Phenylsilane

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Names

[ CAS No. ]:
694-53-1

[ Name ]:
Phenylsilane

[Synonym ]:
Phenylsilane
phenyl silane
Benzene, silyl-
EINECS 211-772-5
Silylbenzene
Fenylsilan
SILANE,PHENYL
MFCD00013478
monophenylsilane
Benzene,silyl

Chemical & Physical Properties

[ Density]:
0.877 g/mL at 25 °C(lit.)

[ Boiling Point ]:
119.3±9.0 °C at 760 mmHg

[ Melting Point ]:
-64 to -68°C

[ Molecular Formula ]:
C6H8Si

[ Molecular Weight ]:
108.213

[ Flash Point ]:
7.2±0.0 °C

[ Exact Mass ]:
108.039528

[ Vapour Pressure ]:
19.2±0.2 mmHg at 25°C

[ Index of Refraction ]:
n20/D 1.510(lit.)

[ Storage condition ]:
Flammables area

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
VV4825000
CHEMICAL NAME :
Silane, phenyl-
CAS REGISTRY NUMBER :
694-53-1
LAST UPDATED :
199701
DATA ITEMS CITED :
4
MOLECULAR FORMULA :
C6-H8-Si

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
700 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J., Prague, Czechoslovakia, Avicenum, 1986 Volume(issue)/page/year: -,1227,1986
TYPE OF TEST :
LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
14500 mg/m3/2H
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J., Prague, Czechoslovakia, Avicenum, 1986 Volume(issue)/page/year: -,1227,1986

Safety Information

[ Symbol ]:

GHS02, GHS07

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H225-H261-H302-H315-H319-H332-H335

[ Supplemental HS ]:
Reacts violently with water.

[ Precautionary Statements ]:
P210-P231 + P232-P261-P305 + P351 + P338-P422

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xn:Harmful;F:Flammable;

[ Risk Phrases ]:
R11;R14/15;R20/22;R36/37/38

[ Safety Phrases ]:
S16-S43

[ RIDADR ]:
UN 3399 4.3/PG 2

[ WGK Germany ]:
1

[ RTECS ]:
VV4825000

[ Packaging Group ]:
II

[ Hazard Class ]:
4.3

[ HS Code ]:
2931900090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • Trichlorophenylsilane
  • 2-hydroxy-5-[(5-methyl-3-phenyl-oxazole-4-carbonyl)amino]benzoic acid
  • Lithium Aluminium Hydride
  • Phenyltriethoxysilane
  • METHYLMAGNESIUM BROMIDE
  • chlorophenylsilane
  • METHYLLITHIUM
  • Diphenylsilane
  • (η(5)-C5Me5)2HfH2
  • phenyl(phenylsilyl)silane

DownStream

  • tribromo(phenyl)silane
  • tributoxy(phenyl)silane
  • Benzene,1-methyl-4-[(4-methylphenyl)methyl]-
  • phenylsilyl cation
  • chlorophenylsilane
  • phenyltrifluorosilane
  • 1-phenyl-1-butene
  • Cyclopropyl phenylmethanol
  • (cyclopropyl(phenyl)methoxy)(phenyl)silane
  • (PhCH(C3H5)O)2SiHPh

Customs

[ HS Code ]: 2931900090

[ Summary ]:
2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%

Articles

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Nano Lett. 16 , 374-80, (2016)

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ACS Nano 9 , 7456-65, (2015)

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Related Compounds

  • phenylsilane
  • phenylsilane-d3
  • methyl-phenylsilane
  • p-methoxyphenylsilane
  • 1-Naphthylphenylsilane
  • Methyl(oxo)phenylsilane
  • 2-Amino-3-(3,3-dimethyl-2,5-dioxopyrrolidin-1-yl)butanoic acid
  • 2-amino-3-[4-(trifluoromethyl)-1H-pyrazol-1-yl]butanoic acid
  • 2-(methylamino)-3-[3-(propan-2-yl)-1H-1,2,4-triazol-1-yl]butanamide
  • 3-(4-cyclopropyl-1H-pyrazol-1-yl)-2-(methylamino)butanamide
  • 2-amino-3-(1H-indazol-1-yl)butanamide
  • 3-Chloro-4-fluoro-5-(pyridin-3-yl)aniline
  • 3-Chloro-4-fluoro-5-(3-methoxyphenyl)aniline
  • 3-chloro-4-fluoro-5-(1H-imidazol-4-yl)aniline
  • 3-Chloro-4-fluoro-5-(pyridin-2-yl)aniline
  • 1-(3-Formylpyridin-4-yl)azetidine-2-carboxylic acid
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