4-Bromo-3-methylaniline

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Names

[ CAS No. ]:
6933-10-4

[ Name ]:
4-Bromo-3-methylaniline

[Synonym ]:
4-bromo-3-methylbenzenamine
EINECS 230-056-3
Benzenamine, 4-bromo-3-methyl-
Benzenamine,4-bromo-3-methyl
4-Bromo-m-toluidine
2-bromo-5-aminotoluene
5-Amino-2-bromotoluene
4-Bromo-3-methylaniline
MFCD00007828
4-bromo-3-methyl-aniline
amino-5-bromo-2-toluene
3-Methyl-4-bromoaniline

Chemical & Physical Properties

[ Density]:
1.5±0.1 g/cm3

[ Boiling Point ]:
240.0±0.0 °C at 760 mmHg

[ Melting Point ]:
80-82 °C(lit.)

[ Molecular Formula ]:
C7H8BrN

[ Molecular Weight ]:
186.049

[ Flash Point ]:
101.2±21.8 °C

[ Exact Mass ]:
184.984009

[ PSA ]:
26.02000

[ LogP ]:
2.51

[ Vapour Pressure ]:
0.0±0.4 mmHg at 25°C

[ Index of Refraction ]:
1.609

[ Storage condition ]:
Room temperature.

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H302 + H312 + H332-H315-H319-H335

[ Precautionary Statements ]:
P261-P280-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi:Irritant;

[ Risk Phrases ]:
R33;R36/37/38

[ Safety Phrases ]:
S26-S37/39-S24/25

[ RIDADR ]:
UN2811

[ WGK Germany ]:
3

[ Packaging Group ]:
III

[ Hazard Class ]:
6.1

[ HS Code ]:
2921430090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • 1-Bromo-2-methyl-4-nitrobenzene
  • 3,5-Dibromotoluene
  • 4-azido-1-bromo-2-methylbenzene
  • 3-Toluidine
  • 3'-Methylacetanilide
  • META-TOLYLHYDROXYLAMINE
  • Benzamide, N-m-tolyl-
  • Water
  • Bromine

DownStream

  • N-(4-bromo-3-methylphenyl)-3-hydrazinyl-3-oxopropanamide
  • 5-Bromo-6-Methylindoline-2,3-dione
  • 4-methyl-5-bromoisatin
  • 4-Bromo-3-methylbenzonitrile
  • 4-bromo-3-methylbenzenethiol
  • 2-Bromo-5-fluorotoluene
  • N-(4-bromo-3-methylphenyl)-3-chloropropanamide
  • 4-[2-methyl-4-(2-oxopyrrolidin-1-yl)phenyl]benzoic acid
  • 3-(4-bromo-3-methylphenyl)-1,1-dimethylurea
  • 1-Bromo-2-(bromomethyl)-4-iodobenzene, alpha,2-Dibromo-5-iodotoluene

Customs

[ HS Code ]: 2921430090

[ Summary ]:
HS:2921430090 toluidines and their derivatives; salts thereof VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

Articles

Multikilogram-scale synthesis of a biphenyl carboxylic acid derivative using a Pd/C-mediated suzuki coupling approach.

Org. Process Res. Dev. 3(4) , 248-252, (1999)


More Articles

Related Compounds

  • N-BOC-4-bromo-3-Methylaniline
  • 4-bromo-3-methylaniline,hydrochloride
  • N-(α-bromopropionyl)-4-bromo-3-methylaniline
  • N-(1,3-Benzodioxol-5-ylmethyl)-4-bromo-3-methylaniline
  • N-(1H-Benzotriazol-1-ylmethyl)-4-bromo-3-methylaniline
  • 4-Bromo-3-fluoro-2-methylaniline
  • 4,4,5,5-Tetramethyl-2-(7-methylbenzofuran-2-yl)-1,3,2-dioxaborolane
  • 7-ethoxy-2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-1H-indole
  • 2-(7-Methoxybenzofuran-2-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
  • 7-Fluoro-1-methyl-6-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-1H-indole
  • 1-Methyl-1h-imidazole-4-sulfonyl fluoride
  • 3-Acetyl-5-formylbenzoic acid
  • 2-Benzyl-4-bromoisoindoline hydrochloride
  • 5-(2-Ethylazepan-1-yl)pentanenitrile
  • 3-(Azetidin-1-ylmethyl)-5-trifluoromethyl-aniline
  • 1-(2,2-Dimethylpropyl)piperazine dihydrobromide
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