2'-Hydroxy-4'-methylacetophenone

Names

[ CAS No. ]:
6921-64-8

[ Name ]:
2'-Hydroxy-4'-methylacetophenone

[Synonym ]:
EINECS 230-040-6
1-(2-hydroxy-4-methylphenyl)ethanone
MFCD00100559
2'-Hydroxy-4'-methylacetophenone

Chemical & Physical Properties

[ Density]:
1.08 g/mL at 25 °C(lit.)

[ Boiling Point ]:
245 °C(lit.)

[ Melting Point ]:
45-48ºC

[ Molecular Formula ]:
C₉H₁₀O₂

[ Molecular Weight ]:
150.17400

[ Flash Point ]:
>230 °F

[ Exact Mass ]:
150.06800

[ PSA ]:
37.30000

[ LogP ]:
1.90320

[ Index of Refraction ]:
n20/D 1.565(lit.)

MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xi: Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S36-S37/39

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2914501900

Synthetic Route

Click to get detail synthetic route

Customs

[ HS Code ]: 2914501900

[ Summary ]:
2914501900 other ketone-phenols。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:5.5%。General tariff:30.0%

Articles

Acaricidal toxicity of 2'-hydroxy-4'-methylacetophenone isolated from Angelicae koreana roots and structure-activity relationships of its derivatives.

J. Agric. Food Chem. 60(14) , 3606-11, (2012)

The acaricidal activities of 2'-hydroxy-4'-methylacetophenone derived from Angelica koreana roots and its derivatives against Dermatophagoides farinae, Dermatophagoides pteronyssinus, and Tyrophagus p...

Zirconium tetrachloride as a mediator for ambient temperature ortho-fries rearrangements. Harrowven DC and Dainty RF.

Tetrahedron 37(42) , 7659-7660, (1996)

4'-Hydroxy-3-methoxyflavones with potent antipicornavirus activity. De Meyer N, et al.

J. Med. Chem. 34(2) , 736-746, (1991)

2'-Hydroxy-4'-methylacetophenone oxime
5'-chloro-2'-hydroxy-4'-methylacetophenone
2'-Hydroxy-4'-methyl-5'-acetylacetophenone
2'-hydroxy-4'-methoxy-4-nitrochalcone
2'-hydroxy-4'-benzyloxy-6'methoxychalkone
2'-hydroxy-4'-iodo-4-benzyloxy-3,5-dimethoxy-chalcone
(2R,4R)-1-{2-[({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)methyl]cyclopentanecarbonyl}-4-hydroxypyrrolidine-2-carboxylic acid
(2S,4R)-1-[4-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)-3-methyloxolane-3-carbonyl]-4-hydroxypyrrolidine-2-carboxylic acid
(2R,4R)-1-[4-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)-3-methyloxolane-3-carbonyl]-4-hydroxypyrrolidine-2-carboxylic acid
(2S,4R)-1-[3-ethoxy-4-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)butanoyl]-4-hydroxypyrrolidine-2-carboxylic acid
9-(5-Ethyl-1,3,4-thiadiazol-2-yl)-5-oxa-8-azaspiro[3.5]nonane
2-ethyl-2-{2-[({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)methyl]-3-methylbutanamido}butanoic acid
3-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)-3-{[(1,3-thiazol-5-yl)methyl]carbamoyl}propanoic acid
4-[3-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)-N,2-dimethylbutanamido]butanoic acid
2-[3-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)-2-methylbutanamido]-2-methylbutanoic acid
(2S)-2-[(2R)-2-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)-3,3-dimethylbutanamido]-3-hydroxypropanoic acid

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