Tris(trimethylsiloxy)ethylene

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Names

[ CAS No. ]:
69097-20-7

[ Name ]:
Tris(trimethylsiloxy)ethylene

[Synonym ]:
Tris(trimethylsiloxy)ethylene
3,6-Dioxa-2,7-disilaoct-4-ene, 2,2,7,7-tetramethyl-4-[(trimethylsilyl)oxy]-
2,2,7,7-Tetramethyl-4-[(trimethylsilyl)oxy]-3,6-dioxa-2,7-disilaoct-4-ene
1,2-bis(trimethylsilyloxy)ethenoxy-trimethylsilane
EINECS 273-864-1
Silane, [1-ethenyl-2-ylidenetris(oxy)]tris[trimethyl-
MFCD00011641

Chemical & Physical Properties

[ Density]:
0.9±0.1 g/cm3

[ Boiling Point ]:
272.9±0.0 °C at 760 mmHg

[ Molecular Formula ]:
C11H28O3Si3

[ Molecular Weight ]:
292.595

[ Flash Point ]:
95.2±22.2 °C

[ Exact Mass ]:
292.134613

[ PSA ]:
27.69000

[ LogP ]:
5.55

[ Vapour Pressure ]:
0.0±0.5 mmHg at 25°C

[ Index of Refraction ]:
1.425

[ Storage condition ]:
2-8°C

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS02, GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H226-H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xi: Irritant;

[ Risk Phrases ]:
R10;R36/37/38

[ Safety Phrases ]:
S26-S36-S37/39-S16

[ RIDADR ]:
UN 1993 3/PG 3

[ WGK Germany ]:
3

[ Packaging Group ]:
III

[ Hazard Class ]:
3.2

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • Trimethylsilyl trifluoromethanesulfonate
  • Trimethylsilyl trimethylsiloxyacetate
  • Chlorotrimethylsilane

DownStream

  • trimethylsilyl 3-ethoxy-2-trimethylsilyloxybutanoate
  • Glycolophenone
  • 1-(4-chlorophenyl)-3-hydroxypropan-2-one
  • 1-hydroxy-3-phenylpropan-2-one
  • 1-cyclohexyl-2-hydroxyethanone
  • 2-hydroxy-3,3-dimethylbutyricacid

Articles

Stereospecific total synthesis of ajugarin-IV. Kende AS, et al.

Tetrahedron Lett. 23(17) , 1751-54, (1982)

Multienzymatic preparation of 3-[(1R)-1-hydroxyethyl] benzoic acid and (2< i> S</i>)-hydroxy (phenyl) ethanoic acid. Gennaro PD, et al.

Tetrahedron Asymmetry 21(15) , 1885-89, (2010)


More Articles

Related Compounds

  • tris[(trimethylsiloxy)methyl] isocyanurate
  • [tris(trimethylsiloxy)silylethyl]dimethylchlorosilane
  • tris(trimethylsiloxy)chlorogermane
  • tris(trimethylsiloxy)silanol
  • tris(trimethylsiloxy)silylethyltriethoxysilane
  • tris(trimethylsiloxy)silane
  • Tert-butyl 4-{5-[(chloromethoxy)carbonyl]-4-ethyl-1,3-oxazol-2-yl}piperidine-1-carboxylate
  • Chloromethyl 3-[benzyl(methyl)amino]-2-{[(tert-butoxy)carbonyl]amino}propanoate
  • 2-tert-butyl 3-chloromethyl (1R,3R,5R)-2-azabicyclo[3.1.0]hexane-2,3-dicarboxylate
  • tert-butyl (3S)-4-{5-[(chloromethoxy)carbonyl]pyridin-3-yl}-3-methylpiperazine-1-carboxylate
  • 3-[5-(2-fluorophenyl)-1-methyl-2-oxo-2,3-dihydro-1H-1,4-benzodiazepin-3-yl]-1-[(1R)-1-phenylpropyl]urea
  • 3-(5-chlorothiophen-2-yl)-1-[5-(2-fluorophenyl)-1-methyl-2-oxo-2,3-dihydro-1H-1,4-benzodiazepin-3-yl]urea
  • 5-(1-ethyl-1H-1,2,4-triazol-5-yl)-1,3-oxazolidin-2-one
  • 5-cyclobutyl-1-(1,1,1-trifluoropropan-2-yl)-1H-1,2,3-triazole-4-carbothioamide
  • 1-[2-(1-ethyl-1H-1,2,4-triazol-5-yl)ethyl]cyclopropan-1-ol
  • 3-(2,5-dichlorothiophen-3-yl)-1-[5-(2-fluorophenyl)-1-methyl-2-oxo-2,3-dihydro-1H-1,4-benzodiazepin-3-yl]urea
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