGISTRY NUMBER :
69-74-9
LAST UPDATED :
199706
DATA ITEMS CITED :
17
MOLECULAR FORMULA :
C9-H13-N3-O5.Cl-H
MOLECULAR WEIGHT :
279.71

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
Standard Draize test
ROUTE OF EXPOSURE :
Administration into the eye
SPECIES OBSERVED :
Human
TYPE OF TEST :
Standard Draize test
ROUTE OF EXPOSURE :
Administration into the eye
SPECIES OBSERVED :
Primate - monkey
TYPE OF TEST :
Standard Draize test
ROUTE OF EXPOSURE :
Administration into the eye
SPECIES OBSERVED :
Rodent - rabbit
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
>3200 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
5500 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
826 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
825 mg/kg
TOXIC EFFECTS :
Behavioral - food intake (animal) Behavioral - changes in motor activity (specific assay) Nutritional and Gross Metabolic - weight loss or decreased weight gain
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Subcutaneous
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
2262 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intravenous
SPECIES OBSERVED :
Mammal - dog
DOSE/DURATION :
172 mg/kg
TOXIC EFFECTS :
Gastrointestinal - nausea or vomiting
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intravenous
SPECIES OBSERVED :
Primate - monkey
DOSE/DURATION :
396 mg/kg
TOXIC EFFECTS :
Behavioral - changes in motor activity (specific assay) Gastrointestinal - changes in structure or function of salivary glands Gastrointestinal - nausea or vomiting
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Intraperitoneal
DOSE :
280 mg/kg
SEX/DURATION :
female 15 day(s) after conception
TOXIC EFFECTS :
Reproductive - Effects on Newborn - biochemical and metabolic
TYPE OF TEST :
Specific locus test
TYPE OF TEST :
Cytogenetic analysis

MUTATION DATA

TYPE OF TEST :
Mutation in mammalian somatic cells
TEST SYSTEM :
Rodent - mouse Lymphocyte
DOSE/DURATION :
5 mg/L
REFERENCE :
EMMUEG Environmental and Molecular Mutagenesis. (Alan R. Liss, Inc., 41 E. 11th St., New York, NY 10003) V.10- 1987- Volume(issue)/page/year: 12,85,1988

Safety Information

[ Symbol ]:

GHS07, GHS08

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H317-H319-H341-H361

[ Precautionary Statements ]:
P280-P305 + P351 + P338

[ Hazard Codes ]:
Xn:Harmful;

[ Risk Phrases ]:
R36;R43;R63

[ Safety Phrases ]:
S26-S36/37

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ RTECS ]:
HA5500000

[ HS Code ]:
2942000000

Synthetic Route

Precursor & DownStream

Precursor

  • Cytarabine

DownStream

  • 5-Chlorocytosine arabinoside
  • 1-β-d-ARABINOFURANOSYL-2′,3′,5′-TRIACETATE
  • [5-(4-acetamido-2-oxo-pyrimidin-1-yl)-3,4-diacetyloxy-oxolan-2-yl]methyl acetate

Customs

[ HS Code ]: 2942000000

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